Li/Ag2VO2PO4 batteries: the roles of composite electrode constituents on electrochemistry

Bock, David C.; Bruck, Andrea M.; Pelliccione, Christopher J.; Zhang, Yiman; Takeuchi, Kenneth J.; Marschilok, Amy C.; Takeuchi, Esther S.

doi:10.1039/C6RA24024K

Title: Li/Ag₂VO₂PO₄ batteries: the roles of composite electrode constituents on electrochemistry

Journal Article · Tue Nov 01 00:00:00 EDT 2016 · RSC Advances

DOI:https://doi.org/10.1039/C6RA24024K· OSTI ID:1347289

Bock, David C. ^[1]; Bruck, Andrea M. ^[2]; Pelliccione, Christopher J. ^[1]; Zhang, Yiman ^[2]; Takeuchi, Kenneth J. ^[3]; Marschilok, Amy C. ^[3]; Takeuchi, Esther S. ^[4]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States). Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Engineering

In this study, we utilize silver vanadium phosphorous oxide, Ag₂VO₂PO₄, as a model system to systematically study the impact of the constituents of a composite electrode, including polymeric and conductive additives, on electrochemistry. Notably, although highly resistive, this bimetallic cathode can be discharged as a pure electroactive material in the absence of a conductive additive as it generates an in situ conductive matrix via a reduction displacement reaction resulting in the formation of silver metal nanoparticles. Also, three different electrode compositions were investigated: Ag₂VO₂PO₄ only, Ag₂VO₂PO₄4 with binder, and Ag₂VO₂PO₄ with binder and carbon. Constant current discharge, pulse testing and impedance spectroscopy measurements were used to characterize the electrochemical properties of the electrodes as a function of depth of discharge. In situ EDXRD was used to spatially resolve the discharge progression within the cathode by following the formation of Ag⁰. Ex situ XRD and EXAFS modeling were used to quantify the amount of Ag⁰ formed. Results indicate that the metal center reduced (V⁵⁺ or Ag⁺) was highly dependent on composite composition (presence of PTFE, carbon), depth of discharge (Ag⁰ nanoparticle formation), and spatial location within the cathode. The addition of a binder was found to increase cell polarization, and the percolation network provided by the carbon in the presence of PTFE was further increased with reduction and formation of Ag⁰. Lastly, this study provides insight into the factors controlling the electrochemistry of resistive active materials in composite electrodes.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; SC0012673; AC02-06CH11357

OSTI ID:: 1347289

Report Number(s):: BNL-113549-2017-JA; RSCACL

Journal Information:: RSC Advances, Vol. 6, Issue 108; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 8 works

Citation information provided by
Web of Science

References (63)

Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag ₂ VO ₂ PO ₄ : The Formation of Electrically Conductive Metallic Silver Nanoparticles Takeuchi, Esther S.; Marschilok, Amy C.; Tanzil, Kevin Chemistry of Materials, Vol. 21, Issue 20 https://doi.org/10.1021/cm902102k	journal	October 2009
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Structural and silver/vanadium ratio effects on silver vanadium phosphorous oxide solution formation kinetics: Impact on battery electrochemistry Bock, David C.; Takeuchi, Kenneth J.; Marschilok, Amy C. Physical Chemistry Chemical Physics, Vol. 17, Issue 3 https://doi.org/10.1039/C4CP04819A	journal	January 2015
Modeling and Characterization of the Resistance of Lithium/SVO Batteries for Implantable Cardioverter Defibrillators Crespi, Ann; Schmidt, Craig; Norton, John Journal of The Electrochemical Society, Vol. 148, Issue 1 https://doi.org/10.1149/1.1342156	journal	January 2001
Advanced lithium batteries for implantable medical devices: mechanistic study of SVO cathode synthesis Takeuchi, Kenneth J.; Leising, Randolph A.; Palazzo, Marcus J. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00304-5	journal	June 2003
Ab initio curved-wave x-ray-absorption fine structure Mustre de Leon, J.; Rehr, J. J.; Zabinsky, S. I. Physical Review B, Vol. 44, Issue 9 https://doi.org/10.1103/PhysRevB.44.4146	journal	September 1991
Reflections on the history of electrochemical impedance spectroscopy Macdonald, Digby D. Electrochimica Acta, Vol. 51, Issue 8-9 https://doi.org/10.1016/j.electacta.2005.02.107	journal	January 2006
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism Kirshenbaum, K.; Bock, D. C.; Lee, C. -Y. Science, Vol. 347, Issue 6218 https://doi.org/10.1126/science.1257289	journal	January 2015
Evolution of power sources for implantable cardioverter defibrillators Crespi, Ann M.; Somdahl, Sonja K.; Schmidt, Craig L. Journal of Power Sources, Vol. 96, Issue 1 https://doi.org/10.1016/S0378-7753(01)00499-2	journal	June 2001
A kinetics and equilibrium study of vanadium dissolution from vanadium oxides and phosphates in battery electrolytes: Possible impacts on ICD battery performance Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J. Journal of Power Sources, Vol. 231 https://doi.org/10.1016/j.jpowsour.2013.01.012	journal	June 2013
Silver vanadium oxides and related battery applications Takeuchi*, K. Coordination Chemistry Reviews, Vol. 219-221 https://doi.org/10.1016/S0010-8545(01)00340-X	journal	October 2001
Mapping the Anode Surface-Electrolyte Interphase: Investigating a Life Limiting Process of Lithium Primary Batteries Bock, David C.; Tappero, Ryan V.; Takeuchi, Kenneth J. ACS Applied Materials & Interfaces, Vol. 7, Issue 9 https://doi.org/10.1021/am509066n	journal	February 2015
Impedance spectra of porous, composite intercalation electrodes: The origin of the low-frequency semicircles Levi, M. D.; Aurbach, D. Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.164	journal	August 2005
Spectroscopic X-ray Diffraction for Microfocus Inspection of Li-Ion Batteries Murayama, Haruno; Kitada, Koji; Fukuda, Katsutoshi The Journal of Physical Chemistry C, Vol. 118, Issue 36 https://doi.org/10.1021/jp5029273	journal	August 2014
Electrochemical reduction of an Ag ₂ VO ₂ PO ₄ particle: dramatic increase of local electronic conductivity Kirshenbaum, Kevin C.; Bock, David C.; Brady, Alexander B. Physical Chemistry Chemical Physics, Vol. 17, Issue 17 https://doi.org/10.1039/C5CP00961H	journal	January 2015
Batteries used to power implantable biomedical devices Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J. Electrochimica Acta, Vol. 84 https://doi.org/10.1016/j.electacta.2012.03.057	journal	December 2012
In situ profiling of lithium/Ag₂VP₂O₈ primary batteries using energy dispersive X-ray diffraction Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong Physical Chemistry Chemical Physics, Vol. 16, Issue 19, p. 9138-9147 https://doi.org/10.1039/C4CP01220H	journal	January 2014
A Simplified Electrochemical and Thermal Aging Model of LiFePO ₄ -Graphite Li-ion Batteries: Power and Capacity Fade Simulations Prada, E.; Di Domenico, D.; Creff, Y. Journal of The Electrochemical Society, Vol. 160, Issue 4 https://doi.org/10.1149/2.053304jes	journal	January 2013
The Scherrer Formula for X-Ray Particle Size Determination Patterson, A. L. Physical Review, Vol. 56, Issue 10 https://doi.org/10.1103/PhysRev.56.978	journal	November 1939
Facile preparation of Ag2V4O11 nanoparticles via low-temperature molten salt synthesis method Cao, Xiaoyu; Xie, Lingling; Zhan, Hui Inorganic Materials, Vol. 44, Issue 8 https://doi.org/10.1134/S0020168508080190	journal	August 2008
In Situ X-ray Absorption Spectroscopy Study of the Capacity Fading Mechanism in Hybrid Sn ₃ O ₂ (OH) ₂ /Graphite Battery Anode Nanomaterials Pelliccione, Christopher J.; Timofeeva, Elena V.; Segre, Carlo U. Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm504101h	journal	January 2015
Small things make a big difference: binder effects on the performance of Li and Na batteries Chou, Shu-Lei; Pan, Yuede; Wang, Jia-Zhao Phys. Chem. Chem. Phys., Vol. 16, Issue 38 https://doi.org/10.1039/C4CP02475C	journal	January 2014
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
A novel assembly of LiFePO4 microspheres from nanoplates Zhang, Chuanjian; He, Xiang; Kong, Qingshan CrystEngComm, Vol. 14, Issue 13 https://doi.org/10.1039/c2ce25114k	journal	January 2012
Solid-State Synthesis and Characterization of Silver Vanadium Oxide for Use as a Cathode Material for Lithium Batteries Leising, Randolph A.; Takeuchi, Esther Sans Chemistry of Materials, Vol. 6, Issue 4 https://doi.org/10.1021/cm00040a025	journal	April 1994
Theoretical x-ray absorption fine structure standards Rehr, J. J.; Mustre de Leon, J.; Zabinsky, S. I. Journal of the American Chemical Society, Vol. 113, Issue 14 https://doi.org/10.1021/ja00014a001	journal	July 1991
Optimization of multicomponent aqueous suspensions of lithium iron phosphate (LiFePO₄) nanoparticles and carbon black for lithium-ion battery cathodes Li, Jianlin; Armstrong, Beth L.; Daniel, Claus Journal of Colloid and Interface Science, Vol. 405, p. 118-124 https://doi.org/10.1016/j.jcis.2013.05.030	journal	September 2013
Energy Dispersive X-ray Diffraction Profiling of Prototype LiMn ₂ O ₄ -Based Coin Cells Liang, Gan; Croft, Mark C.; Zhong, Zhong Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.115308jes	journal	January 2013
Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries Liu, Xin; Wu, Minghao; Li, Mingrun Journal of Materials Chemistry A, Vol. 1, Issue 33 https://doi.org/10.1039/c3ta00049d	journal	January 2013
Tracking inhomogeneity in high-capacity lithium iron phosphate batteries Paxton, William A.; Zhong, Zhong; Tsakalakos, Thomas Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.035	journal	February 2015
Operando identification of the point of [Mn2]O4 spinel formation during γ-MnO2 discharge within batteries Gallaway, Joshua W.; Hertzberg, Benjamin J.; Zhong, Zhong Journal of Power Sources, Vol. 321 https://doi.org/10.1016/j.jpowsour.2016.05.002	journal	July 2016
Hydrothermal synthesis, crystal structure and ionic conductivity of Ag2VO2PO4: a new layered phosphate of vanadium(V) Kang, Hsun-Yueh; Wang, Sue-Lein; Tsai, Ping-Ping Journal of the Chemical Society, Dalton Transactions, Issue 10 https://doi.org/10.1039/dt9930001525	journal	January 1993
Cooperation between Active Material, Polymeric Binder and Conductive Carbon Additive in Lithium Ion Battery Cathode Zheng, Honghe; Yang, Ruizhi; Liu, Gao The Journal of Physical Chemistry C, Vol. 116, Issue 7 https://doi.org/10.1021/jp208428w	journal	February 2012
Analysis of the passive surface film on a graphite electrode charged in polysiloxane-based electrolyte Nakahara, Hiroshi; Yoon, Sang-Young; Piao, Tracy Journal of Power Sources, Vol. 158, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.09.041	journal	July 2006
The Reduction of Silver Vanadium Oxide in Lithium/Silver Vanadium Oxide Cells Takeuchi, Esther Sans; Thiebolt III, William C. Journal of The Electrochemical Society, Vol. 135, Issue 11, p. 2691-2694 https://doi.org/10.1149/1.2095412	journal	January 1988
Electrochemical reduction of silver vanadium phosphorous oxide, Ag2VO2PO4: Silver metal deposition and associated increase in electrical conductivity Marschilok, Amy C.; Kozarsky, Eric S.; Tanzil, Kevin Journal of Power Sources, Vol. 195, Issue 19 https://doi.org/10.1016/j.jpowsour.2010.04.033	journal	October 2010
Silver Vanadium Phosphorous Oxide, Ag _0.48 VOPO ₄ : Exploration as a Cathode Material in Primary and Secondary Battery Applications Marschilok, Amy C.; Kim, Young Jin; Takeuchi, Kenneth J. Journal of The Electrochemical Society, Vol. 159, Issue 10 https://doi.org/10.1149/2.062210jes	journal	January 2012
Energy dispersive X-ray diffraction of lithium–silver vanadium phosphorous oxide cells: in situ cathode depth profiling of an electrochemical reduction–displacement reaction Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J. Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee40152a	journal	January 2013
Electrochemical performance of polypyrrole/silver vanadium oxide composite cathodes in lithium primary batteries Anguchamy, Yogesh K.; Lee, Jong-Won; Popov, Branko N. Journal of Power Sources, Vol. 184, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.06.034	journal	September 2008
Synthesis and Electrochemistry of Silver Ferrite Farley, K. E.; Marschilok, A. C.; Takeuchi, E. S. Electrochemical and Solid-State Letters, Vol. 15, Issue 2 https://doi.org/10.1149/2.010202esl	journal	January 2011
Ohmic Drop in LiFePO ₄ Based Lithium Battery Cathodes Containing Agglomerates Cornut, R.; Lepage, D.; Schougaard, S. B. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.081206jes	journal	January 2012
Preparation and Electrochemistry of Silver Vanadium Phosphorous Oxide, Ag[sub 2]VO[sub 2]PO[sub 4] Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S. Electrochemical and Solid-State Letters, Vol. 12, Issue 1 https://doi.org/10.1149/1.2998546	journal	January 2009
Silver vanadium oxide and silver vanadium phosphorous oxide dissolution kinetics: a mechanistic study with possible impact on future ICD battery lifetimes Bock, David C.; Takeuchi, Kenneth J.; Marschilok, Amy C. Dalton Transactions, Vol. 42, Issue 38 https://doi.org/10.1039/c3dt51544c	journal	January 2013
Effects of Various Conductive Additive and Polymeric Binder Contents on the Performance of a Lithium-Ion Composite Cathode Liu, G.; Zheng, H.; Kim, S. Journal of The Electrochemical Society, Vol. 155, Issue 12 https://doi.org/10.1149/1.2976031	journal	January 2008
Potential-Resolved In Situ X-ray Absorption Spectroscopy Study of Sn and SnO ₂ Nanomaterial Anodes for Lithium-Ion Batteries Pelliccione, Christopher J.; Timofeeva, Elena V.; Segre, Carlo U. The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.5b12279	journal	January 2016
Redox chemistry of a binary transition metal oxide (AB ₂ O ₄ ): a study of the Cu ²⁺ /Cu ⁰ and Fe ³⁺ /Fe ⁰ interconversions observed upon lithiation in a CuFe ₂ O ₄ battery using X-ray absorption spectroscopy Cama, Christina A.; Pelliccione, Christopher J.; Brady, Alexander B. Physical Chemistry Chemical Physics, Vol. 18, Issue 25 https://doi.org/10.1039/C6CP02974D	journal	January 2016
Development of carbon conductive additives for advanced lithium ion batteries Spahr, Michael E.; Goers, Dietrich; Leone, Antonio Journal of Power Sources, Vol. 196, Issue 7 https://doi.org/10.1016/j.jpowsour.2010.07.002	journal	April 2011
A reversible copper extrusion–insertion electrode for rechargeable Li batteries Morcrette, M.; Rozier, P.; Dupont, L. Nature Materials, Vol. 2, Issue 11 https://doi.org/10.1038/nmat1002	journal	October 2003
A comparative study of electrochemical properties of two kinds of carbon nanotubes as anode materials for lithium ion batteries Yang, Shubin; Huo, Junping; Song, Huaihe Electrochimica Acta, Vol. 53, Issue 5 https://doi.org/10.1016/j.electacta.2007.09.040	journal	January 2008
Ag ₄ V ₂ O ₆ F ₂ (SVOF): A High Silver Density Phase and Potential New Cathode Material for Implantable Cardioverter Defibrillators Sauvage, Frédéric; Bodenez, Vincent; Vezin, Hervé Inorganic Chemistry, Vol. 47, Issue 19 https://doi.org/10.1021/ic800793e	journal	October 2008
Synthetic control of composition and crystallite size of silver ferrite composites: profound electrochemistry impacts Durham, Jessica L.; Kirshenbaum, Kevin; Takeuchi, Esther S. Chemical Communications, Vol. 51, Issue 24 https://doi.org/10.1039/C4CC10277K	journal	January 2015
Understanding and recent development of carbon coating on LiFePO ₄ cathode materials for lithium-ion batteries Wang, Jiajun; Sun, Xueliang Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE01263K	journal	January 2012
Kinetics of rapid electrode reactions Randles, J. E. B. Discussions of the Faraday Society, Vol. 1 https://doi.org/10.1039/df9470100011	journal	January 1947
Electrochemical reduction of Ag ₂ VP ₂ O ₈ composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong Journal of Materials Chemistry A, Vol. 3, Issue 35 https://doi.org/10.1039/C5TA04523A	journal	January 2015
Using all energy in a battery Dudney, N. J.; Li, J. Science, Vol. 347, Issue 6218 https://doi.org/10.1126/science.aaa2870	journal	January 2015
Mapping the Inhomogeneous Electrochemical Reaction Through Porous LiFePO ₄ -Electrodes in a Standard Coin Cell Battery Strobridge, Fiona C.; Orvananos, Bernardo; Croft, Mark Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/cm504317a	journal	March 2015
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
Impedance spectroscopy and its use in analyzing the steady-state AC response of solid and liquid electrolytes Macdonald, J. Ross Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 223, Issue 1-2 https://doi.org/10.1016/0022-0728(87)85249-X	journal	May 1987
Discharge characteristics of silver vanadium oxide cathodes Ramasamy, R. P.; Feger, C.; Strange, T. Journal of Applied Electrochemistry, Vol. 36, Issue 4, p. 487-497 https://doi.org/10.1007/s10800-005-9103-x	journal	January 2006
In Situ Energy Dispersive X-ray Diffraction Study of Prototype LiMnO4- and LiFePO4-Based Coin Cell Batteries Liang, G.; Croft, M.; Zhong, Z. ECS Transactions, Vol. 50, Issue 26 https://doi.org/10.1149/05026.0293ecst	journal	April 2013
X-ray absorption spectroscopy of lithium insertion and de-insertion in copper birnessite nanoparticle electrodes Pelliccione, Christopher J.; Li, Yue Ru; Marschilok, Amy C. Physical Chemistry Chemical Physics, Vol. 18, Issue 4 https://doi.org/10.1039/C5CP05926G	journal	January 2016
Synthesis, Characterization, and Electrochemical Properties of Ag ₂ V ₄ O ₁₁ and AgVO ₃ 1-D Nano/Microstructures Zhang, Shaoyan; Li, Weiyang; Li, Chunsheng The Journal of Physical Chemistry B, Vol. 110, Issue 49 https://doi.org/10.1021/jp065478p	journal	December 2006
Particle Interaction and Aggregation in Cathode Material of Li-Ion Batteries: A Numerical Study Zhu, M.; Park, J.; Sastry, A. M. Journal of The Electrochemical Society, Vol. 158, Issue 10 https://doi.org/10.1149/1.3625286	journal	January 2011

Cited By (1)

Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries Bruck, Andrea M.; Li, Yue Ru; Brady, Alexander B. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0411914jes	journal	January 2019

Similar Records

Hybrid Ag₂VO₂PO₄/CF_x as a High Capacity and Energy Cathode for Primary Batteries

Journal Article · Fri Aug 18 00:00:00 EDT 2017 · Journal of the Electrochemical Society · OSTI ID:1347289

Li, Yue Ru; Bruck, Andrea M.; Brady, Alexander B.; +4 more

Silver vanadium diphosphate Ag{sub 2}VP{sub 2}O{sub 8}: Electrochemistry and characterization of reduced material providing mechanistic insights

Journal Article · Mon Apr 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:1347289

Lee, Chia-Ying; Cheng, Po-Jen; Menard, Melissa C.

Electrochemical Reduction of Ag₂VP₂O₈ Composite Electrodes Visualized via In situ Energy Dispersive X-ray Diffraction (EDXRD). Unexpected Conductive Additive Effects

Journal Article · Wed Jul 29 00:00:00 EDT 2015 · Journal of Materials Chemistry. A · OSTI ID:1347289

Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong; +3 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
batteries
composite
electrode
electrochemistry

Title: Li/Ag2VO2PO4 batteries: the roles of composite electrode constituents on electrochemistry

Citation Formats

References (63)

Cited By (1)

Similar Records

Related Subjects

Title: Li/Ag₂VO₂PO₄ batteries: the roles of composite electrode constituents on electrochemistry