A Macrocyclic Chelator That Selectively Binds Ln4+ over Ln3+ by a Factor of 1029

Pham, Tiffany A.; Altman, Alison B.; Stieber, S. Chantal E.; Booth, Corwin H.; Kozimor, Stosh A.; Lukens, Wayne W.; Olive, Daniel T.; Tyliszczak, Tolek; Wang, Jian; Minasian, Stefan G.; Raymond, Kenneth N.

doi:10.1021/acs.inorgchem.6b00684

Title: A Macrocyclic Chelator That Selectively Binds Ln⁴⁺ over Ln³⁺ by a Factor of 10²⁹

Journal Article · Fri Jun 24 00:00:00 EDT 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b00684· OSTI ID:1377540

Pham, Tiffany A. ^[1]; Altman, Alison B. ^[1]; Stieber, S. Chantal E. ^[2]; Booth, Corwin H. ^[3]; Kozimor, Stosh A. ^[4]; Lukens, Wayne W. ^[3]; Olive, Daniel T. ^[3]; Tyliszczak, Tolek ^[3]; Wang, Jian ^[5]; Minasian, Stefan G. ^[3]; Raymond, Kenneth N. ^[1]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); California State Polytechnic Univ., Pomona, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Canadian Light Source (CLS), Saskatoon, SK (Canada)

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC02-05CH11231; AC52-06NA25396

OSTI ID:: 1377540

Alternate ID(s):: OSTI ID: 1407873

Report Number(s):: LA-UR-16-23578; ark:/13030/qt921839xr

Journal Information:: Inorganic Chemistry, Vol. 55, Issue 20; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 26 works

Citation information provided by
Web of Science

References (162)

Compounds in the cerium tetrafluoride-ammonium fluoride-water system Penneman, Robert A.; Rosenzweig, Abraham Inorganic Chemistry, Vol. 8, Issue 3 https://doi.org/10.1021/ic50073a043	journal	March 1969
Crystal structure of ammonium hexafluorocerate(IV), (NH4)2CeF6 Ryan, Robert Reynolds; Larson, Allen C.; Kruse, F. H. Inorganic Chemistry, Vol. 8, Issue 1 https://doi.org/10.1021/ic50071a008	journal	January 1969
The synthesis and structures of complex rare-earth halides Meyer, Gerd Progress in Solid State Chemistry, Vol. 14, Issue 3 https://doi.org/10.1016/0079-6786(82)90005-X	journal	January 1982
Specific intermediate-valence state of insulating 4 f compounds detected by $L_{3}$ x-ray absorption Bianconi, A.; Marcelli, A.; Dexpert, H. Physical Review B, Vol. 35, Issue 2 https://doi.org/10.1103/PhysRevB.35.806	journal	January 1987
Determination of mixing of 4f-ligand orbitals in Ce(SO4)2 by Xanes is Ce(SO4)2 a mixed valent insulating system? Bianconi, A.; Marcelli, A.; Tomellini, M. Journal of Magnetism and Magnetic Materials, Vol. 47-48 https://doi.org/10.1016/0304-8853(85)90396-8	journal	February 1985
Recent Advances in Synthetic Transformations Mediated by Cerium(IV) Ammonium Nitrate Nair, Vijay; Balagopal, Lakshmi; Rajan, Roshini Accounts of Chemical Research, Vol. 37, Issue 1 https://doi.org/10.1021/ar030002z	journal	January 2004
Cerium(IV) Ammonium NitrateA Versatile Single-Electron Oxidant Nair, Vijay; Deepthi, Ani Chemical Reviews, Vol. 107, Issue 5 https://doi.org/10.1021/cr068408n	journal	May 2007
From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates Cross, Justin N.; Duncan, Patrick M.; Villa, Eric M. Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja311910h	journal	February 2013
Theory of core-level spectroscopy of rare-earth oxides Kotani, Akio; Ogasawara, Haruhiko Journal of Electron Spectroscopy and Related Phenomena, Vol. 60, Issue 4 https://doi.org/10.1016/0368-2048(92)80024-3	journal	December 1992
Study of bulk ground state properties of cerium intermetallics by linear dichroism in 4f resonant inelastic X-ray scattering Dallera, C.; Marcon, M.; Ghiringhelli, G. Solid State Communications, Vol. 121, Issue 11 https://doi.org/10.1016/S0038-1098(02)00030-3	journal	March 2002
Localization of screening orbitals, local-environment effects, and intermediate valence in core-level spectroscopy: Ce vs Tm Bianconi, A.; Campagna, M.; Stizza, S. Physical Review B, Vol. 25, Issue 4 https://doi.org/10.1103/PhysRevB.25.2477	journal	February 1982
Experimental evidence for the “shake-down” peak in LIII (and LII)-xanes of light rare earth intermetallics Bianconi, A.; Marcelli, A.; Davoli, I. Solid State Communications, Vol. 49, Issue 5 https://doi.org/10.1016/0038-1098(84)90653-7	journal	February 1984
Anomalous saturation of mixed valence in cerium-based systems as studied by x-ray absorption Parks, R. D.; Raaen, S.; denBoer, M. L. Physical Review B, Vol. 28, Issue 6 https://doi.org/10.1103/PhysRevB.28.3556	journal	September 1983
X-ray absorption studies of ${CeO}_{2}$ , ${PrO}_{2}$ , and ${TbO}_{2}$ . II. Rare-earth valence state by $L_{III}$ absorption edges Dexpert, H.; Karnatak, R. C.; Esteva, J. -M. Physical Review B, Vol. 36, Issue 3 https://doi.org/10.1103/PhysRevB.36.1750	journal	July 1987
Pressure-induced changes in $L_{III}$ x-ray-absorption near-edge structure of Ce $O_{2}$ and Ce $F_{4}$ : Relevance to $4 f$ -electronic structure Kaindl, G.; Schmiester, G.; Sampathkumaran, E. V. Physical Review B, Vol. 38, Issue 14 https://doi.org/10.1103/PhysRevB.38.10174	journal	November 1988
Preparation, crystalline properties and X-ray absorption spectra of rare earth oxides ROx (R ≡ Ce, PrandTb; 1.5 ⩽ x ⩽ 2) Gasgnier, M.; Schiffmacher, G.; Albert, L. Journal of the Less Common Metals, Vol. 156, Issue 1-2 https://doi.org/10.1016/0022-5088(89)90407-4	journal	December 1989
High-energy resonant photoemission and resonant Auger spectroscopy in Ce-Rh compounds Le Fèvre, P.; Magnan, H.; Chandesris, D. Physical Review B, Vol. 58, Issue 3 https://doi.org/10.1103/PhysRevB.58.1080	journal	July 1998
Direct study of the f-electron configuration in lanthanide systems Kvashnina, Kristina O.; Butorin, Sergei M.; Glatzel, Pieter Journal of Analytical Atomic Spectrometry, Vol. 26, Issue 6 https://doi.org/10.1039/c0ja00142b	journal	January 2011
Spectator and participator processes in the resonant photon-in and photon-out spectra at the Ce L3 edge of CeO2 Kotani, A.; Kvashnina, K. O.; Butorin, S. M. The European Physical Journal B, Vol. 85, Issue 8 https://doi.org/10.1140/epjb/e2012-30079-1	journal	July 2012
$f$ -count effects in x-ray-absorption spectra of the $3 d$ levels in Ce and its intermetallic compounds Fuggle, J. C.; Hillebrecht, F. U.; Esteva, J. -M. Physical Review B, Vol. 27, Issue 8 https://doi.org/10.1103/PhysRevB.27.4637	journal	April 1983
M ‐edge x‐ray absorption spectroscopy of 4 f instabilities in rare‐earth systems (invited) Kaindl, G.; Kalkowski, G.; Brewer, W. D. Journal of Applied Physics, Vol. 55, Issue 6 https://doi.org/10.1063/1.333517	journal	March 1984
3d x-ray-absorption lines and the 3 $d^{9}$ 4 $f^{n + 1}$ multiplets of the lanthanides Thole, B. T.; van der Laan, G.; Fuggle, J. C. Physical Review B, Vol. 32, Issue 8 https://doi.org/10.1103/PhysRevB.32.5107	journal	October 1985
Effect of valence mixing on multiplet structure in core photoabsorption spectra for Ce compounds Jo, T.; Kotani, A. Physical Review B, Vol. 38, Issue 1 https://doi.org/10.1103/PhysRevB.38.830	journal	July 1988
Quantitative electron energy loss spectroscopy on M45 edges in rare earth oxides Manoubi, T.; Colliex, C.; Rez, P. Journal of Electron Spectroscopy and Related Phenomena, Vol. 50, Issue 1 https://doi.org/10.1016/0368-2048(90)80001-Q	journal	January 1990
A cerium M-edge X-ray absorption study of the CeM2 compounds, where M is Mg, Al, Fe, Co, Ni, Ru and Rh Grandjean, F.; Waddill, G. D.; Cummins, T. R. Solid State Communications, Vol. 108, Issue 8 https://doi.org/10.1016/S0038-1098(98)00404-9	journal	October 1998
L ₃ and M _4,5 absorption edges of intermediate valent cerium unravelled by resonant photoemission and resonant Auger spectroscopy Le Fèvre, P.; Magnan, H.; Vogel, J. Journal of Synchrotron Radiation, Vol. 6, Issue 3 https://doi.org/10.1107/S090904959801704X	journal	May 1999
Electronic structure and valence state of CeAl2 from X-ray absorption and emission spectroscopy Dong, C. L.; Augustsson, A.; Chen, C. L. Journal of Electron Spectroscopy and Related Phenomena, Vol. 144-147 https://doi.org/10.1016/j.elspec.2005.01.177	journal	June 2005
X-ray absorption at the oxygen K edge in cubic f oxides examined using a full multiple-scattering approach Wu, Z. Y.; Jollet, F.; Gota, S. Journal of Physics: Condensed Matter, Vol. 11, Issue 37 https://doi.org/10.1088/0953-8984/11/37/314	journal	September 1999
Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy Altman, Alison B.; Pacold, Joseph I.; Wang, Jian Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00358C	journal	January 2016
Spectroscopic Evidence for Localized and Extended $f$ -Symmetry States in Ce $O_{2}$ Wuilloud, E.; Delley, B.; Schneider, W. -D. Physical Review Letters, Vol. 53, Issue 2 https://doi.org/10.1103/PhysRevLett.53.202	journal	July 1984
Many-body effects in core-level spectroscopy of rare-earth compounds Kotani, A.; Jo, T.; Parlebas, J. C. Advances in Physics, Vol. 37, Issue 1 https://doi.org/10.1080/00018738800101359	journal	February 1988
Resonant inelastic x-ray scattering at the Ce $L_{3}$ edge of ${CePO}_{4}$ and ${CeO}_{2}$ : Implications for the valence of ${CeO}_{2}$ and related phenomena Sham, T. K.; Gordon, R. A.; Heald, S. M. Physical Review B, Vol. 72, Issue 3 https://doi.org/10.1103/PhysRevB.72.035113	journal	July 2005
CORE-HOLE EFFECT IN THE Ce L ₃ X-RAY ABSORPTION SPECTRA OF CeO ₂ AND CeFe ₂ : NEW EXAMINATION BY USING RESONANT X-RAY EMISSION SPECTROSCOPY Kotani, A. Modern Physics Letters B, Vol. 27, Issue 16 https://doi.org/10.1142/S0217984913300123	journal	June 2013
Understanding the valency of rare earths from first-principles theory Strange, P.; Svane, A.; Temmerman, W. M. Nature, Vol. 399, Issue 6738 https://doi.org/10.1038/21595	journal	June 1999
Electronic, bonding, and optical properties of ${CeO}_{2}$ and ${Ce}_{2} O_{3}$ from first principles Skorodumova, N. V.; Ahuja, R.; Simak, S. I. Physical Review B, Vol. 64, Issue 11 https://doi.org/10.1103/PhysRevB.64.115108	journal	August 2001
First-principles study of rare-earth oxides Petit, L.; Svane, A.; Szotek, Z. Physical Review B, Vol. 72, Issue 20 https://doi.org/10.1103/PhysRevB.72.205118	journal	November 2005
Theoretical study of CeO2 and Ce2O3 using a screened hybrid density functional Hay, P. Jeffrey; Martin, Richard L.; Uddin, Jamal The Journal of Chemical Physics, Vol. 125, Issue 3 https://doi.org/10.1063/1.2206184	journal	July 2006
Modeling of $Ce O_{2}$ , ${Ce}_{2} O_{3}$ , and $Ce O_{2 - x}$ in the $LDA + U$ formalism Andersson, D. A.; Simak, S. I.; Johansson, B. Physical Review B, Vol. 75, Issue 3 https://doi.org/10.1103/PhysRevB.75.035109	journal	January 2007
First-principles $LDA + U$ and $GGA + U$ study of cerium oxides: Dependence on the effective U parameter Loschen, Christoph; Carrasco, Javier; Neyman, Konstantin M. Physical Review B, Vol. 75, Issue 3 https://doi.org/10.1103/PhysRevB.75.035115	journal	January 2007
Localized and Itinerant States in Lanthanide Oxides United by $G W @ LDA + U$ Jiang, Hong; Gomez-Abal, Ricardo I.; Rinke, Patrick Physical Review Letters, Vol. 102, Issue 12 https://doi.org/10.1103/PhysRevLett.102.126403	journal	March 2009
B3LYP calculations of cerium oxides Kullgren, Jolla; Castleton, Christopher W. M.; Müller, Carsten The Journal of Chemical Physics, Vol. 132, Issue 5 https://doi.org/10.1063/1.3253795	journal	February 2010
Nature of the electronic band gap in lanthanide oxides Gillen, Roland; Clark, Stewart J.; Robertson, John Physical Review B, Vol. 87, Issue 12 https://doi.org/10.1103/PhysRevB.87.125116	journal	March 2013
Localized Magnetic States in Metals Anderson, P. W. Physical Review, Vol. 124, Issue 1 https://doi.org/10.1103/PhysRev.124.41	journal	October 1961
Disorder effects on Kondo behavior in CePt2+x Chen, Y. Y.; Huang, P. H.; Booth, C. H. Physica B: Condensed Matter, Vol. 378-380 https://doi.org/10.1016/j.physb.2006.01.479	journal	May 2006
Q -dependence of the spin fluctuations in the intermediate valence compound CePd ₃ Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A. Journal of Physics: Condensed Matter, Vol. 26, Issue 22 https://doi.org/10.1088/0953-8984/26/22/225602	journal	May 2014
Lattice disorder and magnetism in f-electron intermetallics Booth, C. H.; Han, S. -W.; Skanthakumar, S. Physica B: Condensed Matter, Vol. 354, Issue 1-4 https://doi.org/10.1016/j.physb.2004.09.088	journal	December 2004
X-ray absorption studies of the local structure and $f$ -level occupancy in ${CeIr}_{1 - x} {Rh}_{x} {In}_{5}$ Daniel, M.; Han, S. -W.; Booth, C. H. Physical Review B, Vol. 71, Issue 5 https://doi.org/10.1103/PhysRevB.71.054417	journal	February 2005
Local structure and site occupancy of Cd and Hg substitutions in $Ce T {In}_{5}$ ( $T = Co$ , Rh, and Ir) Booth, C. H.; Bauer, E. D.; Bianchi, A. D. Physical Review B, Vol. 79, Issue 14 https://doi.org/10.1103/PhysRevB.79.144519	journal	April 2009
Electronic structure and $f$ -orbital occupancy in Yb-substituted CeCoIn $_{5}$ Booth, C. H.; Durakiewicz, T.; Capan, C. Physical Review B, Vol. 83, Issue 23 https://doi.org/10.1103/PhysRevB.83.235117	journal	June 2011
Heavy-fermion superconductivity in CeCoIn ₅ at 2.3 K Petrovic, C.; Pagliuso, P. G.; Hundley, M. F. Journal of Physics: Condensed Matter, Vol. 13, Issue 17 https://doi.org/10.1088/0953-8984/13/17/103	journal	April 2001
The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis Piro, Nicholas A.; Robinson, Jerome R.; Walsh, Patrick J. Coordination Chemistry Reviews, Vol. 260 https://doi.org/10.1016/j.ccr.2013.08.034	journal	February 2014
Aspects of non-classical organolanthanide chemistry Cristina Cassani, M.; Gun'ko, Yurii K.; Hitchcock, Peter B. Journal of Organometallic Chemistry, Vol. 647, Issue 1-2 https://doi.org/10.1016/S0022-328X(01)01484-X	journal	March 2002
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl ₆ ^{x –} ( x = 3, 2) Löble, Matthias W.; Keith, Jason M.; Altman, Alison B. Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja510067v	journal	February 2015
439. Structural chemistry of the alkoxides. Part VI. Primary alkoxides of quadrivalent cerium and thorium Bradley, D. C.; Chatterjee, A. K.; Wardlaw, W. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9560002260	journal	January 1956
671. Structural chemistry of the alkoxides. Part VII. Secondary alkoxides of quadrivalent cerium and thorium Bradley, D. C.; Chatterjee, A. K.; Wardlaw, W. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9560003469	journal	January 1956
Efficient synthesis, redox characteristics, and electronic structure of a tetravalent tris(cyclopentadienyl)cerium alkoxide complex Gulino, Antonino.; Casarin, Maurizio.; Conticello, Vincent P. Organometallics, Vol. 7, Issue 11 https://doi.org/10.1021/om00101a016	journal	November 1988
Synthetic and structural studies of a series of soluble cerium(IV) alkoxide and alkoxide nitrate complexes Evans, William J.; Deming, Timothy J.; Olofson, Jeffrey M. Inorganic Chemistry, Vol. 28, Issue 21 https://doi.org/10.1021/ic00320a018	journal	October 1989
The utility of ceric ammonium nitrate-derived alkoxide complexes in the synthesis of organometallic cerium(IV) complexes. Synthesis and first x-ray crystallographic determination of a tetravalent cerium cyclopentadienide complex, (C5H5)3Ce(OCMe3) Evans, William J.; Deming, Timothy J.; Ziller, Joseph W. Organometallics, Vol. 8, Issue 6 https://doi.org/10.1021/om00108a042	journal	June 1989
Synthesis, structure, and reactivity of homoleptic cerium(IV) and cerium(III) alkoxides Sen, Ayusman; Stecher, Hilmar A.; Rheingold, Arnold L. Inorganic Chemistry, Vol. 31, Issue 3 https://doi.org/10.1021/ic00029a025	journal	February 1992
The First CeIV Metallasilsesquioxane Complex: [Ce{(c-C6H11)8Si8O13}2(py)3] Gun'ko, Yurii K.; Reilly, Roisin; Edelmann, Frank T. Angewandte Chemie International Edition, Vol. 40, Issue 7 https://doi.org/10.1002/1521-3773(20010401)40:7<1279::AID-ANIE1279>3.0.CO;2-2	journal	April 2001
Variation of electronic transitions and reduction potentials of cerium( iv ) complexes Williams, Ursula J.; Schneider, David; Dorfner, Walter L. Dalton Trans., Vol. 43, Issue 43 https://doi.org/10.1039/C4DT01386G	journal	January 2014
Synthesis and Analysis of a Family of Cerium(IV) Halide and Pseudohalide Compounds Williams, Ursula J.; Carroll, Patrick J.; Schelter, Eric J. Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic500969r	journal	May 2014
Synthesis, Bonding, and Reactivity of a Cerium(IV) Fluoride Complex Williams, Ursula J.; Robinson, Jerome R.; Lewis, Andrew J. Inorganic Chemistry, Vol. 53, Issue 1 https://doi.org/10.1021/ic402769u	journal	December 2013
Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O Behrsing, Thomas; Bond, Alan M.; Deacon, Glen B. Inorganica Chimica Acta, Vol. 352 https://doi.org/10.1016/S0020-1693(03)00147-6	journal	August 2003
Synthesis, Structure, and Reactivity of Cerium(IV) Calix[4]arene Complexes Gottfriedsen, Jochen; Hagner, Reimo; Spoida, Marlies European Journal of Inorganic Chemistry, Vol. 2007, Issue 16 https://doi.org/10.1002/ejic.200601004	journal	June 2007
Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents Dröse, Peter; Crozier, Alan R.; Lashkari, Samira Journal of the American Chemical Society, Vol. 132, Issue 40 https://doi.org/10.1021/ja107494h	journal	October 2010
X-ray crystal structure of the tetra(tert-butyl)erbate anion and attempts to prepare tetravalent organolanthanide complexes Noh, Wontae; Girolami, Gregory S. Polyhedron, Vol. 26, Issue 14 https://doi.org/10.1016/j.poly.2007.04.006	journal	August 2007
Bis(permethylpentalene)cerium ? another ambiguity in lanthanide oxidation state Ashley, Andrew; Balazs, Gabor; Cowley, Andrew Chemical Communications, Issue 15 https://doi.org/10.1039/b700303j	journal	January 2007
Cerium masquerading as a Group 4 element: synthesis, structure and computational characterisation of [CeCl{N(SiMe3)2}3] Eisenstein, Odile; Hitchcock, Peter B.; Hulkes, Alexander G. Chemical Communications, Issue 17 https://doi.org/10.1039/b103634n	journal	January 2001
Oxidation in Nonclassical Organolanthanide Chemistry: Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F. Inorganic Chemistry, Vol. 43, Issue 3 https://doi.org/10.1021/ic035100v	journal	February 2004
Facile formation of a homoleptic Ce(iv) amide via aerobic oxidation Hitchcock, Peter B.; Lappert, Michael F.; Protchenko, Andrey V. Chemical Communications, Issue 33 https://doi.org/10.1039/b607429d	journal	January 2006
Crystalline amidocerium(iv) oxides and a side-on bridging dioxygen complex Coles, Martyn P.; Hitchcock, Peter B.; Khvostov, Alexei V. Dalton Transactions, Vol. 39, Issue 29 https://doi.org/10.1039/c0dt00349b	journal	January 2010
A homoleptic tetravalent cerium silylamide Crozier, Alan R.; Bienfait, Andre M.; Maichle-Mössmer, Cäcilia Chem. Commun., Vol. 49, Issue 1 https://doi.org/10.1039/C2CC37404H	journal	January 2013
Cerium tetrakis(diisopropylamide) – a useful precursor for cerium( iv ) chemistry Schneider, David; Spallek, Tatiana; Maichle-Mössmer, Cäcilia Chem. Commun., Vol. 50, Issue 94 https://doi.org/10.1039/C4CC06228K	journal	January 2014
Metal complexes with tetrapyrrole ligands. 40. Cerium(IV) bis(octaethylporphyrinate) and dicerium(III) tris(octaethylporphyrinate): Parents of a new family of lanthanoid double-decker and triple-decker molecules Buchler, Johann W.; De Cian, Andre.; Fischer, Jean. Journal of the American Chemical Society, Vol. 108, Issue 13 https://doi.org/10.1021/ja00273a018	journal	June 1986
Metal complexes with tetrapyrrole ligands, LIV: Synthesis, spectra, structure, and redox properties of cerium(IV) Bisporphyrinates with identical and different porphyrin rings in the sandwich system Buchler, Johann W.; De Cian, André; Fischer, Jean Chemische Berichte, Vol. 122, Issue 12 https://doi.org/10.1002/cber.19891221203	journal	December 1989
Strong Positive Allosterism which Appears in Molecular Recognition with Cerium(IV) Double Decker Porphyrins: Correlation between the Number of Binding Sites and Hill Coefficients Ikeda, Masato; Takeuchi, Masayuki; Sugasaki, Atsushi Supramolecular Chemistry, Vol. 12, Issue 3 https://doi.org/10.1080/10610270008029453	journal	November 2000
Tuning the Valence of the Cerium Center in (Na)phthalocyaninato and Porphyrinato Cerium Double-Deckers by Changing the Nature of the Tetrapyrrole Ligands Bian, Yongzhong; Jiang, Jianzhuang; Tao, Ye Journal of the American Chemical Society, Vol. 125, Issue 40 https://doi.org/10.1021/ja036017+	journal	September 2003
Synthesis and magnetic properties of cerium macrocyclic complexes with tetramethyldibenzotetraaza[14]annulene, tmtaaH2 Walter, Marc D.; Fandos, Rosa; Andersen, Richard A. New Journal of Chemistry, Vol. 30, Issue 7 https://doi.org/10.1039/b602644c	journal	January 2006
Single Crystal to Single Crystal Transformation and Hydrogen-Atom Transfer upon Oxidation of a Cerium Coordination Compound Williams, Ursula J.; Mahoney, Brian D.; Lewis, Andrew J. Inorganic Chemistry, Vol. 52, Issue 8 https://doi.org/10.1021/ic4001973	journal	March 2013
Cerium(III/IV) Formamidinate Chemistry, and a Stable Cerium(IV) Diolate Werner, Daniel; Deacon, Glen B.; Junk, Peter C. Chemistry - A European Journal, Vol. 20, Issue 15 https://doi.org/10.1002/chem.201304582	journal	March 2014
Homoleptic Cerium(III) and Cerium(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A. Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401974t	journal	September 2013
Synthesis, Electrochemistry, and Reactivity of Cerium(III/IV) Methylene-Bis-Phenolate Complexes Mahoney, Brian D.; Piro, Nicholas A.; Carroll, Patrick J. Inorganic Chemistry, Vol. 52, Issue 10 https://doi.org/10.1021/ic400202r	journal	April 2013
A homoleptic η2 hydroxylaminato CeIV complex with S4 symmetry Dorfner, Walter L.; Carroll, Patrick J.; Schelter, Eric J. Dalton Transactions, Vol. 43, Issue 17 https://doi.org/10.1039/c4dt00287c	journal	January 2014
Structural and electrochemical characterization of a cerium( iv ) hydroxamate complex: implications for the beneficiation of light rare earth ores Lee, Heui Beom; Bogart, Justin A.; Carroll, Patrick J. Chem. Commun., Vol. 50, Issue 40 https://doi.org/10.1039/C3CC46486E	journal	January 2014
Bidentate nitroxide ligands stable toward oxidative redox cycling and their complexes with cerium and lanthanum Kim, Jee Eon; Carroll, Patrick J.; Schelter, Eric J. Chemical Communications, Vol. 51, Issue 81 https://doi.org/10.1039/C5CC06052D	journal	January 2015
Lanthanide complexes with cyclooctatetraene di-anion Mares, F.; Hodgson, K.; Streitwieser, A. Journal of Organometallic Chemistry, Vol. 24, Issue 3 https://doi.org/10.1016/S0022-328X(00)84477-0	journal	October 1970
New 7r-cyclooctate'I'raenyl and iT-cyclopentadienyl complexes of cerium Greco, Alberto; Cesca, Sebastiano; Bertolini, Wiglielmo Journal of Organometallic Chemistry, Vol. 113, Issue 4 https://doi.org/10.1016/S0022-328X(00)96143-6	journal	July 1976
Luminescence spectra of a series of cerium(III) halides and organometallics. Probes of bonding properties using 4f-5d excited states Hazin, Paulette N.; Bruno, Joseph W.; Brittain, Harry G. Organometallics, Vol. 6, Issue 5 https://doi.org/10.1021/om00148a002	journal	May 1987
Ground state calculations of di‐π‐cyclooctatetraene cerium Dolg, Michael; Fulde, Peter; Küchle, Wolfgang The Journal of Chemical Physics, Vol. 94, Issue 4 https://doi.org/10.1063/1.459824	journal	February 1991
Electronic structure of f1 lanthanide and actinide complexes. Part 2. Non-relativistic and relativistic calculations of the ground state electronic structures and optical transition energies of [Ce(η-C5H5)3], [Th(η-C5H5)3] and [Pa(η-C8H8)2] Kaltsoyannis, Nikolas; Bursten, Bruce E. Journal of Organometallic Chemistry, Vol. 528, Issue 1-2 https://doi.org/10.1016/S0022-328X(96)06406-6	journal	February 1997
Self-Contained Kondo Effect in Single Molecules Booth, C. H.; Walter, M. D.; Daniel, M. Physical Review Letters, Vol. 95, Issue 26 https://doi.org/10.1103/PhysRevLett.95.267202	journal	December 2005
Cerocene Revisited: The Electronic Structure of and Interconversion Between Ce ₂ (C ₈ H ₈ ) ₃ and Ce(C ₈ H ₈ ) ₂ Walter, Marc D.; Booth, Corwin H.; Lukens, Wayne W. Organometallics, Vol. 28, Issue 3 https://doi.org/10.1021/om7012327	journal	February 2009
Is Cerocene Really a Ce(III) Compound? All-Electron Spin−Orbit Coupled CASPT2 Calculations on M(η ⁸ -C ₈ H ₈ ) ₂ (M = Th, Pa, Ce) Kerridge, Andrew; Coates, Rosemary; Kaltsoyannis, Nikolas The Journal of Physical Chemistry A, Vol. 113, Issue 12 https://doi.org/10.1021/jp807804w	journal	March 2009
Oxidation state and covalency in f-element metallocenes (M = Ce, Th, Pu): a combined CASSCF and topological study Kerridge, Andrew Dalton Transactions, Vol. 42, Issue 46 https://doi.org/10.1039/c3dt52279b	journal	January 2013
Two interpretations of the cerocene electronic ground state Mooßen, Oliver; Dolg, Michael Chemical Physics Letters, Vol. 594 https://doi.org/10.1016/j.cplett.2014.01.022	journal	February 2014
Structural and magnetic conformation of a cerocene [Ce(COT′′) ₂ ] ⁻ exhibiting a uniconfigurational f ¹ ground state and slow-magnetic relaxation Le Roy, Jennifer J.; Korobkov, Ilia; Kim, Jee Eon Dalton Trans., Vol. 43, Issue 7 https://doi.org/10.1039/C3DT53280A	journal	January 2014
Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H. Journal of the American Chemical Society, Vol. 135, Issue 50 https://doi.org/10.1021/ja410688w	journal	December 2013
A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic503000z	journal	February 2015
Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework Bogart, Justin A.; Lippincott, Connor A.; Carroll, Patrick J. Chemistry - A European Journal, Vol. 21, Issue 49 https://doi.org/10.1002/chem.201502952	journal	October 2015
The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry Robinson, Jerome R.; Carroll, Patrick J.; Walsh, Patrick J. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201203481	journal	August 2012
DFT Study of the Active Site of the XoxF-Type Natural, Cerium-Dependent Methanol Dehydrogenase Enzyme Bogart, Justin A.; Lewis, Andrew J.; Schelter, Eric J. Chemistry - A European Journal, Vol. 21, Issue 4 https://doi.org/10.1002/chem.201405159	journal	November 2014
Ligand Effects in the Synthesis of Ln ²⁺ Complexes by Reduction of Tris(cyclopentadienyl) Precursors Including C–H Bond Activation of an Indenyl Anion Corbey, Jordan F.; Woen, David H.; Palumbo, Chad T. Organometallics, Vol. 34, Issue 15 https://doi.org/10.1021/acs.organomet.5b00500	journal	May 2015
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln ²⁺ Ions in the [K(2.2.2-cryptand)][(C ₅ H ₄ SiMe ₃ ) ₃ Ln] Complexes: The Variable Nature of Dy ²⁺ and Nd ²⁺ Fieser, Megan E.; MacDonald, Matthew R.; Krull, Brandon T. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja510831n	journal	December 2014
Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II) MacDonald, Matthew R.; Bates, Jefferson E.; Fieser, Megan E. Journal of the American Chemical Society, Vol. 134, Issue 20 https://doi.org/10.1021/ja303357w	journal	May 2012
Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr ²⁺ , Gd ²⁺ , Tb ²⁺ , and Lu ²⁺ MacDonald, Matthew R.; Bates, Jefferson E.; Ziller, Joseph W. Journal of the American Chemical Society, Vol. 135, Issue 26 https://doi.org/10.1021/ja403753j	journal	May 2013
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C ₅ H ₄ SiMe ₃ ) ₃ U] MacDonald, Matthew R.; Fieser, Megan E.; Bates, Jefferson E. Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja406791t	journal	August 2013
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding La Pierre, Henry S.; Scheurer, Andreas; Heinemann, Frank W. Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201402050	journal	May 2014
A Macrocyclic Chelator with Unprecedented Th ⁴⁺ Affinity Pham, Tiffany A.; Xu, Jide; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja503456r	journal	June 2014
Development of Decorporation Agents for the Actinides Durbin, P. W.; Kullgren, B.; Xu, J. Radiation Protection Dosimetry, Vol. 79, Issue 1 https://doi.org/10.1093/oxfordjournals.rpd.a032445	journal	October 1998
Rational Design of Sequestering Agents for Plutonium and Other Actinides Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N. Chemical Reviews, Vol. 103, Issue 11 https://doi.org/10.1021/cr990114x	journal	November 2003
3,4,3-LI(1,2-HOPO): In vitro formation of highly stable lanthanide complexes translates into efficacious in vivo europium decorporation Sturzbecher-Hoehne, Manuel; Ng Pak Leung, Clara; D'Aléo, Anthony Dalton Transactions, Vol. 40, Issue 33 https://doi.org/10.1039/c1dt10840a	journal	January 2011
An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides ¹ Diamond, R. M.; Street, K.; Seaborg, G. T. Journal of the American Chemical Society, Vol. 76, Issue 6 https://doi.org/10.1021/ja01635a001	journal	March 1954
Comparison of the solution chemistry of the actinides and lanthanides Choppin, Gregory R. Journal of the Less Common Metals, Vol. 93, Issue 2 https://doi.org/10.1016/0022-5088(83)90177-7	journal	September 1983
Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes¹ Xu, Jide; Radkov, Emil; Ziegler, Marco Inorganic Chemistry, Vol. 39, Issue 18, p. 4156-4164 https://doi.org/10.1021/ic000063i	journal	September 2000
On the Suitability of Lanthanides as Actinide Analogs Raymond, Kenneth; Szigethy, Geza MRS Proceedings, Vol. 1104 https://doi.org/10.1557/PROC-1104-NN04-01	journal	January 2008
Characterization of a Mixed Salt of 1-Hydroxypyridin-2-one Pu(IV) Complexes ¹ Gorden, Anne E. V.; Xu, Jide; Szigethy, Géza Journal of the American Chemical Society, Vol. 129, Issue 21 https://doi.org/10.1021/ja070168l	journal	May 2007
Surprising Coordination Geometry Differences in CeIV- and PuIV-Maltol Complexes Szigethy, Géza; Xu, Jide; Gorden, Anne E. V. European Journal of Inorganic Chemistry, Vol. 2008, Issue 13 https://doi.org/10.1002/ejic.200800144	journal	May 2008
Lanthanides and actinides among other groups of elements of the periodic table Mikheev, N. B.; Kulyukhin, S. A.; Melikhov, I. V. Radiochemistry, Vol. 49, Issue 5 https://doi.org/10.1134/S1066362207050025	journal	October 2007
Hydroxypyridinonate Complex Stability of Group (IV) Metals and Tetravalent f-Block Elements: The Key to the Next Generation of Chelating Agents for Radiopharmaceuticals Sturzbecher-Hoehne, Manuel; Choi, Taylor A.; Abergel, Rebecca J. Inorganic Chemistry, Vol. 54, Issue 7 https://doi.org/10.1021/acs.inorgchem.5b00033	journal	March 2015
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
WinGX suite for small-molecule single-crystal crystallography Farrugia, Louis J. Journal of Applied Crystallography, Vol. 32, Issue 4 https://doi.org/10.1107/S0021889899006020	journal	August 1999
Experimental and Theoretical Comparison of the O K-Edge Nonresonant Inelastic X-ray Scattering and X-ray Absorption Spectra of NaReO ₄ Bradley, Joseph A.; Yang, Ping; Batista, Enrique R. Journal of the American Chemical Society, Vol. 132, Issue 39 https://doi.org/10.1021/ja1040978	journal	October 2010
Uranium oxides investigated by X-ray absorption and emission spectroscopies Magnuson, M.; Butorin, S. M.; Werme, L. Applied Surface Science, Vol. 252, Issue 15 https://doi.org/10.1016/j.apsusc.2005.12.131	journal	May 2006
Covalency in Metal–Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 135, Issue 5 https://doi.org/10.1021/ja310223b	journal	January 2013
Influence of Pyrazolate vs N -Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes Meihaus, Katie R.; Minasian, Stefan G.; Lukens, Wayne W. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja501569t	journal	April 2014
Soft X-ray spectromicroscopy beamline at the CLS: Commissioning results Kaznatcheev, K. V.; Karunakaran, Ch.; Lanke, U. D. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 582, Issue 1 https://doi.org/10.1016/j.nima.2007.08.083	journal	November 2007
Soft X-ray microscopy and spectroscopy at the molecular environmental science beamline at the Advanced Light Source Bluhm, H.; Andersson, K.; Araki, T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 150, Issue 2-3 https://doi.org/10.1016/j.elspec.2005.07.005	journal	February 2006
Soft X-ray scanning transmission X-ray microscopy (STXM) of actinide particles Nilsson, Hans J.; Tyliszczak, Tolek; Wilson, Richard E. Analytical and Bioanalytical Chemistry, Vol. 383, Issue 1 https://doi.org/10.1007/s00216-005-3355-5	journal	July 2005
Total and partial atomic-level widths Keski-Rahkonen, Olavi; Krause, Manfred O. Atomic Data and Nuclear Data Tables, Vol. 14, Issue 2 https://doi.org/10.1016/S0092-640X(74)80020-3	journal	August 1974
The Theory of Atomic Structure and Spectra Cowan, Robert D. Los Alamos Series in Basic and Applied Sciences, Vol. 3 https://doi.org/10.1525/9780520906150	book	December 1981
Core Level Spectroscopy of Solids de Groot, Frank; Kotani, Akio CRC Press https://doi.org/10.1201/9781420008425	book	January 2008
GLEE, a new computer program for glass electrode calibration Gans, P. Talanta, Vol. 51, Issue 1 https://doi.org/10.1016/S0039-9140(99)00245-3	journal	January 2000
Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs Gans, P.; Sabatini, A.; Vacca, A. Talanta, Vol. 43, Issue 10 https://doi.org/10.1016/0039-9140(96)01958-3	journal	October 1996
Redox behavior of Ce(IV)/Ce(III) in the presence of nitrilotriacetic acid: A surrogate study for An(IV)/An(III) redox behavior Suzuki, Yoshinori; Nankawa, T.; Francis, Arokiasamy J. Radiochimica Acta, Vol. 98, Issue 7 https://doi.org/10.1524/ract.2010.1735	journal	January 2010
Hyperquad simulation and speciation (HySS): a utility program for the investigation of equilibria involving soluble and partially soluble species Alderighi, Lucia; Gans, Peter; Ienco, Andrea Coordination Chemistry Reviews, Vol. 184, Issue 1 https://doi.org/10.1016/S0010-8545(98)00260-4	journal	April 1999
ORTEP -3 for Windows - a version of ORTEP -III with a Graphical User Interface (GUI) Farrugia, L. J. Journal of Applied Crystallography, Vol. 30, Issue 5 https://doi.org/10.1107/S0021889897003117	journal	October 1997
Solution Thermodynamic Stability of Complexes Formed with the Octadentate Hydroxypyridinonate Ligand 3,4,3-LI(1,2-HOPO): A Critical Feature for Efficient Chelation of Lanthanide(IV) and Actinide(IV) Ions Deblonde, Gauthier J-P.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J. Inorganic Chemistry, Vol. 52, Issue 15 https://doi.org/10.1021/ic4010246	journal	July 2013
Toward Optimized High-Relaxivity MRI Agents: The Effect of Ligand Basicity on the Thermodynamic Stability of Hexadentate Hydroxypyridonate/Catecholate Gadolinium(III) Complexes Doble, Dan M. J.; Melchior, Marco; O'Sullivan, Brendon Inorganic Chemistry, Vol. 42, Issue 16, p. 4930-4937 https://doi.org/10.1021/ic026240s	journal	August 2003
Rare earth valence in ROx (R  Ce, Pr, Tb; 1.5 ⩽ x ⩽ 2) studied by x-ray absorption spectroscopy Karnatak, R. C. Journal of Alloys and Compounds, Vol. 192, Issue 1-2 https://doi.org/10.1016/0925-8388(93)90187-R	journal	February 1993
A new method of directly determining the core–hole effect in the Ce L3 XAS of mixed valence Ce compounds—An application of resonant X-ray emission spectroscopy Kotani, A.; Kvashnina, K. O.; Butorin, S. M. Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6 https://doi.org/10.1016/j.elspec.2010.12.028	journal	April 2011
Ln-4f/ligand-2p covalence in BaLnO3 and Cs3LnF7 (Ln=Ce, Pr, Tb) Hu, Z.; Kaindl, G.; Ogasawara, H. Chemical Physics Letters, Vol. 325, Issue 1-3 https://doi.org/10.1016/S0009-2614(00)00656-4	journal	July 2000
Narrowing Due to Valence Mixing in the 3d Core Level Spectra for Ce Compounds Jo, Takeo; Kotani, Akio Journal of the Physical Society of Japan, Vol. 57, Issue 7 https://doi.org/10.1143/JPSJ.57.2288	journal	July 1988
The CTM4XAS program for EELS and XAS spectral shape analysis of transition metal L edges Stavitski, Eli; de Groot, Frank M. F. Micron, Vol. 41, Issue 7 https://doi.org/10.1016/j.micron.2010.06.005	journal	October 2010
Multiplet effects in X-ray spectroscopy Groot, Frank de Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.03.018	journal	January 2005
Electronic structure of nanoporous ceria from x-ray absorption spectroscopy and atomic multiplet calculations Kucheyev, S. O.; Clapsaddle, B. J.; Wang, Y. M. Physical Review B, Vol. 76, Issue 23 https://doi.org/10.1103/PhysRevB.76.235420	journal	December 2007
High resolution mapping of surface reduction in ceria nanoparticles Turner, Stuart; Lazar, Sorin; Freitag, Bert Nanoscale, Vol. 3, Issue 8 https://doi.org/10.1039/c1nr10510h	journal	January 2011
Formally tetravalent cerium and thorium compounds: a configuration interaction study of cerocene Ce(C8H8)2 and thorocene Th(C8H8)2 using energy-adjusted quasirelativistic ab initio pseudopotentials Dolg, M.; Fulde, P.; Stoll, H. Chemical Physics, Vol. 195, Issue 1-3 https://doi.org/10.1016/0301-0104(94)00363-F	journal	June 1995
Crystal and molecular structures of tetrakis(catecholato)hafnate(IV) and -cerate(IV). Further evidence for a ligand field effect in the structure of tetrakis(catecholato)uranate(IV) Sofen, Stephen R.; Cooper, Stephen R.; Raymond, Kenneth N. Inorganic Chemistry, Vol. 18, Issue 6 https://doi.org/10.1021/ic50196a046	journal	June 1979
The structure and properties of tetrakis(tironato)cerate(IV), Na12[Ce(C6H2O2(SO3)2)4]·9H2O·6C3H7NO Haddad, Salim F.; Raymond, Kenneth N. Inorganica Chimica Acta, Vol. 122, Issue 1 https://doi.org/10.1016/S0020-1693(00)81277-3	journal	December 1986
Electrochemical studies of cerium chelate complexes Wester, Dennis W.; Palenik, Gus J.; Palenik, Ruth C. Inorganic Chemistry, Vol. 24, Issue 25 https://doi.org/10.1021/ic00219a051	journal	December 1985
Present Status of Cerium(IV)-Cerium(III) Potentials Wadsworth, Earl.; Duke, F. R.; Goetz, C. A. Analytical Chemistry, Vol. 29, Issue 12 https://doi.org/10.1021/ac60132a046	journal	December 1957
Aqueous Complexation of Thorium(IV), Uranium(IV), Neptunium(IV), Plutonium(III/IV), and Cerium(III/IV) with DTPA Brown, M. Alex; Paulenova, Alena; Gelis, Artem V. Inorganic Chemistry, Vol. 51, Issue 14 https://doi.org/10.1021/ic300757k	journal	April 2012
Enthalpy formation of americium dioxide and a thermochemical estimate of the electrode potential Am4+/Am3+ Morss, L. R.; Fuger, J. Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 9 https://doi.org/10.1016/0022-1902(81)80548-9	journal	January 1981
Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl ₆ ^2– (M = Ti, Zr, Hf, U) and UOCl ₅ ^– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja2105015	journal	March 2012
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning Kaltsoyannis, Nikolas Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic3006025	journal	June 2012
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
Spectrum analysis of U 3+ :LaCl 3 Crosswhite, H. M.; Crosswhite, H.; Carnall, W. T. The Journal of Chemical Physics, Vol. 72, Issue 9 https://doi.org/10.1063/1.439742	journal	May 1980
Effective core potential methods for the lanthanides Cundari, Thomas R.; Stevens, Walter J. The Journal of Chemical Physics, Vol. 98, Issue 7 https://doi.org/10.1063/1.464902	journal	April 1993
Comparative studies of quasi-relativistic density functional methods for the description of lanthanide and actinide complexes Vetere, Valentina; Maldivi, Pascale; Adamo, Carlo Journal of Computational Chemistry, Vol. 24, Issue 7 https://doi.org/10.1002/jcc.10228	journal	May 2003
Ground States, Excited States, and Metal−Ligand Bonding in Rare Earth Hexachloro Complexes: A DFT-Based Ligand Field Study Atanasov, M.; Daul, C.; Güdel, H. U. Inorganic Chemistry, Vol. 44, Issue 8 https://doi.org/10.1021/ic040105t	journal	April 2005

Cited By (5)

Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium Friedrich, Jochen; Qiao, Yusen; Maichle-Mössmer, Cäcilia Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt01878b	journal	January 2018
Reactions of cerium complexes with transition metal nitrides: synthesis and structure of heterometallic cerium complexes containing bridging catecholate ligands Cheung, Wai-Man; Au-Yeung, Ka-Chun; Wong, Kai-Hong Dalton Transactions, Vol. 48, Issue 35 https://doi.org/10.1039/c9dt02959a	journal	January 2019
Ultra-selective ligand-driven separation of strategic actinides Deblonde, Gauthier J. -P.; Ricano, Abel; Abergel, Rebecca J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10240-x	journal	June 2019
Stabilization of the Oxidation State +IV in Siloxide‐Supported Terbium Compounds Willauer, Aurélien R.; Palumbo, Chad T.; Scopelliti, Rosario Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201914733	journal	February 2020
Stabilization of the Oxidation State +IV in Siloxide‐Supported Terbium Compounds Willauer, Aurélien R.; Palumbo, Chad T.; Scopelliti, Rosario Angewandte Chemie, Vol. 132, Issue 9 https://doi.org/10.1002/ange.201914733	journal	January 2020

Similar Records

Chelating Rare-Earth Metals (Ln³⁺) and ²²⁵Ac³⁺ with the Dual-Size-Selective Macrocyclic Ligand Py₂-Macrodipa

Journal Article · Mon Aug 01 00:00:00 EDT 2022 · Inorganic Chemistry · OSTI ID:1377540

Hu, Aohan; Simms, Megan E.; Kertesz, Vilmos; +2 more

Evaluating the electronic structure of formal Ln^II ions in Ln^II(C₅H₄SiMe₃)₃^1– using XANES spectroscopy and DFT calculations

Journal Article · Fri Jun 30 00:00:00 EDT 2017 · Chemical Science · OSTI ID:1377540

Fieser, Megan E.; Ferrier, Maryline Ghislaine; Su, Jing; +13 more

Nitrogen-rich macrocyclic ligands, chelation complexes thereof, and process for selective chelation of radioactive bismuth ions with the ligands

Patent · Tue Oct 22 00:00:00 EDT 2019 · OSTI ID:1377540

Wilson, Justin; Birnbaum, Eva; John, Kevin; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Inorganic and Physical Chemistry

Title: A Macrocyclic Chelator That Selectively Binds Ln4+ over Ln3+ by a Factor of 1029

Citation Formats

References (162)

Cited By (5)

Linked Research (1)

Similar Records

Related Subjects

Title: A Macrocyclic Chelator That Selectively Binds Ln⁴⁺ over Ln³⁺ by a Factor of 10²⁹