Electrochemical Transport Phenomena in Hybrid Pseudocapacitors under Galvanostatic Cycling

d'Entremont, Anna L.; Girard, Henri -Louis; Wang, Hainan; Pilon, Laurent

doi:10.1149/2.0441602jes

Title: Electrochemical Transport Phenomena in Hybrid Pseudocapacitors under Galvanostatic Cycling

Journal Article · Wed Nov 18 00:00:00 EST 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0441602jes· OSTI ID:1370222

d'Entremont, Anna L. ^[1]; Girard, Henri -Louis ^[1]; Wang, Hainan ^[1]; Pilon, Laurent ^[1]

Univ. of California, Los Angeles, CA (United States)

Here, this study aims to provide insights into the electrochemical transport and interfacial phenomena in hybrid pseudocapacitors under galvanostatic cycling. Pseudocapacitors are promising electrical energy storage devices for applications requiring large power density. They also involve complex, coupled, and multiscale physical phenomena that are difficult to probe experimentally. The present study performed detailed numerical simulations for a hybrid pseudocapacitor with planar electrodes and binary, asymmetric electrolyte under various cycling conditions, based on a first-principles continuum model accounting simultaneously for charge storage by electric double layer (EDL) formation and by faradaic reactions with intercalation. Two asymptotic regimes were identified corresponding to (i) dominant faradaic charge storage at low current and low frequency or (ii) dominant EDL charge storage at high current and high frequency. Analytical expressions for the intercalated ion concentration and surface overpotential were derived for both asymptotic regimes. Features of typical experimentally measured cell potential were physically interpreted. These insights could guide the optimization of hybrid pseudocapacitors.

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Research Organization:: Energy Frontier Research Centers (EFRC), Washington, D.C. (United States). Molecularly Engineered Energy Materials (MEEM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001342

OSTI ID:: 1370222

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 2; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
energy storage
intercalation
pseudocapacitors
supercapacitors

Title: Electrochemical Transport Phenomena in Hybrid Pseudocapacitors under Galvanostatic Cycling

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