Active and stable Ir@Pt core–shell catalysts for electrochemical oxygen reduction

Strickler, Alaina L.; Jackson, Ariel; Jaramillo, Thomas F.

doi:10.1021/acsenergylett.6b00585

Title: Active and stable Ir@Pt core–shell catalysts for electrochemical oxygen reduction

Journal Article · Wed Dec 28 00:00:00 EST 2016 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.6b00585· OSTI ID:1349289

Strickler, Alaina L. ^[1]; Jackson, Ariel ^[1];

^[2]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Electrochemical oxygen reduction is an important reaction for many sustainable energy technologies, such as fuel cells and metal–air batteries. Kinetic limitations of this reaction, expensive electrocatalysts, and catalyst instability, however, limit the commercial viability of such devices. Herein, we report an active Ir@Pt core–shell catalyst that combines platinum overlayers with nanostructure effects to tune the oxygen binding to the Pt surface, thereby achieving enhanced activity and stability for the oxygen reduction reaction. Ir@Pt nanoparticles with several shell thicknesses were synthesized in a scalable, inexpensive, one-pot polyol method. Electrochemical analysis demonstrates the activity and stability of the Ir@Pt catalyst, with specific and mass activities increasing to 2.6 and 1.8 times that of commercial Pt/C (TKK), respectively, after 10 000 stability cycles. Furthermore, activity enhancement of the Ir@Pt catalyst is attributed to weakening of the oxygen binding to the Pt surface induced by the Ir core.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1349289

Journal Information:: ACS Energy Letters, Vol. 2, Issue 1; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 56 works

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References (43)

Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Benchmarking Pt-based electrocatalysts for low temperature fuel cell reactions with the rotating disk electrode: oxygen reduction and hydrogen oxidation in the presence of CO (review article) Pedersen, Christoffer M.; Escudero-Escribano, María; Velázquez-Palenzuela, Amado Electrochimica Acta, Vol. 179 https://doi.org/10.1016/j.electacta.2015.03.176	journal	October 2015
Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction Guo, Shaojun; Zhang, Sen; Sun, Shouheng Angewandte Chemie International Edition, Vol. 52, Issue 33 https://doi.org/10.1002/anie.201207186	journal	June 2013
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges Rabis, Annett; Rodriguez, Paramaconi; Schmidt, Thomas J. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs3000864	journal	April 2012
Pt-Based Core–Shell Catalyst Architectures for Oxygen Fuel Cell Electrodes Oezaslan, Mehtap; Hasché, Frédéric; Strasser, Peter The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz4014135	journal	September 2013
Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A. The Journal of Chemical Physics, Vol. 120, Issue 21 https://doi.org/10.1063/1.1737365	journal	June 2004
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A. Physical Review Letters, Vol. 93, Issue 15 https://doi.org/10.1103/PhysRevLett.93.156801	journal	October 2004
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Tuning Nanoparticle Structure and Surface Strain for Catalysis Optimization Zhang, Sen; Zhang, Xu; Jiang, Guangming Journal of the American Chemical Society, Vol. 136, Issue 21 https://doi.org/10.1021/ja5030172	journal	May 2014
Understanding the electrocatalysis of oxygen reduction on platinum and its alloys Stephens, Ifan E. L.; Bondarenko, Alexander S.; Grønbjerg, Ulrik Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03590a	journal	January 2012
Theoretical surface science and catalysis—calculations and concepts Hammer, B.; Nørskov, J. K. Impact of Surface Science on Catalysis, p. 71-129 https://doi.org/10.1016/S0360-0564(02)45013-4	book	January 2000
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction Escudero-Escribano, M.; Malacrida, P.; Hansen, M. H. Science, Vol. 352, Issue 6281 https://doi.org/10.1126/science.aad8892	journal	March 2016
Platinum monolayer electrocatalysts for oxygen reduction Vukmirovic, M. B.; Zhang, J.; Sasaki, K. Electrochimica Acta, Vol. 52, Issue 6 https://doi.org/10.1016/j.electacta.2006.05.062	journal	January 2007
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction Huang, X.; Zhao, Z.; Cao, L. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa8765	journal	June 2015
Improved Oxygen Reduction Activity on Pt₃Ni(111) via Increased Surface Site Availability Stamenkovic, V. R.; Fowler, B.; Mun, B. S. Science, Vol. 315, Issue 5811, p. 493-497 https://doi.org/10.1126/science.1135941	journal	January 2007
Platinum Monolayer Fuel Cell Electrocatalysts Adzic, R. R.; Zhang, J.; Sasaki, K. Topics in Catalysis, Vol. 46, Issue 3-4, p. 249-262 https://doi.org/10.1007/s11244-007-9003-x	journal	November 2007
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S. Nature Chemistry, Vol. 1, Issue 7, p. 552-556 https://doi.org/10.1038/nchem.367	journal	September 2009
Climbing the Activity Volcano: Core-Shell Ru@Pt Electrocatalysts for Oxygen Reduction Jackson, Ariel; Viswanathan, Venkatasubramanian; Forman, Arnold J. ChemElectroChem, Vol. 1, Issue 1 https://doi.org/10.1002/celc.201300117	journal	November 2013
Universality in Oxygen Reduction Electrocatalysis on Metal Surfaces Viswanathan, Venkatasubramanian; Hansen, Heine Anton; Rossmeisl, Jan ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs300227s	journal	July 2012
Combinatorial Density Functional Theory-Based Screening of Surface Alloys for the Oxygen Reduction Reaction Greeley, Jeff; Nørskov, Jens K. The Journal of Physical Chemistry C, Vol. 113, Issue 12 https://doi.org/10.1021/jp808945y	journal	March 2009
Activity, Stability, and Degradation Mechanisms of Dealloyed PtCu3 and PtCo3 Nanoparticle Fuel Cell Catalysts Hasché, Frédéric; Oezaslan, Mehtap; Strasser, Peter ChemCatChem https://doi.org/10.1002/cctc.201100169	journal	September 2011
Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes Chen, Shuo; Gasteiger, Hubert A.; Hayakawa, Katsuichiro Journal of The Electrochemical Society, Vol. 157, Issue 1 https://doi.org/10.1149/1.3258275	journal	January 2010
Activity, Structure and Degradation of Dealloyed PtNi ₃ Nanoparticle Electrocatalyst for the Oxygen Reduction Reaction in PEMFC Hasché, Frédéric; Oezaslan, Mehtap; Strasser, Peter Journal of The Electrochemical Society, Vol. 159, Issue 1 https://doi.org/10.1149/2.030201jes	journal	January 2011
Density Functional Theory Study of Pt ₃ M Alloy Surface Segregation with Adsorbed O/OH and Pt ₃ Os as Catalysts for Oxygen Reduction Reaction Tsai, Ho-Cheng; Yu, Ted H.; Sha, Yao The Journal of Physical Chemistry C, Vol. 118, Issue 46 https://doi.org/10.1021/jp507103c	journal	November 2014
Surface segregation and stability of core–shell alloy catalysts for oxygen reduction in acid medium Ramírez-Caballero, Gustavo E.; Ma, Yuguang; Callejas-Tovar, Rafael Physical Chemistry Chemical Physics, Vol. 12, Issue 9 https://doi.org/10.1039/b917899f	journal	January 2010
Predicted Trends of Core−Shell Preferences for 132 Late Transition-Metal Binary-Alloy Nanoparticles Wang, Lin-Lin; Johnson, Duane D. Journal of the American Chemical Society, Vol. 131, Issue 39 https://doi.org/10.1021/ja903247x	journal	October 2009
Catalytic Activity of Platinum Monolayer on Iridium and Rhenium Alloy Nanoparticles for the Oxygen Reduction Reaction Karan, Hiroko I.; Sasaki, Kotaro; Kuttiyiel, Kurian ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200592x	journal	April 2012
Bimetallic IrNi core platinum monolayer shell electrocatalysts for the oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Choi, YongMan Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02067F	journal	January 2012
Platinum Monolayer on IrFe Core–Shell Nanoparticle Electrocatalysts for the Oxygen Reduction Reaction Sasaki, Kotaro; Kuttiyiel, Kurian A.; Su, Dong Electrocatalysis, Vol. 2, Issue 2 https://doi.org/10.1007/s12678-011-0048-z	journal	April 2011
High performance of core–shell structured Ir@Pt/C catalyst prepared by a facile pulse electrochemical deposition Chen, Dan; Chen, Rong; Dang, Dai Electrochemistry Communications, Vol. 46 https://doi.org/10.1016/j.elecom.2014.07.004	journal	September 2014
Tuning electrocatalytic activity of Pt monolayer shell by bimetallic Ir-M (M=Fe, Co, Ni or Cu) cores for the oxygen reduction reaction Kuttiyiel, Kurian A.; Choi, YongMan; Sasaki, Kotaro Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.05.024	journal	November 2016
Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos Nature Materials, Vol. 7, Issue 4, p. 333-338 https://doi.org/10.1038/nmat2156	journal	March 2008
Synthesis of monodisperse Au, Pt, Pd, Ru and Ir nanoparticles in ethylene glycol Bonet, F.; Delmas, V.; Grugeon, S. Nanostructured Materials, Vol. 11, Issue 8, p. 1277-1284 https://doi.org/10.1016/S0965-9773(99)00419-5	journal	November 1999
Facile Synthesis of Iridium Nanocrystals with Well-Controlled Facets Using Seed-Mediated Growth Xia, Xiaohu; Figueroa-Cosme, Legna; Tao, Jing Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja505716v	journal	July 2014
Effects of a New Electrochemical Cleaning Protocol on Ru@Pt Core-Shell ORR Catalysts Jackson, A.; Viswanathan, V.; Forman, A. J. ECS Transactions, Vol. 58, Issue 1 https://doi.org/10.1149/05801.0929ecst	journal	August 2013
Electrochemical Hydrogen Adsorption and Absorption. Part 1: Under-potential Deposition of Hydrogen Jerkiewicz, Gregory Electrocatalysis, Vol. 1, Issue 4 https://doi.org/10.1007/s12678-010-0022-1	journal	August 2010
Tuning the Activity of Pt(111) for Oxygen Electroreduction by Subsurface Alloying Stephens, Ifan E. L.; Bondarenko, Alexander S.; Perez-Alonso, Francisco J. Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja111690g	journal	April 2011
Electrochemical Stability of Elemental Metal Nanoparticles Tang, Lei; Li, Xiaoqian; Cammarata, Robert C. Journal of the American Chemical Society, Vol. 132, Issue 33 https://doi.org/10.1021/ja104421t	journal	August 2010
Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity Shao, Minhua; Peles, Amra; Shoemaker, Krista Nano Letters, Vol. 11, Issue 9 https://doi.org/10.1021/nl2017459	journal	September 2011
Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates Zhang, Junliang; Vukmirovic, Miomir B.; Xu, Ye Angewandte Chemie International Edition, Vol. 44, Issue 14, p. 2132-2135 https://doi.org/10.1002/anie.200462335	journal	March 2005
Highly Enhanced Oxygen Reduction Reaction Activity and Electrochemical Stability of Pt/Ir(111) Bimetallic Surfaces Todoroki, Naoto; Watanabe, Hirofumi; Kondo, Takayuki Electrochimica Acta, Vol. 222 https://doi.org/10.1016/j.electacta.2016.11.149	journal	December 2016

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