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Title: Isomer-dependent fragmentation dynamics of inner-shell photoionized difluoroiodobenzene

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI:https://doi.org/10.1039/c7cp01379e· OSTI ID:1369402
 [1];  [2];  [2];  [3];  [4]; ORCiD logo [2];  [5];  [6]; ORCiD logo [7];  [4];  [3]; ORCiD logo [4]
  1. Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab.; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  2. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  3. Univ. of Connecticut, Storrs, CT (United States). Dept. of Physics
  4. Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab.
  5. Univ. of Oxford (United Kingdom). Dept. of Chemistry
  6. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  7. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

The fragmentation dynamics of 2,6- and 3,5-difluoroiodobenzene after iodine 4d inner-shell photoionization with soft X-rays are studied using coincident electron and ion momentum imaging.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-76SF00515; FG02-86ER13491; SC0012376; AC02-05CH11231
OSTI ID:
1369402
Alternate ID(s):
OSTI ID: 1458495
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Vol. 19, Issue 21; ISSN 1463-9076
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 18 works
Citation information provided by
Web of Science

References (49)

Direct Determination of Absolute Molecular Stereochemistry in Gas Phase by Coulomb Explosion Imaging journal September 2013
Visualizing Recurrently Migrating Hydrogen in Acetylene Dication by Intense Ultrashort Laser Pulses journal December 2007
Direct and indirect dissociative double photoionization of diatomic molecules journal December 1996
Imaging the Absolute Configuration of a Chiral Epoxide in the Gas Phase journal November 2013
Absolute Configuration from Different Multifragmentation Pathways in Light-Induced Coulomb Explosion Imaging journal June 2016
Photofragment image analysis using the Onion-Peeling Algorithm journal July 2003
Ion-induced triple fragmentation of CO 2 3 + into C + + O + + O + journal December 2011
Doppler-free kinetic energy release spectrum of journal April 1996
Photo induced three body decay journal January 1997
Geometry modifications and alignment of H 2 O in an intense femtosecond laser pulse journal April 1999
Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera journal July 2017
Reconstruction of Abel-transformable images: The Gaussian basis-set expansion Abel transform method journal July 2002
Multielectron spectroscopy: Auger decays of the argon 2p hole journal May 2007
Ultrafast isomerization initiated by X-ray core ionization journal September 2015
Coulomb explosion of simple molecules in intense laser fields journal July 1994
Fragmentation Dynamics of CO 2 3 + Investigated by Multiple Electron Capture in Collisions with Slow Highly Charged Ions journal March 2010
Laser-induced 3D alignment and orientation of quantum state-selected molecules journal January 2009
Two-dimensional charged particle image inversion using a polar basis function expansion journal November 2004
Direct Probe of the Bent and Linear Geometries of the Core-Excited Renner-Teller Pair States by Means of the Triple-Ion-Coincidence Momentum Imaging Technique journal March 2002
Incorporating real time velocity map image reconstruction into closed-loop coherent control journal November 2014
Recoil-ion momentum spectroscopy journal July 1997
Holding and Spinning Molecules in Space journal October 2007
Multiply charged molecules journal April 1993
Three-body fragmentation of C O 2 2 + upon K -shell photoionization journal November 2008
Auger cascades versus direct double Auger: relaxation processes following photoionization of the Kr 3d and Xe 4d, 3d inner shells journal October 2005
A study of the photoionisation dynamics of chloromethane and iodomethane journal August 2006
Femtosecond charge and molecular dynamics of I-containing organic molecules induced by intense X-ray free-electron laser pulses journal January 2016
Jitter-correction for IR/UV-XUV pump-probe experiments at the FLASH free-electron laser journal April 2017
Fragmentation of CO 2 into C + + O + + O, in collisions with protons journal July 2000
Cold Target Recoil Ion Momentum Spectroscopy: a ‘momentum microscope’ to view atomic collision dynamics journal June 2000
Molecular photodissociation studied by VUV and soft x-ray radiation journal April 2005
K-shell photoionization of CO and N 2 : is there a link between the photoelectron angular distribution and the molecular decay dynamics? journal September 2001
Photoelectron imaging spectrometry: Principle and inversion method journal June 1996
Two‐dimensional imaging of state‐selected photodissociation products detected by multiphoton ionization journal July 1987
Direct observation of “dynamic” chirality by Coulomb explosion imaging journal July 2001
Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen journal September 1997
Dissociative photoionisation of molecules probed by triple coincidence; double time-of-flight techniques journal December 1986
Identification of absolute geometries of cis and trans molecular isomers by Coulomb Explosion Imaging journal December 2016
Dissociation of Benzene Dication [C 6 H 6 ] 2+ :  Exploring the Potential Energy Surface journal December 2005
Dynamics of three-body reactions in ICN2+ and related molecules journal February 1993
Recoil-ion and electron momentum spectroscopy: reaction-microscopes journal August 2003
Core Ionization Initiates Subfemtosecond Charge Migration in the Valence Shell of Molecules journal August 2016
The dynamics of three-body dissociations of dications studied by the triple coincidence technique PEPIPICO journal June 1987
Tabletop imaging of structural evolutions in chemical reactions demonstrated for the acetylene cation journal July 2014
Nonsequential and Sequential Fragmentation of CO 2 3 + in Intense Laser Fields journal March 2013
HCI-Induced Molecule Fragmentation: non-Coulombic Explosion and Three-Body Effects journal January 2001
Excitation of autoionizing states of helium by 100 keV proton impact: II. Excitation cross sections and mechanisms of excitation journal March 2000
Ultrafast Charge Rearrangement and Nuclear Dynamics upon Inner-Shell Multiple Ionization of Small Polyatomic Molecules journal January 2013
Downstream molecular pathways of FLT3 in the pathogenesis of acute myeloid leukemia: biology and therapeutic implications journal April 2011

Cited By (7)

Photophysics of indole upon X-ray absorption journal January 2018
Photodissociation of aligned CH 3 I and C 6 H 3 F 2 I molecules probed with time-resolved Coulomb explosion imaging by site-selective extreme ultraviolet ionization journal January 2018
A coincidence velocity map imaging spectrometer for ions and high-energy electrons to study inner-shell photoionization of gas-phase molecules journal May 2019
Three-dimensional momentum imaging of dissociation in flight of metastable molecules journal October 2017
Photophysics of indole upon X-ray absorption text January 2018
Photophysics of indole upon x-ray absorption text January 2018
A Coincidence Velocity Map Imaging Spectrometer for Ions and High-Energy Electrons to Study Inner-Shell Photoionization of Gas-Phase Molecules text January 2019