Controlling the Temperature and Speed of the Phase Transition of VO2 Microcrystals

Yoon, Joonseok; Kim, Howon; Chen, Xian; Tamura, Nobumichi; Mun, Bongjin Simon; Park, Changwoo; Ju, Honglyoul

doi:10.1021/acsami.5b11144

Title: Controlling the Temperature and Speed of the Phase Transition of VO₂ Microcrystals

Journal Article · Tue Dec 29 00:00:00 EST 2015 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.5b11144· OSTI ID:1379049

Yoon, Joonseok ^[1]; Kim, Howon ^[1]; Chen, Xian ^[2]; Tamura, Nobumichi ^[3]; Mun, Bongjin Simon ^[4]; Park, Changwoo ^[5]; Ju, Honglyoul ^[1]

Yonsei Univ., Seoul (Republic of Korea). Dept. of Physics
Hong Kong Univ., of Science and Technology (China). Dept. of Mechanical and Aerospace Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Gwangju Inst. of Science and Technology (Korea, Republic of). Dept. of Physics and Photon Science, Ertl Center for Electrochemistry and Catalysis
Hanbat National Univ., Daejeon (Republic of Korea). Division of Applied Chemistry and Biotechnology; Advanced Nano Products, Sejong (Republic of Korea)

Here, we investigated the control of two important parameters of vanadium dioxide (VO₂ ) microcrystals, the phase transition temperature and speed, by varying microcrystal width. By using the reflectivity change between insulating and metallic phases, phase transition temperature is measured by optical microscopy. As the width of square cylinder-shaped microcrystals decreases from ~70 to ~1 μm, the phase transition temperature (67 °C for bulk) varied as much as 26.1 °C (19.7 °C) during heating (cooling). In addition, the propagation speed of phase boundary in the microcrystal, i.e., phase transition speed, is monitored at the onset of phase transition by using the high-speed resistance measurement. The phase transition speed increases from 4.6 × 10 ² to 1.7 × 10⁴ μm/s as the width decreases from ~50 to ~2 μm. While the statistical description for a heterogeneous nucleation process explains the size dependence on phase transition temperature of VO₂, the increase of effective thermal exchange process is responsible for the enhancement of phase transition speed of small VO ₂ microcrystals. These findings not only enhance the understanding of VO₂ intrinsic properties but also contribute to the development of innovative electronic devices.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1379049

Journal Information:: ACS Applied Materials and Interfaces, Vol. 8, Issue 3; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 36 works

Citation information provided by
Web of Science

References (44)

Oxide Electronics Utilizing Ultrafast Metal-Insulator Transitions Yang, Zheng; Ko, Changhyun; Ramanathan, Shriram Annual Review of Materials Research, Vol. 41, Issue 1 https://doi.org/10.1146/annurev-matsci-062910-100347	journal	August 2011
Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature Morin, F. J. Physical Review Letters, Vol. 3, Issue 1 https://doi.org/10.1103/PhysRevLett.3.34	journal	July 1959
Pulsed laser deposition of VO ₂ thin films Kim, D. H.; Kwok, H. S. Applied Physics Letters, Vol. 65, Issue 25 https://doi.org/10.1063/1.112476	journal	December 1994
Evidence of a Pressure-Induced Metallization Process in Monoclinic ${VO}_{2}$ Arcangeletti, E.; Baldassarre, L.; Di Castro, D. Physical Review Letters, Vol. 98, Issue 19 https://doi.org/10.1103/PhysRevLett.98.196406	journal	May 2007
Femtosecond Structural Dynamics in ${VO}_{2}$ during an Ultrafast Solid-Solid Phase Transition Cavalleri, A.; Tóth, Cs.; Siders, C. W. Physical Review Letters, Vol. 87, Issue 23 https://doi.org/10.1103/PhysRevLett.87.237401	journal	November 2001
Coherent Structural Dynamics and Electronic Correlations during an Ultrafast Insulator-to-Metal Phase Transition in ${VO}_{2}$ Kübler, C.; Ehrke, H.; Huber, R. Physical Review Letters, Vol. 99, Issue 11 https://doi.org/10.1103/PhysRevLett.99.116401	journal	September 2007
Mechanism and observation of Mott transition in VO ₂ -based two- and three-terminal devices Kim, Hyun-Tak; Chae, Byung-Gyu; Youn, Doo-Hyeb New Journal of Physics, Vol. 6 https://doi.org/10.1088/1367-2630/6/1/052	journal	January 2004
Electromechanical Actuation and Current-Induced Metastable States in Suspended Single-Crystalline VO ₂ Nanoplatelets Tselev, Alexander; Budai, John D.; Strelcov, Evgheni Nano Letters, Vol. 11, Issue 8 https://doi.org/10.1021/nl200493k	journal	August 2011
Electrical switching and Mott transition in VO ₂ Stefanovich, G.; Pergament, A.; Stefanovich, D. Journal of Physics: Condensed Matter, Vol. 12, Issue 41 https://doi.org/10.1088/0953-8984/12/41/310	journal	September 2000
Gas Sensor Based on Metal−Insulator Transition in VO ₂ Nanowire Thermistor Strelcov, Evgheni; Lilach, Yigal; Kolmakov, Andrei Nano Letters, Vol. 9, Issue 6 https://doi.org/10.1021/nl900676n	journal	June 2009
Nanoceramic VO2 thermochromic smart glass: A review on progress in solution processing Gao, Yanfeng; Luo, Hongjie; Zhang, Zongtao Nano Energy, Vol. 1, Issue 2 https://doi.org/10.1016/j.nanoen.2011.12.002	journal	March 2012
Two Series Oxide Resistors Applicable to High Speed and High Density Nonvolatile Memory Lee, M. -J.; Park, Y.; Suh, D. -S. Advanced Materials, Vol. 19, Issue 22 https://doi.org/10.1002/adma.200700251	journal	November 2007
Terahertz-field-induced insulator-to-metal transition in vanadium dioxide metamaterial Liu, Mengkun; Hwang, Harold Y.; Tao, Hu Nature, Vol. 487, Issue 7407 https://doi.org/10.1038/nature11231	journal	July 2012
Limits on vanadium oxide Mott metal–insulator transition field-effect transistors Hormoz, S.; Ramanathan, S. Solid-State Electronics, Vol. 54, Issue 6 https://doi.org/10.1016/j.sse.2010.01.006	journal	June 2010
Measurement of a solid-state triple point at the metal–insulator transition in VO2 Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan Nature, Vol. 500, Issue 7463 https://doi.org/10.1038/nature12425	journal	August 2013
Metallization of vanadium dioxide driven by large phonon entropy Budai, John D.; Hong, Jiawang; Manley, Michael E. Nature, Vol. 515, Issue 7528 https://doi.org/10.1038/nature13865	journal	November 2014
Suppression of Metal-Insulator Transition in VO2 by Electric Field-Induced Oxygen Vacancy Formation Jeong, J.; Aetukuri, N.; Graf, T. Science, Vol. 339, Issue 6126 https://doi.org/10.1126/science.1230512	journal	March 2013
Field Effect and Strongly Localized Carriers in the Metal-Insulator Transition Material ${VO}_{2}$ Martens, K.; Jeong, J. W.; Aetukuri, N. Physical Review Letters, Vol. 115, Issue 19 https://doi.org/10.1103/PhysRevLett.115.196401	journal	November 2015
Stoichiometry Engineering of Monoclinic to Rutile Phase Transition in Suspended Single Crystalline Vanadium Dioxide Nanobeams Zhang, Shixiong; Kim, In Soo; Lauhon, Lincoln J. Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl103925m	journal	April 2011
Axially Engineered Metal–Insulator Phase Transition by Graded Doping VO ₂ Nanowires Lee, Sangwook; Cheng, Chun; Guo, Hua Journal of the American Chemical Society, Vol. 135, Issue 12 https://doi.org/10.1021/ja400658u	journal	March 2013
New aspects of the metal–insulator transition in single-domain vanadium dioxide nanobeams Wei, Jiang; Wang, Zenghui; Chen, Wei Nature Nanotechnology, Vol. 4, Issue 7 https://doi.org/10.1038/nnano.2009.141	journal	May 2009
Memory Metamaterials Driscoll, T.; Kim, H. -T.; Chae, B. -G. Science, Vol. 325, Issue 5947 https://doi.org/10.1126/science.1176580	journal	August 2009
The Memristive Properties of a Single VO 2 Nanowire with Switching Controlled by Self-Heating Bae, Sung-Hwan; Lee, Sangmin; Koo, Hyun Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201302511	journal	August 2013
Size-Dependent Optical Properties of ${V O}_{2}$ Nanoparticle Arrays Lopez, R.; Feldman, L. C.; Haglund, R. F. Physical Review Letters, Vol. 93, Issue 17 https://doi.org/10.1103/PhysRevLett.93.177403	journal	October 2004
Depressed Phase Transition in Solution-Grown VO ₂ Nanostructures Whittaker, Luisa; Jaye, Cherno; Fu, Zugen Journal of the American Chemical Society, Vol. 131, Issue 25 https://doi.org/10.1021/ja902054w	journal	July 2009
Size effects on metal-insulator phase transition in individual vanadium dioxide nanowires Hongwei, Liu; Junpeng, Lu; Minrui, Zheng Optics Express, Vol. 22, Issue 25 https://doi.org/10.1364/OE.22.030748	journal	January 2014
Size effects in the structural phase transition of ${VO}_{2}$ nanoparticles Lopez, R.; Haynes, T. E.; Boatner, L. A. Physical Review B, Vol. 65, Issue 22 https://doi.org/10.1103/PhysRevB.65.224113	journal	June 2002
A Ge/Si heterostructure nanowire-based double quantum dot with integrated charge sensor Hu, Yongjie; Churchill, Hugh O. H.; Reilly, David J. Nature Nanotechnology, Vol. 2, Issue 10 https://doi.org/10.1038/nnano.2007.302	journal	September 2007
Electronic States and Luminescence in Porous Silicon Quantum Dots: The Role of Oxygen Wolkin, M. V.; Jorne, J.; Fauchet, P. M. Physical Review Letters, Vol. 82, Issue 1 https://doi.org/10.1103/PhysRevLett.82.197	journal	January 1999
Electronic Energy Transfer in CdSe Quantum Dot Solids Kagan, C. R.; Murray, C. B.; Nirmal, M. Physical Review Letters, Vol. 76, Issue 9 https://doi.org/10.1103/PhysRevLett.76.1517	journal	February 1996
Scaling of strength and lifetime probability distributions of quasibrittle structures based on atomistic fracture mechanics: Fig. 1. Bažant, Zdeněk P.; Le, Jia-Liang; Bazant, Martin Z. Proceedings of the National Academy of Sciences, Vol. 106, Issue 28 https://doi.org/10.1073/pnas.0904797106	journal	June 2009
Nanoscale Size Effect of Magnetic Nanocrystals and Their Utilization for Cancer Diagnosis via Magnetic Resonance Imaging Jun, Young-wook; Huh, Yong-Min; Choi, Jin-sil Journal of the American Chemical Society, Vol. 127, Issue 16 https://doi.org/10.1021/ja0422155	journal	April 2005
Size effect on the ferroelectric phase transition in ${PbTiO}_{3}$ ultrafine particles Ishikawa, Kenji; Yoshikawa, Kazutoshi; Okada, Nagaya Physical Review B, Vol. 37, Issue 10 https://doi.org/10.1103/PhysRevB.37.5852	journal	April 1988
New Directions for Low-Dimensional Thermoelectric Materials Dresselhaus, M. S.; Chen, G.; Tang, M. Y. Advanced Materials, Vol. 19, Issue 8, p. 1043-1053 https://doi.org/10.1002/adma.200600527	journal	April 2007
Observation of insulating-insulating monoclinic structural transition in macro-sized VO2 single crystals Mun, Bongjin Simon; Chen, Kai; Leem, Youngchul physica status solidi (RRL) - Rapid Research Letters, Vol. 5, Issue 3 https://doi.org/10.1002/pssr.201105011	journal	January 2011
Nonpercolative metal-insulator transition in VO $_{2}$ single crystals Mun, Bongjin Simon; Chen, Kai; Yoon, Joonseok Physical Review B, Vol. 84, Issue 11 https://doi.org/10.1103/PhysRevB.84.113109	journal	September 2011
Mott Transition in VO2 Revealed by Infrared Spectroscopy and Nano-Imaging Qazilbash, M. M.; Brehm, M.; Chae, B. -G. Science, Vol. 318, Issue 5857 https://doi.org/10.1126/science.1150124	journal	December 2007
Strain-Induced Self Organization of Metal−Insulator Domains in Single-Crystalline VO ₂ Nanobeams Wu, Junqiao; Gu, Qian; Guiton, Beth S. Nano Letters, Vol. 6, Issue 10 https://doi.org/10.1021/nl061831r	journal	October 2006
Extended Mapping and Exploration of the Vanadium Dioxide Stress-Temperature Phase Diagram Cao, J.; Gu, Y.; Fan, W. Nano Letters, Vol. 10, Issue 7 https://doi.org/10.1021/nl101457k	journal	July 2010
Nano-optical Investigations of the Metal−Insulator Phase Behavior of Individual VO ₂ Microcrystals Jones, Andrew C.; Berweger, Samuel; Wei, Jiang Nano Letters, Vol. 10, Issue 5 https://doi.org/10.1021/nl903765h	journal	May 2010
Inhomogeneity of the ultrafast insulator-to-metal transition dynamics of VO2 O’Callahan, Brian T.; Jones, Andrew C.; Hyung Park, Jae Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7849	journal	April 2015
Statistics of martensitic nucleation Chen, I-Wei; Chiao, Y-H.; Tsuzaki, K. Acta Metallurgica, Vol. 33, Issue 10 https://doi.org/10.1016/0001-6160(85)90007-0	journal	October 1985
Grain size effect on the semiconductor-metal phase transition characteristics of magnetron-sputtered VO2 thin films Brassard, D.; Fourmaux, S.; Jean-Jacques, M. Applied Physics Letters, Vol. 87, Issue 5 https://doi.org/10.1063/1.2001139	journal	August 2005
Intrinsic Optical Properties of Vanadium Dioxide near the Insulator−Metal Transition Liu, Wei-Tao; Cao, J.; Fan, W. Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl1032205	journal	February 2011

Cited By (4)

Radiative Thermal Memristor Ordonez-Miranda, Jose; Ezzahri, Younès; Tiburcio-Moreno, Jose A. Physical Review Letters, Vol. 123, Issue 2 https://doi.org/10.1103/physrevlett.123.025901	journal	July 2019
Theoretical framework of the thermal memristor via a solid-state phase change material Yang, Fan; Gordon, Madeleine P.; Urban, Jeffrey J. Journal of Applied Physics, Vol. 125, Issue 2 https://doi.org/10.1063/1.5063737	journal	January 2019
Spatiotemporal dynamics of the spin transition in $[Fe {(HB {(tz)}_{3})}_{2}]$ single crystals Ridier, Karl; Rat, Sylvain; Shepherd, Helena J. Physical Review B, Vol. 96, Issue 13 https://doi.org/10.1103/physrevb.96.134106	journal	October 2017
Size and crystallinity control of dispersed VO ₂ particles for modulation of metal–insulator transition temperature and hysteresis Zeng, Wen; Lai, Haojie; Chen, Tianyin CrystEngComm, Vol. 21, Issue 38 https://doi.org/10.1039/c9ce01013k	journal	January 2019

Similar Records

The role of the laser fluence on the Al{sub 2}O{sub 3} target in the nanostructure and morphology of VO{sub x} : Al{sub 2}O{sub 3} thin films prepared by pulsed laser deposition.

Journal Article · Sat Dec 15 00:00:00 EST 2007 · Appl. Surf. Sci. · OSTI ID:1379049

Nunez-Sanchez, S; Serna, R; Petford-Long, A K; +1 more

Modifications in the phase transition properties of predeposited VO/sub 2/ films

Journal Article · Mon Oct 01 00:00:00 EDT 1984 · J. Vac. Sci. Technol., A; (United States) · OSTI ID:1379049

Case, F C

Influence of grain size on transition temperature of thermochromic VO{sub 2}

Journal Article · Wed Jan 21 00:00:00 EST 2015 · Journal of Applied Physics · OSTI ID:1379049

Miller, Mark J.; Wang, Junlan

Related Subjects

36 MATERIALS SCIENCE
high-speed resistance measurement
metal−insulator transition
microcrystal
phase transition speed
phase transition temperature
size effect
vanadium dioxide

Title: Controlling the Temperature and Speed of the Phase Transition of VO2 Microcrystals

Citation Formats

References (44)

Cited By (4)

Similar Records

Related Subjects

Title: Controlling the Temperature and Speed of the Phase Transition of VO₂ Microcrystals