High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin

Chen, Tao; Hu, Jiazhi; Zhang, Long; Pan, Jie; Liu, Yiyang; Cheng, Yang -Tse

doi:10.1016/j.jpowsour.2017.07.049

Title: High performance binder-free SiO_x/C composite LIB electrode made of SiO_x and lignin

Abstract

A high performance binder-free SiO_x/C composite electrode was synthesized by mixing SiO_x particles and Kraft lignin in a cryo-mill followed by heat treatment at 600 °C. After the heat treatment, lignin formed a conductive matrix hosting SiO_x particles, ensuring electronic conductivity, connectivity, and accommodation of volume changes during lithiation/delithiation. As the result, no conventional binder or conductive agent was necessary. When electrochemically cycled, the composite electrode delivered excellent performance, maintaining ~900 mAh g^-1 after 250 cycles at a rate of 200 mA g^-1, and good rate capability. The robustness of the electrode was also examined by post-cycling SEM images, where few cracks were observed. The excellent electrochemical performance can be attributed to the comparatively small volume change of SiO_x-based electrodes (160%) and the flexibility of the lignin derived carbon matrix to accommodate the volume change. In conclusion, this work should stimulate further interests in using bio-renewable resources in making advanced electrochemical energy storage systems.

Authors:

Chen, Tao ^[1];

^[1]; Zhang, Long ^[1]; Pan, Jie ^[2]; Liu, Yiyang ^[1]; Cheng, Yang -Tse ^[1]

Univ. of Kentucky, Lexington, KY (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Publication Date:: Wed Jul 19 00:00:00 EDT 2017

Research Org.:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Org.:: National Science Foundation (NSF); USDOE

OSTI Identifier:: 1375117

Report Number(s):: NREL/JA-5K00-69033
Journal ID: ISSN 0378-7753

Grant/Contract Number:: AC36-08GO28308

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Volume: 362; Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; SiOx/C composite electrode; lithium-ion battery; lignin; renewable

Citation Formats


                    Chen, Tao, Hu, Jiazhi, Zhang, Long, Pan, Jie, Liu, Yiyang, and Cheng, Yang -Tse. High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin.  United States: N. p., 2017. 
        Web.  doi:10.1016/j.jpowsour.2017.07.049.

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                    Chen, Tao, Hu, Jiazhi, Zhang, Long, Pan, Jie, Liu, Yiyang, & Cheng, Yang -Tse. High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin.  United States.  https://doi.org/10.1016/j.jpowsour.2017.07.049

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                    Chen, Tao, Hu, Jiazhi, Zhang, Long, Pan, Jie, Liu, Yiyang, and Cheng, Yang -Tse. 2017.  
        "High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin".  United States.  https://doi.org/10.1016/j.jpowsour.2017.07.049.  https://www.osti.gov/servlets/purl/1375117.

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@article{osti_1375117,

  title        = {High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin},

  author       = {Chen, Tao and Hu, Jiazhi and Zhang, Long and Pan, Jie and Liu, Yiyang and Cheng, Yang -Tse},

  abstractNote = {A high performance binder-free SiOx/C composite electrode was synthesized by mixing SiOx particles and Kraft lignin in a cryo-mill followed by heat treatment at 600 °C. After the heat treatment, lignin formed a conductive matrix hosting SiOx particles, ensuring electronic conductivity, connectivity, and accommodation of volume changes during lithiation/delithiation. As the result, no conventional binder or conductive agent was necessary. When electrochemically cycled, the composite electrode delivered excellent performance, maintaining ~900 mAh g-1 after 250 cycles at a rate of 200 mA g-1, and good rate capability. The robustness of the electrode was also examined by post-cycling SEM images, where few cracks were observed. The excellent electrochemical performance can be attributed to the comparatively small volume change of SiOx-based electrodes (160%) and the flexibility of the lignin derived carbon matrix to accommodate the volume change. In conclusion, this work should stimulate further interests in using bio-renewable resources in making advanced electrochemical energy storage systems.},

  doi          = {10.1016/j.jpowsour.2017.07.049},

  url          = {https://www.osti.gov/biblio/1375117},
  journal      = {Journal of Power Sources},

  issn         = {0378-7753},

  number       = C,

  volume       = 362,

  place        = {United States},

  year         = {Wed Jul 19 00:00:00 EDT 2017},

  month        = {Wed Jul 19 00:00:00 EDT 2017}

}

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Wu, Xiaoyu; Jiang, Junhua; Wang, Chongmin
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Designing of hierarchical mesoporous/macroporous silicon-based composite anode material for low-cost high-performance lithium-ion batteries
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Electrochemical properties of Sn-based nanopowders synthesized by a pulsed wire evaporation method and effect of binder coating

Journal Article Ha, Jong-Keun; Song, Ju-Seok; Cho, Gyu-Bong; ... - Materials Research Bulletin

Highlights: • Sn-based nanoparticles are fabricated by using the pulsed wire evaporation method. • The electrodes are prepared by mixing the graphene and coating the surface. • Coating the surface of electrode is used with brushing of simple and facile method. • The electrochemical measurements are performed with galvanostatic experiments. • The coating electrode maintains capacity nearly of 501 mAh g{sup −1} up to 100 cycles. - Abstract: Sn-based nanoparticles are prepared with the O{sub 2} concentrations in chamber of Ar atmosphere (by v/v) by using the pulsed wire evaporation (PWE) method. The prepared electrodes are only Sn-based powder electrode,more »« less
https://doi.org/10.1016/J.MATERRESBULL.2015.12.037

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Title: High performance binder-free SiOx/C composite LIB electrode made of SiOx and lignin

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Silicon-based materials as high capacity anodes for next generation lithium ion batteries journal, December 2014

Colossal Reversible Volume Changes in Lithium Alloys journal, January 2001

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction journal, January 2004

High-performance lithium battery anodes using silicon nanowires journal, December 2007

Improved cycling stability of silicon thin film electrodes through patterning for high energy density lithium batteries journal, February 2011

Regulated Breathing Effect of Silicon Negative Electrode for Dramatically Enhanced Performance of Li-Ion Battery journal, January 2015

Effects of stress on lithium transport in amorphous silicon electrodes for lithium-ion batteries journal, April 2015

The design of a Li-ion full cell battery using a nano silicon and nano multi-layer graphene composite anode journal, March 2014

Facile Synthesis of Carbon-Coated Silicon/Graphite Spherical Composites for High-Performance Lithium-Ion Batteries journal, May 2016

Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes journal, January 2016

Si–SiC nanocomposite anodes synthesized using high-energy mechanical milling journal, May 2004

Cross-linked aluminum dioxybenzene coating for stabilization of silicon electrodes journal, April 2016

Alumina-Coated Patterned Amorphous Silicon as the Anode for a Lithium-Ion Battery with High Coulombic Efficiency journal, September 2011

Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries journal, February 2016

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries journal, September 2011

Sodium Carboxymethyl Cellulose journal, January 2007

Enhancing Electrochemical Performance of Silicon Film Anode by Vinylene Carbonate Electrolyte Additive journal, January 2006

Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode journal, October 2006

General method to predict voltage-dependent ionic conduction in a solid electrolyte coating on electrodes journal, April 2015

SiOx-based anodes for secondary lithium batteries journal, December 2002

Analysis of SiO Anodes for Lithium-Ion Batteries journal, January 2005

Atomic-Level Understanding toward a High-Capacity and High-Power Silicon Oxide (SiO) Material journal, December 2015

Combinatorial Studies of Si 1− x O x as a Potential Negative Electrode Material for Li-Ion Battery Applications journal, January 2013

Improvement of cycle behaviour of SiO/C anode composite by thermochemically generated Li4SiO4 inert phase for lithium batteries journal, March 2009

Fabrication and lithium storage performance of sugar apple-shaped SiO x @C nanocomposite spheres journal, August 2015

Nitrogen-doped carbon coating for a high-performance SiO anode in lithium-ion batteries journal, September 2013

Nano-sized SiOx/C composite anode for lithium ion batteries journal, May 2011

Facile spray-drying/pyrolysis synthesis of intertwined SiO@CNFs&G composites as superior anode materials for Li-ion batteries journal, January 2014

Si@SiOx/graphene hydrogel composite anode for lithium-ion battery journal, February 2016

Nanostructured silicon for high capacity lithium battery anodes journal, January 2011

Lignin Biosynthesis journal, June 2003

Conversion of Lignin Precursors to Carbon Fibers with Nanoscale Graphitic Domains journal, July 2014

Highly Robust Lithium Ion Battery Anodes from Lignin: An Abundant, Renewable, and Low-Cost Material journal, August 2013

Binder-free lithium ion battery electrodes made of silicon and pyrolized lignin journal, January 2016

Low-Temperature Treated Lignin as Both Binder and Conductive Additive for Silicon Nanoparticle Composite Electrodes in Lithium-Ion Batteries journal, November 2016

Preparation and Characterization of Interconnected, Kraft Lignin-Based Carbon Fibrous Materials by Electrospinning: Preparation and Characterization of Interconnected … journal, October 2013

Correlation of Elongational Fluid Properties to Fiber Diameter in Electrospinning of Softwood Kraft Lignin Solutions journal, February 2014

Kraft lignin/poly(ethylene oxide) blends: Effect of lignin structure on miscibility and hydrogen bonding journal, January 2005

Role of the binder on the failure mechanism of Si nano-composite electrodes for Li-ion batteries journal, August 2011

Encapsulating micro-nano Si/SiO x into conjugated nitrogen-doped carbon as binder-free monolithic anodes for advanced lithium ion batteries journal, January 2015

Microsized Porous SiO x @C Composites Synthesized through Aluminothermic Reduction from Rice Husks and Used as Anode for Lithium-Ion Batteries journal, October 2016

High performance amorphous-Si@SiOx/C composite anode materials for Li-ion batteries derived from ball-milling and in situ carbonization journal, June 2014

Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors journal, January 2013

Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors journal, January 2013

Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond journal, September 2004

Interpretation of Raman spectra of disordered and amorphous carbon journal, May 2000

Characterizations and electrochemical behaviors of disproportionated SiO and its composite for rechargeable Li-ion batteries journal, January 2010

An interface clusters mixture model for the structure of amorphous silicon monoxide (SiO) journal, June 2003

Carbon scaffold structured silicon anodes for lithium-ion batteries journal, January 2010

Scalable synthesis of core-shell structured SiO x /nitrogen-doped carbon composite as a high-performance anode material for lithium-ion batteries journal, June 2016

Structural Analysis of Pure and Electrochemically Lithiated SiO Using Neutron Elastic Scattering journal, January 2004

Kinetics of Electrochemical Insertion and Extraction of Lithium Ion at SiO journal, January 2010

Electrospun Silicon Nanoparticle/Porous Carbon Hybrid Nanofibers for Lithium-Ion Batteries journal, March 2013

Atomistics of the lithiation of oxidized silicon (SiO x ) nanowires in reactive molecular dynamics simulations journal, January 2016

Improvement of irreversible behavior of SiO anodes for lithium ion batteries by a solid state reaction at high temperature journal, April 2016

Fading mechanisms of carbon-coated and disproportionated Si/SiOx negative electrode (Si/SiOx/C) in Li-ion secondary batteries: Dynamics and component analysis by TEM journal, December 2012

Characterizing local structure of SiOx using confocal μ-Raman spectroscopy and its effects on electrochemical property journal, September 2016

Self-sacrificed synthesis of carbon-coated SiO x nanowires for high capacity lithium ion battery anodes journal, January 2017

Facile synthesis of SiOx@C composite nanorods as anodes for lithium ion batteries with excellent electrochemical performance journal, February 2016

Highly stable SiOx/multiwall carbon nanotube/N-doped carbon composite as anodes for lithium-ion batteries journal, July 2016

Reaction of Li with Alloy Thin Films Studied by In Situ AFM journal, January 2003

Application of Stabilized Lithium Metal Powder (SLMP®) in graphite anode – A high efficient prelithiation method for lithium-ion batteries journal, August 2014

Lignin‐derived electrochemical energy materials and systems journal, January 2020

The effects of carbonization conditions on electrochemical performance of attapulgite-based anode material for lithium-ion batteries journal, April 2019

Dopamine-grafted heparin as an additive to the commercialized carboxymethyl cellulose/styrene-butadiene rubber binder for practical use of SiOx/graphite composite anode journal, July 2018

Designing of hierarchical mesoporous/macroporous silicon-based composite anode material for low-cost high-performance lithium-ion batteries journal, January 2019

Dopamine-grafted heparin as an additive to the commercialized carboxymethyl cellulose/styrene-butadiene rubber binder for practical use of SiOx/graphite composite anode journal, July 2018

Title: High performance binder-free SiO_x/C composite LIB electrode made of SiO_x and lignin

Silicon-based materials as high capacity anodes for next generation lithium ion batteries
journal, December 2014

Colossal Reversible Volume Changes in Lithium Alloys
journal, January 2001

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Improved cycling stability of silicon thin film electrodes through patterning for high energy density lithium batteries
journal, February 2011

Regulated Breathing Effect of Silicon Negative Electrode for Dramatically Enhanced Performance of Li-Ion Battery
journal, January 2015

Effects of stress on lithium transport in amorphous silicon electrodes for lithium-ion batteries
journal, April 2015

The design of a Li-ion full cell battery using a nano silicon and nano multi-layer graphene composite anode
journal, March 2014

Facile Synthesis of Carbon-Coated Silicon/Graphite Spherical Composites for High-Performance Lithium-Ion Batteries
journal, May 2016

Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes
journal, January 2016

Si–SiC nanocomposite anodes synthesized using high-energy mechanical milling
journal, May 2004

Cross-linked aluminum dioxybenzene coating for stabilization of silicon electrodes
journal, April 2016

Alumina-Coated Patterned Amorphous Silicon as the Anode for a Lithium-Ion Battery with High Coulombic Efficiency
journal, September 2011

Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries
journal, February 2016

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011

Sodium Carboxymethyl Cellulose
journal, January 2007

Enhancing Electrochemical Performance of Silicon Film Anode by Vinylene Carbonate Electrolyte Additive
journal, January 2006

Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode
journal, October 2006

General method to predict voltage-dependent ionic conduction in a solid electrolyte coating on electrodes
journal, April 2015

SiO_x-based anodes for secondary lithium batteries
journal, December 2002

Analysis of SiO Anodes for Lithium-Ion Batteries
journal, January 2005

Atomic-Level Understanding toward a High-Capacity and High-Power Silicon Oxide (SiO) Material
journal, December 2015

Combinatorial Studies of Si _{1− x} O _x as a Potential Negative Electrode Material for Li-Ion Battery Applications
journal, January 2013

Improvement of cycle behaviour of SiO/C anode composite by thermochemically generated Li₄SiO₄ inert phase for lithium batteries
journal, March 2009

Fabrication and lithium storage performance of sugar apple-shaped SiO x @C nanocomposite spheres
journal, August 2015

Nitrogen-doped carbon coating for a high-performance SiO anode in lithium-ion batteries
journal, September 2013

Nano-sized SiO_x/C composite anode for lithium ion batteries
journal, May 2011

Facile spray-drying/pyrolysis synthesis of intertwined SiO@CNFs&G composites as superior anode materials for Li-ion batteries
journal, January 2014

Si@SiOx/graphene hydrogel composite anode for lithium-ion battery
journal, February 2016

Nanostructured silicon for high capacity lithium battery anodes
journal, January 2011

Lignin Biosynthesis
journal, June 2003

Conversion of Lignin Precursors to Carbon Fibers with Nanoscale Graphitic Domains
journal, July 2014

Highly Robust Lithium Ion Battery Anodes from Lignin: An Abundant, Renewable, and Low-Cost Material
journal, August 2013

Binder-free lithium ion battery electrodes made of silicon and pyrolized lignin
journal, January 2016

Low-Temperature Treated Lignin as Both Binder and Conductive Additive for Silicon Nanoparticle Composite Electrodes in Lithium-Ion Batteries
journal, November 2016

Preparation and Characterization of Interconnected, Kraft Lignin-Based Carbon Fibrous Materials by Electrospinning: Preparation and Characterization of Interconnected …
journal, October 2013

Correlation of Elongational Fluid Properties to Fiber Diameter in Electrospinning of Softwood Kraft Lignin Solutions
journal, February 2014

Kraft lignin/poly(ethylene oxide) blends: Effect of lignin structure on miscibility and hydrogen bonding
journal, January 2005

Role of the binder on the failure mechanism of Si nano-composite electrodes for Li-ion batteries
journal, August 2011

Encapsulating micro-nano Si/SiO _x into conjugated nitrogen-doped carbon as binder-free monolithic anodes for advanced lithium ion batteries
journal, January 2015

Microsized Porous SiO _x @C Composites Synthesized through Aluminothermic Reduction from Rice Husks and Used as Anode for Lithium-Ion Batteries
journal, October 2016

High performance amorphous-Si@SiOx/C composite anode materials for Li-ion batteries derived from ball-milling and in situ carbonization
journal, June 2014

Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors
journal, January 2013

Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors
journal, January 2013

Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
journal, September 2004

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000

Characterizations and electrochemical behaviors of disproportionated SiO and its composite for rechargeable Li-ion batteries
journal, January 2010

An interface clusters mixture model for the structure of amorphous silicon monoxide (SiO)
journal, June 2003

Carbon scaffold structured silicon anodes for lithium-ion batteries
journal, January 2010

Scalable synthesis of core-shell structured SiO x /nitrogen-doped carbon composite as a high-performance anode material for lithium-ion batteries
journal, June 2016

Structural Analysis of Pure and Electrochemically Lithiated SiO Using Neutron Elastic Scattering
journal, January 2004

Kinetics of Electrochemical Insertion and Extraction of Lithium Ion at SiO
journal, January 2010

Electrospun Silicon Nanoparticle/Porous Carbon Hybrid Nanofibers for Lithium-Ion Batteries
journal, March 2013

Atomistics of the lithiation of oxidized silicon (SiO _x ) nanowires in reactive molecular dynamics simulations
journal, January 2016

Improvement of irreversible behavior of SiO anodes for lithium ion batteries by a solid state reaction at high temperature
journal, April 2016

Fading mechanisms of carbon-coated and disproportionated Si/SiOx negative electrode (Si/SiOx/C) in Li-ion secondary batteries: Dynamics and component analysis by TEM
journal, December 2012

Characterizing local structure of SiOx using confocal μ-Raman spectroscopy and its effects on electrochemical property
journal, September 2016

Self-sacrificed synthesis of carbon-coated SiO _x nanowires for high capacity lithium ion battery anodes
journal, January 2017

Facile synthesis of SiOx@C composite nanorods as anodes for lithium ion batteries with excellent electrochemical performance
journal, February 2016

Highly stable SiOx/multiwall carbon nanotube/N-doped carbon composite as anodes for lithium-ion batteries
journal, July 2016

Reaction of Li with Alloy Thin Films Studied by In Situ AFM
journal, January 2003

Application of Stabilized Lithium Metal Powder (SLMP^®) in graphite anode – A high efficient prelithiation method for lithium-ion batteries
journal, August 2014

Lignin‐derived electrochemical energy materials and systems
journal, January 2020

The effects of carbonization conditions on electrochemical performance of attapulgite-based anode material for lithium-ion batteries
journal, April 2019

Dopamine-grafted heparin as an additive to the commercialized carboxymethyl cellulose/styrene-butadiene rubber binder for practical use of SiOx/graphite composite anode
journal, July 2018

Designing of hierarchical mesoporous/macroporous silicon-based composite anode material for low-cost high-performance lithium-ion batteries
journal, January 2019

Dopamine-grafted heparin as an additive to the commercialized carboxymethyl cellulose/styrene-butadiene rubber binder for practical use of SiOx/graphite composite anode
journal, July 2018