Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons

Mante, Pierre-Adrien; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.; Yartsev, Arkady

doi:10.1038/ncomms14398

Title: Electron–acoustic phonon coupling in single crystal CH₃NH₃PbI₃ perovskites revealed by coherent acoustic phonons

Journal Article · Wed Feb 08 00:00:00 EST 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms14398· OSTI ID:1347386

Mante, Pierre-Adrien ^[1];

^[2]; Kanatzidis, Mercouri G. ^[2]; Yartsev, Arkady ^[1]

Lund Univ. (Sweden). Dept. of Chemistry and NanoLund
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry

The intrinsic properties of CH₃NH₃PbI₃ are still largely unknown in spite of the great amount of attention it has received for its solar cell application. Mobility of charges is a quintessential property in this aspect; however, there is still no clear understanding of electron transport, as reported values span over three orders of magnitude. Here we develop a method to measure the electron and hole deformation potentials using coherent acoustic phonons generated by femtosecond laser pulses. Furthermore, we apply this method to characterize a CH₃NH₃PbI₃ single crystal.We measure the acoustic phonon properties and characterize electron-acoustic phonon scattering. Then, using the deformation potential theory, we calculate the carrier intrinsic mobility and compare it to the reported experimental and theoretical values. These results reveal high electron and hole mobilities of 2,800 and 9,400 cm²V^-1 s ^-1 , respectively. Comparison with literature values of mobility demonstrates the potential role played by polarons in charge transport in CH₃NH₃PbI₃.

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Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0012541

OSTI ID:: 1347386

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 87 works

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Title: Electron–acoustic phonon coupling in single crystal CH₃NH₃PbI₃ perovskites revealed by coherent acoustic phonons