Hard-Soft Composite Carbon as a Long-Cycling and High-Rate Anode for Potassium-Ion Batteries

Jian, Zelang; Hwang, Sooyeon; Li, Zhifei; Hernandez, Alexandre S.; Wang, Xingfeng; Xing, Zhenyu; Su, Dong; Ji, Xiulei

doi:10.1002/adfm.201700324

Title: Hard-Soft Composite Carbon as a Long-Cycling and High-Rate Anode for Potassium-Ion Batteries

Journal Article · Fri May 05 00:00:00 EDT 2017 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201700324· OSTI ID:1362157

Jian, Zelang ^[1]; Hwang, Sooyeon ^[2]; Li, Zhifei ^[1]; Hernandez, Alexandre S. ^[1]; Wang, Xingfeng ^[1]; Xing, Zhenyu ^[1]; Su, Dong ^[2]; Ji, Xiulei ^[1]

Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

There exist tremendous needs for sustainable storage solutions for intermittent renewable energy sources, such as solar and wind energy. Thus, systems based on Earth-abundant elements deserve much attention. Potassium-ion batteries represent a promising candidate because of the abundance of potassium resources. As for the choices of anodes, graphite exhibits encouraging potassium-ion storage properties; however, it suffers limited rate capability and poor cycling stability. Here in this paper, nongraphitic carbons as K-ion anodes with sodium carboxymethyl cellulose as the binder are systematically investigated. Compared to hard carbon and soft carbon, a hard–soft composite carbon with 20 wt% soft carbon distributed in the matrix phase of hard carbon microspheres exhibits highly amenable performance: high capacity, high rate capability, and very stable long-term cycling. In contrast, pure hard carbon suffers limited rate capability, while the capacity of pure soft carbon fades more rapidly.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1362157

Alternate ID(s):: OSTI ID: 1401079

Report Number(s):: BNL-113906-2017-JA; R&D Project: 16060; 16060; KC0403020

Journal Information:: Advanced Functional Materials, Vol. 27, Issue 26; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 437 works

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A high performance SnO ₂ /C nanocomposite cathode for aluminum-ion batteries Lu, Hongyan; Wan, Yuanxin; Wang, Tianyi Journal of Materials Chemistry A, Vol. 7, Issue 12 https://doi.org/10.1039/c8ta11132d	journal	January 2019
Nitrogen-doped bamboo-like carbon nanotubes as anode material for high performance potassium ion batteries Liu, Yanzhen; Yang, Chenghao; Pan, Qichang Journal of Materials Chemistry A, Vol. 6, Issue 31 https://doi.org/10.1039/c8ta04694h	journal	January 2018
A Black Phosphorus–Graphite Composite Anode for Li‐/Na‐/K‐Ion Batteries Jin, Hongchang; Wang, Haiyun; Qi, Zhikai Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201913129	journal	December 2019
Water‐Induced Growth of a Highly Oriented Mesoporous Graphitic Carbon Nanospring for Fast Potassium‐Ion Adsorption/Intercalation Storage Qian, Yong; Jiang, Song; Li, Yang Angewandte Chemie, Vol. 131, Issue 50 https://doi.org/10.1002/ange.201912287	journal	October 2019
Nitrogen/oxygen co-doped mesoporous carbon octahedrons for high-performance potassium-ion batteries Xia, Guoliang; Wang, Changlai; Jiang, Peng Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c8ta12504j	journal	January 2019
In‐situ structural characterizations of electrochemical intercalation of graphite compounds Li, Na; Su, Dong Carbon Energy, Vol. 1, Issue 2 https://doi.org/10.1002/cey2.21	journal	October 2019
CuO Nanoplates for High‐Performance Potassium‐Ion Batteries Cao, Kangzhe; Liu, Huiqiao; Li, Wangyang Small, Vol. 15, Issue 36 https://doi.org/10.1002/smll.201901775	journal	July 2019
Oxygen/Fluorine Dual‐Doped Porous Carbon Nanopolyhedra Enabled Ultrafast and Highly Stable Potassium Storage Lu, Jian; Wang, Changlai; Yu, Haolei Advanced Functional Materials, Vol. 29, Issue 49 https://doi.org/10.1002/adfm.201906126	journal	September 2019
Highly Nitrogen‐Doped Porous Carbon Nanosheets as High‐Performance Anode for Potassium‐Ion Batteries Zhang, Dong Mei; Chen, Zhi Wen; Bai, Jie Batteries & Supercaps, Vol. 3, Issue 2 https://doi.org/10.1002/batt.201900144	journal	November 2019
Ultrahigh Nitrogen Doping of Carbon Nanosheets for High Capacity and Long Cycling Potassium Ion Storage Chang, Xingqi; Zhou, Xiaolong; Ou, Xuewu Advanced Energy Materials, Vol. 9, Issue 47 https://doi.org/10.1002/aenm.201902672	journal	October 2019
Nitrogen-doped hollow carbon nanospheres towards the application of potassium ion storage Ruan, Jiafeng; Wu, Xi; Wang, Yan Journal of Materials Chemistry A, Vol. 7, Issue 33 https://doi.org/10.1039/c9ta05205d	journal	January 2019
Yolk–shell NiS _x @C nanosheets as K-ion battery anodes with high rate capability and ultralong cycle life Yao, Qianqian; Zhang, Jianshuo; Li, Jiaxin Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta06292k	journal	January 2019
Direct Structure–Performance Comparison of All‐Carbon Potassium and Sodium Ion Capacitors Xu, Ziqiang; Wu, Mengqiang; Chen, Zhi Advanced Science, Vol. 6, Issue 12 https://doi.org/10.1002/advs.201802272	journal	April 2019
Fabrication of Porous Carbon with Controllable Nitrogen Doping as Anode for High‐Performance Potassium‐Ion Batteries Wang, Jie; Wang, Dan; Dong, Kangze ChemElectroChem, Vol. 6, Issue 14 https://doi.org/10.1002/celc.201900789	journal	July 2019
Sodium/Potassium‐Ion Batteries: Boosting the Rate Capability and Cycle Life by Combining Morphology, Defect and Structure Engineering Huang, Huijuan; Xu, Rui; Feng, Yuezhan Advanced Materials, Vol. 32, Issue 8 https://doi.org/10.1002/adma.201904320	journal	January 2020
Hyperporous Sponge Interconnected by Hierarchical Carbon Nanotubes as a High-Performance Potassium-Ion Battery Anode Wang, Yunsong; Wang, Zhipeng; Chen, Yijun Advanced Materials, Vol. 30, Issue 32 https://doi.org/10.1002/adma.201802074	journal	June 2018
Recent Progress and Perspective in Electrode Materials for K-Ion Batteries Kim, Haegyeom; Kim, Jae Chul; Bianchini, Matteo Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201702384	journal	December 2017
Graphitic Carbon Nanocage as a Stable and High Power Anode for Potassium-Ion Batteries Cao, Bin; Zhang, Qing; Liu, Huan Advanced Energy Materials, Vol. 8, Issue 25 https://doi.org/10.1002/aenm.201801149	journal	July 2018
A Black Phosphorus–Graphite Composite Anode for Li‐/Na‐/K‐Ion Batteries Jin, Hongchang; Wang, Haiyun; Qi, Zhikai Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201913129	journal	February 2020
Advanced Nanostructured Anode Materials for Sodium-Ion Batteries Wang, Qidi; Zhao, Chenglong; Lu, Yaxiang Small, Vol. 13, Issue 42 https://doi.org/10.1002/smll.201701835	journal	September 2017
Embracing high performance potassium-ion batteries with phosphorus-based electrodes: a review Yang, Dan; Liu, Chuntai; Rui, Xianhong Nanoscale, Vol. 11, Issue 33 https://doi.org/10.1039/c9nr05588f	journal	January 2019
Hierarchical T-Nb ₂ O ₅ nanostructure with hybrid mechanisms of intercalation and pseudocapacitance for potassium storage and high-performance potassium dual-ion batteries Li, Na; Zhang, Fan; Tang, Yongbing Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/c8ta07987k	journal	January 2018
Magnéli Phase Titanium Oxide as a Novel Anode Material for Potassium-Ion Batteries Lee, Geon-Woo; Park, Byung Hoon; Nazarian-Samani, Masoud ACS Omega, Vol. 4, Issue 3 https://doi.org/10.1021/acsomega.9b00045	journal	March 2019
Understanding of the Ultrastable K-Ion Storage of Carbonaceous Anode Liu, Lei; Chen, Yu; Xie, Yihao Advanced Functional Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adfm.201801989	journal	May 2018
Sulfur‐Grafted Hollow Carbon Spheres for Potassium‐Ion Battery Anodes Ding, Jia; Zhang, Hanlei; Zhou, Hui Advanced Materials https://doi.org/10.1002/adma.201900429	journal	June 2019
Highly dispersed Zn nanoparticles confined in a nanoporous carbon network: promising anode materials for sodium and potassium ion batteries Yan, Chunliu; Gu, Xin; Zhang, Li Journal of Materials Chemistry A, Vol. 6, Issue 36 https://doi.org/10.1039/c8ta05297b	journal	January 2018
Bismuthene from sonoelectrochemistry as a superior anode for potassium-ion batteries Shen, Chao; Cheng, Tianle; Liu, Chunyan Journal of Materials Chemistry A, Vol. 8, Issue 1 https://doi.org/10.1039/c9ta11000c	journal	January 2020
Water-Induced Growth of a Highly Oriented Mesoporous Graphitic Carbon Nanospring for Fast Potassium-Ion Adsorption/Intercalation Storage Qian, Yong; Jiang, Song; Li, Yang Angewandte Chemie International Edition, Vol. 58, Issue 50 https://doi.org/10.1002/anie.201912287	journal	October 2019
Capacity Contribution Induced by Pseudo-Capacitance Adsorption Mechanism of Anode Carbonaceous Materials Applied in Potassium-ion Battery Liu, Jiahao; Xu, Ziqiang; Wu, Mengqiang Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00640	journal	October 2019
Candle soot: onion-like carbon, an advanced anode material for a potassium-ion hybrid capacitor Chen, Jiangtao; Yang, Bingjun; Li, Hongxia Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta01653h	journal	January 2019
KVPO ₄ F as a novel insertion-type anode for potassium ion batteries Tan, Hong; Du, Xiaoqiong; Huang, Jian-Qiu Chemical Communications, Vol. 55, Issue 75 https://doi.org/10.1039/c9cc05368a	journal	January 2019

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