Exploring the Use of Ionic Liquid Mixtures to Enhance the Performance of Dicationic Ionic Liquids

Lall-Ramnarine, Sharon I.; Suarez, Sophia N.; Fernandez, Eddie D.; Rodriguez, Chanele; Wei, Sujun; Gobet, Mallory; Jayakody, J. R. P.; Dhiman, Surajdevprakash B.; Wishart, James F.

doi:10.1149/2.0271708jes

Title: Exploring the Use of Ionic Liquid Mixtures to Enhance the Performance of Dicationic Ionic Liquids

Journal Article · Sat May 06 00:00:00 EDT 2017 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0271708jes· OSTI ID:1358033

Lall-Ramnarine, Sharon I. ^[1]; Suarez, Sophia N. ^[2]; Fernandez, Eddie D. ^[3]; Rodriguez, Chanele ^[3]; Wei, Sujun ^[3]; Gobet, Mallory ^[4]; Jayakody, J. R. P. ^[5]; Dhiman, Surajdevprakash B. ^[6]; Wishart, James F. ^[6]

Queensborough Community College, Bayside, NY (United States). Dept. of Chemistry
Brooklyn College, Brooklyn, NY (United States). Physics Dept.
Queensborough Community College of the City Univ. of New York, Bayside, NY (United States). Dept. of Chemistry
Hunter College, New York, NY (United States). Dept. of Physics
Univ. of Kelaniya (Sri Lanka). Dept. of Physics
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division

Dicationic ionic liquids (DILs) of diverse structural architectures (including symmetrical and asymmetrical ammonium, phosphonium and heterodications and the bis(trifluoromethylsulfonyl)amide (NTf₂^-) anion) have been prepared and used as additives to N-methyl-N-ethoxyethylpyrrolidinium (P₁EOE) NTf₂, a relatively high-performing IL in terms of its transport properties (viscosity 53 mPa s). The three-ion, binary IL mixtures were characterized for their thermal and transport properties using differential scanning calorimetry, temperature dependent viscosity, conductivity and Pulsed Gradient Spin Echo (PGSE) NMR. Variable temperature ¹H, ¹⁹F and ³¹P self-diffusion coefficients were determined at 25, 60 and 75°C. The order of the diffusion coefficients was D(P₁EOE⁺) > D(anion) > D(dication), and the composition of the dication had a strong effect on the degree to which diffusion of all three species is more or less coupled. IL mixtures containing about 30 mol % of the dicationic NTf₂ and 70 mol % of P₁EOE NTf₂ resulted in a significant decrease in glass transition temperatures and viscosities compared to the pure DIL. The mixtures extended the liquid range and potential for practical applications significantly. Finally, the data obtained here provides insight into the future design of dicationic salts tailored to exhibit lower viscosity and higher conductivities.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Queensborough Community College, Bayside, NY (United States); Hunter College, New York, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS); National Science Foundation (NSF); National Inst. of Health (NIH) (United States); Staff Congress of the City Univ. of New York (PSC-CUNY) (United States)

Contributing Organization:: Brooklyn College, Brooklyn, NY (United States); Univ. of Kelaniya (Sri Lanka)

Grant/Contract Number:: SC0012704; 68132-00 46

OSTI ID:: 1358033

Report Number(s):: BNL-113883-2017-JA; R&D Project: CO-004; KC0301010

Journal Information:: Journal of the Electrochemical Society, Vol. 164, Issue 8; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 7 works

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Title: Exploring the Use of Ionic Liquid Mixtures to Enhance the Performance of Dicationic Ionic Liquids

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