Experimental study of the proposed super-thermal-conductor: BAs

Lv, Bing; Lan, Yucheng; Wang, Xiqu; Zhang, Qian; Hu, Yongjie; Jacobson, Allan J.; Broido, David; Chen, Gang; Ren, Zhifeng; Chu, Ching-Wu

doi:10.1063/1.4913441

Title: Experimental study of the proposed super-thermal-conductor: BAs

Journal Article · Fri Feb 20 00:00:00 EST 2015 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4913441· OSTI ID:1387754

Lv, Bing ^[1]; Lan, Yucheng ^[1]; Wang, Xiqu ^[2]; Zhang, Qian ^[1]; Hu, Yongjie ^[3]; Jacobson, Allan J. ^[2]; Broido, David ^[4]; Chen, Gang ^[3]; Ren, Zhifeng ^[1]; Chu, Ching-Wu ^[5]

Univ. of Houston, TX (United States). Dept. of Physics. Texas Center for Superconductivity
Univ. of Houston, TX (United States). Dept. of Chemistry. Texas Center for Superconductivity
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Mechanical Engineering
Boston College, Chestnut Hill, MA (United States). Dept. of Physics
Univ. of Houston, TX (United States). Dept. of Physics. Texas Center for Superconductivity; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Recent calculations predict a super-thermal-conductivity of ~2000 Wm^-1 K^-1, comparable to that of diamond, in cubic boron arsenide (BAs) crystals, which may offer inexpensive insulators with super-thermal-conductivity for microelectronic device applications. We have synthesized and characterized here single crystals of BAs with a zinc blende cubic structure and lattice parameters of a = 4.7830(7) Å. A relatively high thermal conductivity of ~200 Wm^-1 K^-1 is obtained, close to those of best non-carbon crystal insulators, such as SiC, although still an order of magnitude smaller than the value predicted. Based on our XPS, X-ray single crystal diffraction, and Raman scattering results, steps to achieve the predicted super-thermal conductivity in BAs are proposed.

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Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001299

OSTI ID:: 1387754

Journal Information:: Applied Physics Letters, Vol. 106, Issue 7; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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High Thermal Conductivity in Boron Arsenide: From Prediction to Reality Tian, Fei; Ren, Zhifeng Angewandte Chemie, Vol. 131, Issue 18 https://doi.org/10.1002/ange.201812112	journal	April 2019
Seeded growth of boron arsenide single crystals with high thermal conductivity Tian, Fei; Song, Bai; Lv, Bing Applied Physics Letters, Vol. 112, Issue 3 https://doi.org/10.1063/1.5004200	journal	January 2018
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Mechanical properties of boron arsenide single crystal Tian, Fei; Luo, Kun; Xie, Chenlong Applied Physics Letters, Vol. 114, Issue 13 https://doi.org/10.1063/1.5093289	journal	April 2019
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