Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam

doi:10.1038/ncomms14589

Title: Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

Journal Article · Wed Apr 26 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms14589· OSTI ID:1368376

Li, Wangda ^[1]; Dolocan, Andrei ^[1]; Oh, Pilgun ^[1]; Celio, Hugo ^[1]; Park, Suhyeon ^[2]; Cho, Jaephil ^[2]; Manthiram, Arumugam ^[1]

Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program and Texas Materials Inst.
Ulsan National Inst. of Science and Technology (UNIST), Ulsan (South Korea). Dept. of Energy Engineering, School of Energy and Chemical Engineering

AbstractUndesired electrode–electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States); Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0006447; EE0007762

OSTI ID:: 1368376

Alternate ID(s):: OSTI ID: 2217289

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 261 works

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References (48)

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries Liu, Wen; Oh, Pilgun; Liu, Xien Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201409262	journal	March 2015
The cathode–electrolyte interface in the Li-ion battery Edström, K.; Gustafsson, T.; Thomas, J. O. Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.03.049	journal	November 2004
Role of Alumina Coating on Li−Ni−Co−Mn−O Particles as Positive Electrode Material for Lithium-Ion Batteries Myung, Seung-Taek; Izumi, Kentarou; Komaba, Shinichi Chemistry of Materials, Vol. 17, Issue 14, p. 3695-3704 https://doi.org/10.1021/cm050566s	journal	July 2005
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Reasons for capacity fading of LiCoPO4 cathodes in LiPF6 containing electrolyte solutions Markevich, E.; Sharabi, R.; Gottlieb, H. Electrochemistry Communications, Vol. 15, Issue 1 https://doi.org/10.1016/j.elecom.2011.11.014	journal	February 2012
Bulk-Type All Solid-State Batteries with 5 V Class LiNi _0.5 Mn _1.5 O ₄ Cathode and Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Oh, Gwangseok; Hirayama, Masaaki; Kwon, Ohmin Chemistry of Materials, Vol. 28, Issue 8 https://doi.org/10.1021/acs.chemmater.5b04940	journal	April 2016
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Electrode/Electrolyte Interface Reactivity in High-Voltage Spinel LiMn _1.6 Ni _0.4 O ₄ /Li ₄ Ti ₅ O ₁₂ Lithium-Ion Battery Dedryvère, R.; Foix, D.; Franger, S. The Journal of Physical Chemistry C, Vol. 114, Issue 24 https://doi.org/10.1021/jp1026509	journal	May 2010
Synthesis of Nanometric LiMnPO ₄ via a Two-Step Technique Pivko, Maja; Bele, Marjan; Tchernychova, Elena Chemistry of Materials, Vol. 24, Issue 6 https://doi.org/10.1021/cm203095d	journal	February 2012
Study of the Cathode–Electrolyte Interface of LiMn[sub 1.5]Ni[sub 0.5]O[sub 4] Synthesized by a Sol–Gel Method for Li-Ion Batteries Duncan, Hugues; Abu-Lebdeh, Yaser; Davidson, Isobel J. Journal of The Electrochemical Society, Vol. 157, Issue 4 https://doi.org/10.1149/1.3321710	journal	January 2010
Principal Factors of Carbon Conductive Agents that Contribute to the Gas Formation in High-Voltage Cathode Systems Kajiyama, Akihisa; Masaki, Ryuta; Wakiyama, Tsuyoshi Journal of The Electrochemical Society, Vol. 162, Issue 8 https://doi.org/10.1149/2.0571508jes	journal	January 2015
Investigation of graphitic carbon foams/LiNiPO4 composites Dimesso, Lucangelo; Becker, Dirk; Spanheimer, Christina Journal of Solid State Electrochemistry, Vol. 16, Issue 12 https://doi.org/10.1007/s10008-012-1817-1	journal	July 2012
Influence of Thermal Treated Carbon Black Conductive Additive on the Performance of High Voltage Spinel Cr-Doped LiNi _0.5 Mn _1.5 O ₄ Composite Cathode Electrode Qi, Xin; Blizanac, Berislav; DuPasquier, Aurelien Journal of The Electrochemical Society, Vol. 162, Issue 3 https://doi.org/10.1149/2.0401503jes	journal	December 2014
Anodic Oxidation of Conductive Carbon and Ethylene Carbonate in High-Voltage Li-Ion Batteries Quantified by On-Line Electrochemical Mass Spectrometry Metzger, Michael; Marino, Cyril; Sicklinger, Johannes Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0951506jes	journal	January 2015
A New Coating Method for Alleviating Surface Degradation of LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Cathode Material: Nanoscale Surface Treatment of Primary Particles Kim, Hyejung; Kim, Min Gyu; Jeong, Hu Young Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00045	journal	February 2015
A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung Energy & Environmental Science, Vol. 7, Issue 4 https://doi.org/10.1039/c3ee42981d	journal	January 2014
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b01727	journal	October 2015
Synthesis and Characterization of Li[(Ni _0.8 Co _0.1 Mn _0.1 ) _0.8 (Ni _0.5 Mn _0.5 ) _0.2 ]O ₂ with the Microscale Core−Shell Structure as the Positive Electrode Material for Lithium Batteries Sun, Yang-Kook; Myung, Seung-Taek; Kim, Myung-Hoon Journal of the American Chemical Society, Vol. 127, Issue 38 https://doi.org/10.1021/ja053675g	journal	September 2005
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries Aurbach, Doron Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00431-6	journal	August 2000
Observation of Electron-Beam-Induced Phase Evolution Mimicking the Effect of the Charge–Discharge Cycle in Li-Rich Layered Cathode Materials Used for Li Ion Batteries Lu, Ping; Yan, Pengfei; Romero, Eric Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm5045573	journal	February 2015
Electrode/Electrolyte Interface of Composite α-Li ₃ V ₂ (PO ₄ ) ₃ Cathodes in a Nonaqueous Electrolyte for Lithium Ion Batteries and the Role of the Carbon Additive Membreño, Nellymar; Park, Kyusung; Goodenough, John B. Chemistry of Materials, Vol. 27, Issue 9 https://doi.org/10.1021/acs.chemmater.5b00447	journal	April 2015
Electron Spectroscopy Study of Li[Ni,Co,Mn]O ₂ /Electrolyte Interface: Electronic Structure, Interface Composition, and Device Implications Cherkashinin, Gennady; Motzko, Markus; Schulz, Natalia Chemistry of Materials, Vol. 27, Issue 8 https://doi.org/10.1021/cm5047534	journal	April 2015
Revealing the planar chemistry of two-dimensional heterostructures at the atomic level Chou, Harry; Ismach, Ariel; Ghosh, Rudresh Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8482	journal	June 2015
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li ₂ MnO ₃ −LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja108588y	journal	March 2011
A High Precision Coulometry Study of the SEI Growth in Li/Graphite Cells Smith, A. J.; Burns, J. C.; Zhao, Xuemei Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3557892	journal	January 2011
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries Nam, Kyung-Wan; Bak, Seong-Min; Hu, Enyuan Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200693	journal	June 2012
Short-range cation ordering in ${Li}_{x}$ ${Ni}_{2 - x}$ $O_{2}$ Reimers, Jan N.; Li, W.; Dahn, J. R. Physical Review B, Vol. 47, Issue 14 https://doi.org/10.1103/PhysRevB.47.8486	journal	April 1993
High-energy cathode material for long-life and safe lithium batteries Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun Nature Materials, Vol. 8, Issue 4 https://doi.org/10.1038/nmat2418	journal	March 2009
High-Performance Heterostructured Cathodes for Lithium-Ion Batteries with a Ni-Rich Layered Oxide Core and a Li-Rich Layered Oxide Shell Oh, Pilgun; Oh, Seung-Min; Li, Wangda Advanced Science, Vol. 3, Issue 11 https://doi.org/10.1002/advs.201600184	journal	May 2016
Aging of the LiNi[sub 1∕2]Mn[sub 1∕2]O[sub 2] Positive Electrode Interface in Electrolyte Dupré, Nicolas; Martin, Jean-Frédéric; Oliveri, Julie Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3098494	journal	January 2009
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Capacity fade of LiAlyNi1−x−yCoxO2 cathode for lithium-ion batteries during accelerated calendar and cycle life tests (surface analysis of LiAlyNi1−x−yCoxO2 cathode after cycle tests in restricted depth of discharge ranges) Watanabe, Shoichiro; Kinoshita, Masahiro; Hosokawa, Takashi Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.018	journal	July 2014
Understanding Transition-Metal Dissolution Behavior in LiNi _0.5 Mn _1.5 O ₄ High-Voltage Spinel for Lithium Ion Batteries Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng The Journal of Physical Chemistry C, Vol. 117, Issue 31 https://doi.org/10.1021/jp405158m	journal	July 2013
Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries Aurbach, Doron; Markovsky, Boris; Salitra, Gregory Journal of Power Sources, Vol. 165, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.025	journal	March 2007
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501010	journal	October 2015
Electrochemical activity of carbon blacks in LiPF6-based organic electrolytes Syzdek, Jarosław; Marcinek, Marek; Kostecki, Robert Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.07.033	journal	January 2014
Development of novel lithium borate additives for designed surface modification of high voltage LiNi _0.5 Mn _1.5 O ₄ cathodes Xu, Mengqing; Zhou, Liu; Dong, Yingnan Energy & Environmental Science, Vol. 9, Issue 4 https://doi.org/10.1039/C5EE03360H	journal	January 2016
The Effect of Fluoroethylene Carbonate as an Additive on the Solid Electrolyte Interphase on Silicon Lithium-Ion Electrodes Schroder, Kjell; Alvarado, Judith; Yersak, Thomas A. Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01627	journal	August 2015
Analysis of the Interphase on Carbon Black Formed in High Voltage Batteries Younesi, Reza; Christiansen, Ane Sælland; Scipioni, Roberto Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0761507jes	journal	January 2015
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004
Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden arXiv https://doi.org/10.48550/arxiv.1404.6177	text	January 2014

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