Chemical tuning of dynamic cation off-centering in the cubic phases of hybrid tin and lead halide perovskites

Laurita, Geneva; Fabini, Douglas H.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.; Seshadri, Ram

doi:10.1039/C7SC01429E

Title: Chemical tuning of dynamic cation off-centering in the cubic phases of hybrid tin and lead halide perovskites

Journal Article · Fri Jun 16 00:00:00 EDT 2017 · Chemical Science

DOI:https://doi.org/10.1039/C7SC01429E· OSTI ID:1373773

Laurita, Geneva ^[1];

^[1]; Stoumpos, Constantinos C. ^[2]; Kanatzidis, Mercouri G. ^[2];

^[1]

Univ. of California, Santa Barbara, CA (United States)
Northwestern Univ., Evanston, IL (United States)

We reveal here a key aspect of the inorganic framework of hybrid halide perovskites that potentially impacts the electronic, thermal, and dielectric properties.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0012541; AC02-06CH11357

OSTI ID:: 1373773

Alternate ID(s):: OSTI ID: 1599743

Journal Information:: Chemical Science, Vol. 8, Issue 8; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 74 works

Citation information provided by
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Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds Vishnoi, Pratap; Zuo, Julia L.; Strom, T. Amanda Angewandte Chemie International Edition, Vol. 59, Issue 23 https://doi.org/10.1002/anie.202003095	journal	April 2020
All-inorganic cesium lead iodide perovskite solar cells with stabilized efficiency beyond 15% Wang, Kang; Jin, Zhiwen; Liang, Lei Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06915-6	journal	October 2018
Dynamic shortening of disorder potentials in anharmonic halide perovskites Gehrmann, Christian; Egger, David A. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11087-y	journal	July 2019
Chemically controlled crystal growth of (CH ₃ NH ₃ ) ₂ AgInBr ₆ Tran, Thao T.; Quintero, Michael A.; Arpino, Kathryn E. CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/c8ce00702k	journal	January 2018
Bond valences and anharmonicity in vacancy-ordered double perovskite halides Maughan, Annalise E.; Paecklar, Arnold A.; Neilson, James R. Journal of Materials Chemistry C, Vol. 6, Issue 44 https://doi.org/10.1039/c8tc03527j	journal	January 2018
Unravelling the effects of oxidation state of interstitial iodine and oxygen passivation on charge trapping and recombination in CH ₃ NH ₃ PbI ₃ perovskite: a time-domain ab initio study He, Jinlu; Fang, Wei-Hai; Long, Run Chemical Science, Vol. 10, Issue 43 https://doi.org/10.1039/c9sc02353d	journal	January 2019
Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds Vishnoi, Pratap; Zuo, Julia L.; Strom, T. Amanda Angewandte Chemie, Vol. 132, Issue 23 https://doi.org/10.1002/ange.202003095	journal	April 2020
Understanding the Instability of the Halide Perovskite CsPbI$_3$ through Temperature-Dependent Structural Analysis Straus, Daniel B.; Guo, Shu; Abeykoon, Milinda arXiv https://doi.org/10.48550/arxiv.2002.10912	text	January 2020

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