A dual cryogenic ion trap spectrometer for the formation and characterization of solvated ionic clusters

Marsh, Brett M.; Voss, Jonathan M.; Garand, Etienne

doi:10.1063/1.4936360

Title: A dual cryogenic ion trap spectrometer for the formation and characterization of solvated ionic clusters

Journal Article · Tue Nov 24 00:00:00 EST 2015 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4936360· OSTI ID:1358401

Marsh, Brett M. ^[1]; Voss, Jonathan M. ^[1]; Garand, Etienne ^[1]

Univ. of Wisconsin, Madison, WI (United States)

A new experimental approach is presented in which two separate cryogenic ion traps are used to reproducibly form weakly bound solvent clusters around electrosprayed ions and messenger-tag them for single-photon infrared photodissociation spectroscopy. This approach thus enables the vibrational characterization of ionic clusters comprised of a solvent network around large and non-volatile ions. We demonstrate the capabilities of the instrument by clustering water, methanol, and acetone around a protonated glycylglycine peptide. For water, cluster sizes with greater than twenty solvent molecules around a single ion are readily formed. We further demonstrate that similar water clusters can be formed around ions having a shielded charge center or those that do not readily form hydrogen bonds. Finally, infrared photodissociation spectra of D₂-tagged GlyGlyH⁺·(H₂O)_1–4 are presented. As a result, they display well-resolved spectral features and comparisons with calculations reveal detailed information on the solvation structures of this prototypical peptide.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010326

OSTI ID:: 1358401

Alternate ID(s):: OSTI ID: 1227169

Journal Information:: Journal of Chemical Physics, Vol. 143, Issue 20; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 56 works

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