Chemical and Morphological Inhomogeneity of Aluminum Metal and Oxides from Soft X-ray Spectromicroscopy

Altman, Alison B.; Pemmaraju, C. Das; Alayoglu, Selim; Arnold, John; Booth, Corwin H.; Braun, Augustin; Bunker, Christopher E.; Herve, Alexandre; Minasian, Stefan G.; Prendergast, David; Shuh, David K.; Tyliszczak, Tolek

doi:10.1021/acs.inorgchem.7b00280

Title: Chemical and Morphological Inhomogeneity of Aluminum Metal and Oxides from Soft X-ray Spectromicroscopy

Journal Article · Thu May 04 00:00:00 EDT 2017 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.7b00280· OSTI ID:1379849

Altman, Alison B. ^[1];

^[2]; Alayoglu, Selim ^[3];

^[1]; Booth, Corwin H. ^[3]; Braun, Augustin ^[3]; Bunker, Christopher E. ^[4]; Herve, Alexandre ^[3];

^[3]; Prendergast, David ^[2]; Shuh, David K. ^[3]; Tyliszczak, Tolek ^[5]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Air Force Research Lab. (AFRL), Wright-Patterson AFB, OH (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source

Oxygen and aluminum K-edge X-ray absorption spectroscopy (XAS), imaging from a scanning transmission X-ray microscope (STXM), and first-principles calculations were used to probe the composition and morphology of bulk aluminum metal, α- and γ-Al ₂ O ₃ , and several types of aluminum nanoparticles. The imaging results agreed with earlier transmission electron microscopy studies that showed a 2 to 5 nm thick layer of Al ₂ O ₃ on all the Al surfaces. Spectral interpretations were guided by examination of the calculated transition energies, which agreed well with the spectroscopic measurements. The features we observed in the experimental O and Al K-edge XAS were used to determine the chemical structure and phase of the Al ₂ O₃ on the aluminum surfaces. For unprotected 18 and 100 nm Al nanoparticles, this analysis revealed an oxide layer that was similar to γ-Al ₂ O ₃ and comprised of both tetrahedral and octahedral Al coordination sites. For oleic acid-protected Al nanoparticles, only tetrahedral Al oxide coordination sites were observed. Our results were correlated to trends in the reactivity of the different materials, which suggests that the structures of different Al ₂ O ₃ layers have an important role in the accessibility of the underlying Al metal toward further oxidation. Combined, the Al K-edge XAS and STXM results provided detailed chemical information that was not obtained from powder X-ray diffraction or imaging from a transmission electron microscope.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1379849

Journal Information:: Inorganic Chemistry, Vol. 56, Issue 10; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework Moreau, Liane M.; Herve, Alexandre; Straub, Mark D. Chemical Science, Vol. 11, Issue 18 https://doi.org/10.1039/c9sc06117g	journal	January 2020

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