One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent

Luo, Helen Y.; Michaelis, Vladimir K.; Hodges, Sydney; Griffin, Robert G.; Roman-Leshkov, Yuriy

doi:10.1039/C5SC01912E

Title: One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent

Journal Article · Wed Jul 22 00:00:00 EDT 2015 · Chemical Science

DOI:https://doi.org/10.1039/C5SC01912E· OSTI ID:1344503

Luo, Helen Y. ^[1]; Michaelis, Vladimir K. ^[2]; Hodges, Sydney ^[1]; Griffin, Robert G. ^[2]; Roman-Leshkov, Yuriy ^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemical Engineering
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemistry and Francis Bitter Magnet Lab.

A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is synthesized in one-pot using a rationally designed organic structure-directing agent (OSDA). The OSDA is comprised of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m²g^-1, and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. In conclusion, compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel-Crafts alkylation of benzene with benzyl alcohol.

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Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH)

Grant/Contract Number:: SC0008742

OSTI ID:: 1344503

Journal Information:: Chemical Science, Vol. 6, Issue 11; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 111 works

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