In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition
- Univ. of Maryland, College Park, MD (United States)
- Univ. of Maryland, College Park, MD (United States); The Johns Hopkins Univ., Laurel, MD (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Here, the insertion/extraction of lithium into/from various host materials is the basic process by which lithium-ion batteries reversible store charge. This process is generally accompanied by strain in the host material, inducing stress which can lead to capacity loss. Therefore, understanding of both the structural changes and the associated stress – investigated almost exclusively separate to date – is a critical factor for developing high-performance batteries. Here, we report an in situ method, which utilizes Raman spectroscopy in parallel with optical interferometry to study effects of varying charging rates (C-rates) on the structure and stress in a V2O5 thin film cathode. Abrupt stress changes at specific crystal phase transitions in the Li—V—O system are observed and the magnitude of the stress changes with the amount of lithium inserted into the electrode are correlated. A linear increase in the stress as a function of x in LixV2O5 is observed, indicating that C-rate does not directly contribute to larger intercalation stress. However, a more rapid increase in disorder within the LixV2O5 layers is correlated with higher C-rate. Ultimately, these experiments demonstrate how the simultaneous stress/Raman in situ approach can be utilized as a characterization platform for investigating various critical factors affecting lithium-ion battery performance.
- Research Organization:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- Grant/Contract Number:
- AC04-94AL85000; SC0001160; DESC0001160
- OSTI ID:
- 1343624
- Alternate ID(s):
- OSTI ID: 1410839
- Report Number(s):
- SAND-2017-0811J; 650724
- Journal Information:
- Journal of Power Sources, Vol. 340, Issue C; ISSN 0378-7753
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
Interfacial Incompatibility and Internal Stresses in All‐Solid‐State Lithium Ion Batteries
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journal | August 2019 |
Real-time monitoring of stress development during electrochemical cycling of electrode materials for Li-ion batteries: overview and perspectives
|
journal | January 2019 |
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