A multifunctional biphasic water splitting catalyst tailored for integration with high-performance semiconductor photoanodes

Yang, Jinhui; Cooper, Jason K.; Toma, Francesca M.; Walczak, Karl A.; Favaro, Marco; Beeman, Jeffrey W.; Hess, Lucas H.; Wang, Cheng; Zhu, Chenhui; Gul, Sheraz; Yano, Junko; Kisielowski, Christian; Schwartzberg, Adam; Sharp, Ian D.

doi:10.1038/nmat4794

Title: A multifunctional biphasic water splitting catalyst tailored for integration with high-performance semiconductor photoanodes

Journal Article · Mon Nov 07 00:00:00 EST 2016 · Nature Materials

DOI:https://doi.org/10.1038/nmat4794· OSTI ID:1379751

Yang, Jinhui ^[1]; Cooper, Jason K. ^[1]; Toma, Francesca M. ^[1]; Walczak, Karl A. ^[1]; Favaro, Marco ^[1]; Beeman, Jeffrey W. ^[1]; Hess, Lucas H. ^[1];

^[2]; Zhu, Chenhui ^[2]; Gul, Sheraz ^[3];

^[4]; Kisielowski, Christian ^[5]; Schwartzberg, Adam ^[5]; Sharp, Ian D. ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis, Chemical Sciences Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Biophysics and Integrated Bioimaging
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis, Molecular Biophysics and Integrated Bioimaging
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry, Materials Science Division

Artificial photosystems are advanced by the development of conformal catalytic materials that promote desired chemical transformations, while also maintaining stability and minimizing parasitic light absorption for integration on surfaces of semiconductor light absorbers. We demonstrate that multifunctional, nanoscale catalysts that enable high-performance photoelectrochemical energy conversion can be engineered by plasma-enhanced atomic layer deposition. The collective properties of tailored Co ₃ O ₄ /Co(OH) ₂ thin films simultaneously provide high activity for water splitting, permit efficient interfacial charge transport from semiconductor substrates, and enhance durability of chemically sensitive interfaces. Furthermore, these films comprise compact and continuous nanocrystalline Co ₃O ₄ spinel that is impervious to phase transformation and impermeable to ions, thereby providing effective protection of the underlying substrate. Moreover, a secondary phase of structurally disordered and chemically labile Co(OH) ₂ is introduced to ensure a high concentration of catalytically active sites. Application of this coating to photovoltaic p ⁺ n-Si junctions yields best reported performance characteristics for crystalline Si photoanodes.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; SC0004993

OSTI ID:: 1379751

Journal Information:: Nature Materials, Vol. 16, Issue 3; ISSN 1476-1122

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 183 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
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