Capacitance of Ti3C2Tx MXene in Ionic Liquid Electrolyte

Lin, Zifeng; Barbara, Daffos; Taberna, Pierre-Louis; Van Aken, Katherine; Anasori, Babak; Gogotsi, Yury G.; Simon, Patrice

doi:10.1016/j.jpowsour.2016.04.035

Title: Capacitance of Ti₃C₂T_x MXene in Ionic Liquid Electrolyte

Journal Article · Thu Apr 14 00:00:00 EDT 2016 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2016.04.035· OSTI ID:1346632

Lin, Zifeng ^[1]; Barbara, Daffos ^[1]; Taberna, Pierre-Louis ^[1]; Van Aken, Katherine ^[2]; Anasori, Babak ^[2]; Gogotsi, Yury G. ^[2]; Simon, Patrice ^[1]

Univ. Paul Sabatier, Toulouse (France)
Drexel Univ., Philadelphia, PA (United States)

Ti₃C₂T_x MXene, a two-dimensional (2D) early transition metal carbide, has shown an extremely high volumetric capacitance in aqueous electrolytes, but in a narrow voltage window (less than 1.23 V). The utilization of MXene materials in ionic liquid electrolytes with a large voltage window has never been addressed. Here, we report the preparation of the Ti₃C₂T_x MXene ionogel film by vacuum filtration for use as supercapacitor electrodes operating in 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-TFSI) neat ionic liquid electrolyte. Due to the disordered structure of the Ti₃C₂T_x hydrogel film and a stable spacing after vacuum drying, achieved through ionic liquid electrolyte immersion of the Ti₃C₂T_x hydrogel film, the Ti₃C₂T_x surface became accessible to EMI⁺ and TFSI^- ions. A capacitance of 70 F g^-1 together with a large voltage window of 3 V was obtained at a scan rate of 20 mV s^-1 in neat EMI-TFSI electrolyte. The electrochemical signature indicates a capacitive behavior even at a high scan rate (500 mV s^-1) and a high power performance. This work opens up the possibilities of using MXene materials with various ionic liquid electrolytes.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1346632

Alternate ID(s):: OSTI ID: 1359471

Journal Information:: Journal of Power Sources, Vol. 326; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 177 works

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25 ENERGY STORAGE
Supercapacitors
MXene
Ti3C2Tx
Ionogel
Ionic liquid

Title: Capacitance of Ti3C2Tx MXene in Ionic Liquid Electrolyte

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Title: Capacitance of Ti₃C₂T_x MXene in Ionic Liquid Electrolyte