CO2 hydrogenation on Pt, Pt/SiO2 and Pt/TiO2: Importance of synergy between Pt and oxide support

Kattel, Shyam; Yan, Binhang; Chen, Jingguang G.; Liu, Ping

doi:10.1016/j.jcat.2015.12.019

Title: CO₂ hydrogenation on Pt, Pt/SiO₂ and Pt/TiO₂: Importance of synergy between Pt and oxide support

Journal Article · Wed Jan 27 00:00:00 EST 2016 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2015.12.019· OSTI ID:1341672

Kattel, Shyam ^[1]; Yan, Binhang ^[2]; Chen, Jingguang G. ^[3]; Liu, Ping ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Tsinghua Univ., Beijing (China). Dept. of Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering

In this paper we combined density functional theory (DFT), kinetic Monte Carlo (KMC) simulations and experimental measurements to gain insight into the mechanisms of CO₂ conversion by hydrogen on the Pt nanoparticle (NP). The results show that in spite of the presence of active, low-coordinated sites, Pt NP alone is not able to catalyze the reaction due to the weak CO₂ binding on the catalyst. Once CO₂ is stabilized, the hydrogenation of CO₂ to CO via the reverse-water–gas shift (RWGS) reaction is promoted; in contrast, the enhancement for further *CO hydrogenation to CH₄ is less significant and no CH₃OH is observed. The selectivity to CO is mainly determined by CO binding energy and the energetics of *CO hydrogenation to *HCO, while that for CH₄ and CH₃OH is determined by the competition between hydrogenation and C–O bond scission reactions of the *H₂COH species. Using SiO₂ and TiO₂ as the support, Pt NP is able to promote the overall CO₂ conversion, while the impact on the selectivity is rather small. The theoretically predicted trend in activity and selectivity is in good agreement with the experimental results. Finally, the enhanced activity of Pt/oxide over Pt is originated from the sites at the Pt–oxide interface, where the synergy between Pt and oxide plays an important role.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Contributing Organization:: Tsinghua Univ., Beijing (China); Columbia Univ., New York, NY (United States)

Grant/Contract Number:: SC0012704; AC02-05CH11231; AC05-00OR22725

OSTI ID:: 1341672

Alternate ID(s):: OSTI ID: 1398838

Report Number(s):: BNL-113400-2017-JA; R&D Project: CO035; KC0302010

Journal Information:: Journal of Catalysis, Vol. 343; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 210 works

Citation information provided by
Web of Science

References (72)

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 Graciani, J.; Mudiyanselage, K.; Xu, F. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1253057	journal	July 2014
Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts Porosoff, Marc D.; Chen, Jingguang G. Journal of Catalysis, Vol. 301 https://doi.org/10.1016/j.jcat.2013.01.022	journal	May 2013
The Mechanism of CO and CO ₂ Hydrogenation to Methanol over Cu-Based Catalysts Studt, Felix; Behrens, Malte; Kunkes, Edward L. ChemCatChem, Vol. 7, Issue 7 https://doi.org/10.1002/cctc.201500123	journal	March 2015
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank Nature Chemistry, Vol. 6, Issue 4 https://doi.org/10.1038/nchem.1873	journal	March 2014
The Active Site of Methanol Synthesis over Cu/ZnO/Al₂O₃ Industrial Catalysts Behrens, M.; Studt, F.; Kasatkin, I. Science, Vol. 336, Issue 6083, p. 893-897 https://doi.org/10.1126/science.1219831	journal	April 2012
Progress in carbon dioxide separation and capture: A review Yang, Hongqun; Xu, Zhenghe; Fan, Maohong Journal of Environmental Sciences, Vol. 20, Issue 1, p. 14-27 https://doi.org/10.1016/S1001-0742(08)60002-9	journal	January 2008
CO ₂ Hydrogenation to Methanol on Supported Au Catalysts under Moderate Reaction Conditions: Support and Particle Size Effects Hartadi, Yeusy; Widmann, Daniel; Behm, R. Jürgen ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402645	journal	October 2014
Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41272e	journal	January 2013
Heterogeneous catalytic CO2 conversion to value-added hydrocarbons Dorner, Robert W.; Hardy, Dennis R.; Williams, Frederick W. Energy & Environmental Science, Vol. 3, Issue 7 https://doi.org/10.1039/c001514h	journal	January 2010
Effective conversion of carbon dioxide and hydrogen to hydrocarbons Inui, Tomoyuki; Takeguchi, Tatsuya Catalysis Today, Vol. 10, Issue 1 https://doi.org/10.1016/0920-5861(91)80077-M	journal	August 1991
Catalysis for the Valorization of Exhaust Carbon: from CO ₂ to Chemicals, Materials, and Fuels. Technological Use of CO ₂ Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella Chemical Reviews, Vol. 114, Issue 3 https://doi.org/10.1021/cr4002758	journal	November 2013
Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries Centi, Gabriele; Quadrelli, Elsje Alessandra; Perathoner, Siglinda Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee00056g	journal	January 2013
Heterogeneous catalytic conversion of CO ₂ : a comprehensive theoretical review Li, Yawei; Chan, Siew Hwa; Sun, Qiang Nanoscale, Vol. 7, Issue 19 https://doi.org/10.1039/C5NR00092K	journal	January 2015
Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing Song, Chunshan Catalysis Today, Vol. 115, Issue 1-4 https://doi.org/10.1016/j.cattod.2006.02.029	journal	June 2006
Mitigation of CO₂ by Chemical Conversion: Plausible Chemical Reactions and Promising Products Xiaoding, Xu; Moulijn, J. A. Energy & Fuels, Vol. 10, Issue 2, p. 305-325 https://doi.org/10.1021/ef9501511	journal	March 1996
Methanol synthesis from CO2 hydrogenation over a Pd4/In2O3 model catalyst: A combined DFT and kinetic study Ye, Jingyun; Liu, Chang-jun; Mei, Donghai Journal of Catalysis, Vol. 317 https://doi.org/10.1016/j.jcat.2014.06.002	journal	August 2014
Mechanism of Methanol Synthesis on Cu through CO ₂ and CO Hydrogenation Grabow, L. C.; Mavrikakis, M. ACS Catalysis, Vol. 1, Issue 4 https://doi.org/10.1021/cs200055d	journal	February 2011
Selectivity of CO ₂ Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps Nie, Xiaowa; Esopi, Monica R.; Janik, Michael J. Angewandte Chemie International Edition, Vol. 52, Issue 9 https://doi.org/10.1002/anie.201208320	journal	January 2013
(Non)formation of Methanol by Direct Hydrogenation of Formate on Copper Catalysts Yang, Yong; Mims, C. A.; Disselkamp, R. S. The Journal of Physical Chemistry C, Vol. 114, Issue 40 https://doi.org/10.1021/jp104068k	journal	July 2010
Isotope Effects in Methanol Synthesis and the Reactivity of Copper Formates on a Cu/SiO2 Catalyst Yang, Y.; Mims, C. A.; Disselkamp, R. S. Catalysis Letters, Vol. 125, Issue 3-4 https://doi.org/10.1007/s10562-008-9592-4	journal	August 2008
Mechanistic studies of methanol synthesis over Cu from CO/CO2/H2/H2O mixtures: The source of C in methanol and the role of water Yang, Y.; Mims, C. A.; Mei, D. H. Journal of Catalysis, Vol. 298 https://doi.org/10.1016/j.jcat.2012.10.028	journal	February 2013
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄) Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A. Physical Chemistry Chemical Physics, Vol. 12, Issue 33 https://doi.org/10.1039/c001484b	journal	January 2010
Theoretical Study of Methanol Synthesis from CO ₂ Hydrogenation on Metal-Doped Cu(111) Surfaces Yang, Yixiong; White, Michael G.; Liu, Ping The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp208448c	journal	December 2011
A study of the selectivity of the reverse water–gas-shift reaction over Pt/TiO2 catalysts Kim, Sung Su; Park, Kwang Hee; Hong, Sung Chang Fuel Processing Technology, Vol. 108 https://doi.org/10.1016/j.fuproc.2012.04.003	journal	April 2013
Plasmon-enhanced reverse water gas shift reaction over oxide supported Au catalysts Upadhye, Aniruddha A.; Ro, Insoo; Zeng, Xu Catalysis Science & Technology, Vol. 5, Issue 5 https://doi.org/10.1039/C4CY01183J	journal	January 2015
Production of Liquid Hydrocarbons with CO ₂ as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis Kaiser, Philipp; Unde, Rajabhau Bajirao; Kern, Christoph Chemie Ingenieur Technik, Vol. 85, Issue 4 https://doi.org/10.1002/cite.201200179	journal	March 2013
Ethanol steam reforming over Rh and Pt catalysts: effect of temperature and catalyst deactivation Bilal, Muhammad; Jackson, S. David Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20703F	journal	January 2013
High-Temperature Catalytic Reforming of n -Hexane over Supported and Core–Shell Pt Nanoparticle Catalysts: Role of Oxide–Metal Interface and Thermal Stability An, Kwangjin; Zhang, Qiao; Alayoglu, Selim Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl502434m	journal	July 2014
Mechanism of the Water Gas Shift Reaction on Pt: First Principles, Experiments, and Microkinetic Modeling Grabow, Lars C.; Gokhale, Amit A.; Evans, Steven T. The Journal of Physical Chemistry C, Vol. 112, Issue 12 https://doi.org/10.1021/jp7099702	journal	March 2008
Kinetics of the water–gas shift reaction on Pt catalysts supported on alumina and ceria Phatak, A. A.; Koryabkina, N.; Rai, S. Catalysis Today, Vol. 123, Issue 1-4, p. 224-234 https://doi.org/10.1016/j.cattod.2007.02.031	journal	May 2007
Mechanism for the water–gas shift reaction on monofunctional platinum and cause of catalyst deactivation Flaherty, David W.; Yu, Wen-Yueh; Pozun, Zachary D. Journal of Catalysis, Vol. 282, Issue 2 https://doi.org/10.1016/j.jcat.2011.06.024	journal	September 2011
Production of Syngas by Direct Catalytic Oxidation of Methane Hickman, D. A.; Schmidt, L. D. Science, Vol. 259, Issue 5093 https://doi.org/10.1126/science.259.5093.343	journal	January 1993
Molecular beam study of CH4 oxidation on a Pt(111)–(2×2)-O surface Kondo, Takahiro; Sasaki, Takashi; Yamamoto, Shigehiko The Journal of Chemical Physics, Vol. 118, Issue 2 https://doi.org/10.1063/1.1527894	journal	January 2003
Methane Oxidation Mechanism on Pt(111): A Cluster Model DFT Study Psofogiannakis, George; St-Amant, Alain; Ternan, Marten The Journal of Physical Chemistry B, Vol. 110, Issue 48 https://doi.org/10.1021/jp061559+	journal	November 2006
Kinetics and reaction pathways of methanol oxidation on platinum McCabe, R. W.; McCready, D. F. The Journal of Physical Chemistry, Vol. 90, Issue 7 https://doi.org/10.1021/j100398a043	journal	March 1986
Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos Nature Materials, Vol. 7, Issue 4, p. 333-338 https://doi.org/10.1038/nmat2156	journal	March 2008
Preferential CO Oxidation in Hydrogen: Reactivity of Core−Shell Nanoparticles Nilekar, Anand Udaykumar; Alayoglu, Selim; Eichhorn, Bryan Journal of the American Chemical Society, Vol. 132, Issue 21, p. 7418-7428 https://doi.org/10.1021/ja101108w	journal	June 2010
Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters Allian, Ayman D.; Takanabe, Kazuhiro; Fujdala, Kyle L. Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja110073u	journal	March 2011
Surface Composition Tuning of Au–Pt Bimetallic Nanoparticles for Enhanced Carbon Monoxide and Methanol Electro-oxidation Suntivich, Jin; Xu, Zhichuan; Carlton, Christopher E. Journal of the American Chemical Society, Vol. 135, Issue 21 https://doi.org/10.1021/ja402072r	journal	May 2013
Spectrokinetic Investigation of Reverse Water-Gas-Shift Reaction Intermediates over a Pt/CeO ₂ Catalyst Goguet, Alexandre; Meunier, Frederic C.; Tibiletti, Daniele The Journal of Physical Chemistry B, Vol. 108, Issue 52 https://doi.org/10.1021/jp047242w	journal	December 2004
Modeling CO2 reduction on Pt(111) Shi, Chuan; O'Grady, Christopher P.; Peterson, Andrew A. Physical Chemistry Chemical Physics, Vol. 15, Issue 19 https://doi.org/10.1039/c3cp50645b	journal	January 2013
Investigation of the Initial Steps of the Electrochemical Reduction of CO ₂ on Pt Electrodes Dhar, Kalyan; Cavallotti, Carlo The Journal of Physical Chemistry A, Vol. 118, Issue 38 https://doi.org/10.1021/jp505347k	journal	September 2014
Electronic Metal–Support Interactions and the Production of Hydrogen Through the Water-Gas Shift Reaction and Ethanol Steam Reforming: Fundamental Studies with Well-Defined Model Catalysts Senanayake, Sanjaya D.; Rodriguez, José A.; Stacchiola, Dario Topics in Catalysis, Vol. 56, Issue 15-17 https://doi.org/10.1007/s11244-013-0148-5	journal	August 2013
Bench-scale study of electrochemically assisted catalytic CO2 hydrogenation to hydrocarbon fuels on Pt, Ni and Pd films deposited on YSZ Ruiz, Esperanza; Cillero, Domingo; Martínez, Pedro J. Journal of CO2 Utilization, Vol. 8 https://doi.org/10.1016/j.jcou.2014.09.001	journal	December 2014
A New Type of Strong Metal–Support Interaction and the Production of H ₂ through the Transformation of Water on Pt/CeO ₂ (111) and Pt/CeO _x /TiO ₂ (110) Catalysts Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J. Journal of the American Chemical Society, Vol. 134, Issue 21 https://doi.org/10.1021/ja302070k	journal	May 2012
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Oxygen Reduction on Well-Defined Core−Shell Nanocatalysts: Particle Size, Facet, and Pt Shell Thickness Effects Wang, Jia X.; Inada, Hiromi; Wu, Lijun Journal of the American Chemical Society, Vol. 131, Issue 47 https://doi.org/10.1021/ja9067645	journal	December 2009
Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes Sasaki, Kotaro; Naohara, Hideo; Cai, Yun Angewandte Chemie International Edition, Vol. 49, Issue 46, p. 8602-8607 https://doi.org/10.1002/anie.201004287	journal	October 2010
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Efficient Monte Carlo methods for the simulation of catalytic surface reactions Lukkien, J. J.; Segers, J. P. L.; Hilbers, P. A. J. Physical Review E, Vol. 58, Issue 2 https://doi.org/10.1103/PhysRevE.58.2598	journal	August 1998
Adsorption of Atomic Oxygen and Nitrogen at β-Cristobalite (100): A Density Functional Theory Study Arasa, C.; Gamallo, P.; Sayós, R. The Journal of Physical Chemistry B, Vol. 109, Issue 31 https://doi.org/10.1021/jp044064y	journal	August 2005
CO Oxidation at the Au/TiO ₂ Boundary: The Role of the Au/Ti _5c Site Duan, Zhiyao; Henkelman, Graeme ACS Catalysis, Vol. 5, Issue 3 https://doi.org/10.1021/cs501610a	journal	February 2015
CO2 fixation into methanol at Cu/ZrO2 interface from first principles kinetic Monte Carlo Tang, Qian-Lin; Hong, Qi-Jun; Liu, Zhi-Pan Journal of Catalysis, Vol. 263, Issue 1 https://doi.org/10.1016/j.jcat.2009.01.017	journal	April 2009
Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O Zhao, Ya-Fan; Yang, Yong; Mims, Charles Journal of Catalysis, Vol. 281, Issue 2 https://doi.org/10.1016/j.jcat.2011.04.012	journal	July 2011
CO ₂ Electrochemical Reduction to Methane and Methanol on Copper-Based Alloys: Theoretical Insight Hirunsit, Pussana; Soodsawang, Wiwaporn; Limtrakul, Jumras The Journal of Physical Chemistry C, Vol. 119, Issue 15 https://doi.org/10.1021/acs.jpcc.5b01574	journal	April 2015
The adsorption of CO, O2, and H2 on Pt Collins, D. M.; Spicer, W. E. Surface Science, Vol. 69, Issue 1 https://doi.org/10.1016/0039-6028(77)90163-7	journal	December 1977
Reverse water-gas shift reaction: steady state isotope switching study of the reverse water-gas shift reaction using in situ DRIFTS and a Pt/ceria catalyst Jacobs, Gary; Davis, Burtron H. Applied Catalysis A: General, Vol. 284, Issue 1-2 https://doi.org/10.1016/j.apcata.2005.01.013	journal	April 2005
On the complexity of the water-gas shift reaction mechanism over a Pt/CeO2 catalyst: Effect of the temperature on the reactivity of formate surface species studied by operando DRIFT during isotopic transient at chemical steady-state Meunier, F. C.; Tibiletti, D.; Goguet, A. Catalysis Today, Vol. 126, Issue 1-2 https://doi.org/10.1016/j.cattod.2006.10.003	journal	August 2007
Mechanism of Ethanol Synthesis from Syngas on Rh(111) Choi, YongMan; Liu, Ping Journal of the American Chemical Society, Vol. 131, Issue 36 https://doi.org/10.1021/ja903013x	journal	September 2009
The surface chemistry of amorphous silica. Zhuravlev model Zhuravlev, L. T. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 173, Issue 1-3 https://doi.org/10.1016/S0927-7757(00)00556-2	journal	November 2000
Vibrational study of ammonia adsorption on Pt/SiO2 Wallin, Mikaela; Grönbeck, Henrik; Lloyd Spetz, Anita Applied Surface Science, Vol. 235, Issue 4 https://doi.org/10.1016/j.apsusc.2004.03.225	journal	August 2004
Catalytic role of lattice defects in the photoassisted oxidation of water at (001) n-titanium(IV) oxide rutile Salvador, P.; Garcia Gonzalez, M. L.; Munoz, F. The Journal of Physical Chemistry, Vol. 96, Issue 25 https://doi.org/10.1021/j100204a046	journal	December 1992
Local Structure of Defects on Hydrogen- and Vacuum-Reduced TiO2 Surfaces Zhong, Qian; Vohs, John M.; Bonnell, Dawn A. Journal of the American Ceramic Society, Vol. 76, Issue 5 https://doi.org/10.1111/j.1151-2916.1993.tb03731.x	journal	May 1993
The surface science of titanium dioxide Diebold, Ulrike Surface Science Reports, Vol. 48, Issue 5-8 https://doi.org/10.1016/S0167-5729(02)00100-0	journal	January 2003
In-situ surface and gas phase analysis for kinetic studies under transient conditions The catalytic hydrogenation of CO2 Marwood, Michel; Doepper, Ralf; Renken, Albert Applied Catalysis A: General, Vol. 151, Issue 1 https://doi.org/10.1016/S0926-860X(96)00267-0	journal	March 1997
Effect of Surface Hydroxyls on CO ₂ Hydrogenation Over Cu/γ-Al ₂ O ₃ Catalyst: A Theoretical Study Zhang, Riguang; Wang, Baojun; Liu, Hongyan The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp206065y	journal	September 2011

Cited By (16)

Selective Hydrogenation of Carbon Dioxide into Methanol Pham Minh, Doan; Roger, Anne-Cécile; Parkhomenko, Ksenia Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology, p. 111-157 https://doi.org/10.1007/978-3-030-28638-5_5	book	January 2020
Preparation of a Cu(BTC)-rGO catalyst loaded on a Pt deposited Cu foam cathode to reduce CO ₂ in a photoelectrochemical cell Cheng, Jun; Xuan, Xiaoxu; Yang, Xiao RSC Advances, Vol. 8, Issue 56 https://doi.org/10.1039/c8ra05964k	journal	January 2018
Room temperature CO oxidation catalysed by supported Pt nanoparticles revealed by solid-state NMR and DNP spectroscopy Klimavicius, Vytautas; Neumann, Sarah; Kunz, Sebastian Catalysis Science & Technology, Vol. 9, Issue 14 https://doi.org/10.1039/c9cy00684b	journal	January 2019
CO ₂ adsorption on gas-phase Cu _4−x Pt _x ( x = 0–4) clusters: a DFT study Gálvez-González, Luis E.; Juárez-Sánchez, J. Octavio; Pacheco-Contreras, Rafael Physical Chemistry Chemical Physics, Vol. 20, Issue 25 https://doi.org/10.1039/c8cp00818c	journal	January 2018
Pyrolysis of metal–organic frameworks to hierarchical porous Cu/Zn-nanoparticle@carbon materials for efficient CO ₂ hydrogenation Zhang, Jingzheng; An, Bing; Hong, Yahui Materials Chemistry Frontiers, Vol. 1, Issue 11 https://doi.org/10.1039/c7qm00328e	journal	January 2017
MOFs-Based Heterogeneous Catalysts: New Opportunities for Energy-Related CO ₂ Conversion Lei, Zhendong; Xue, Yuancheng; Chen, Wenqian Advanced Energy Materials, Vol. 8, Issue 32 https://doi.org/10.1002/aenm.201801587	journal	October 2018
Hydrogenation of Carbon Dioxide to Value-Added Chemicals by Heterogeneous Catalysis and Plasma Catalysis Liu, Miao; Yi, Yanhui; Wang, Li Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030275	journal	March 2019
Unravelling the Promotional Effect of La ₂ O ₃ in Pt/La‐TiO ₂ Catalysts for CO ₂ Hydrogenation Wang, Zhaoyu; Huang, Lijuan; Su, Bo Chemistry – A European Journal, Vol. 26, Issue 2 https://doi.org/10.1002/chem.201903946	journal	November 2019
DFT and microkinetic investigation of methanol synthesis via CO ₂ hydrogenation on Ni(111)-based surfaces Maulana, Arifin Luthfi; Putra, Refaldi Intri Dwi; Saputro, Adhitya Gandaryus Physical Chemistry Chemical Physics, Vol. 21, Issue 36 https://doi.org/10.1039/c9cp02970b	journal	January 2019
Ordered Mesoporous CeO ₂ ‐supported Ag as an Effective Catalyst for Carboxylative Coupling Reaction Using CO ₂ Zhang, Xiao; Wang, Dingkun; Jing, Meizan ChemCatChem, Vol. 11, Issue 8 https://doi.org/10.1002/cctc.201900039	journal	April 2019
Highly efficient binary copper−iron catalyst for photoelectrochemical carbon dioxide reduction toward methane Zhou, Baowen; Ou, Pengfei; Pant, Nick Proceedings of the National Academy of Sciences, Vol. 117, Issue 3 https://doi.org/10.1073/pnas.1911159117	journal	January 2020
Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity Chen, Yizhen; Li, Hongliang; Zhao, Wanghui Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09918-z	journal	April 2019
Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals Nielsen, Dennis U.; Hu, Xin-Ming; Daasbjerg, Kim Nature Catalysis, Vol. 1, Issue 4 https://doi.org/10.1038/s41929-018-0051-3	journal	April 2018
Synthesis of Aluminium Doped Na-Titanate Nanorods and Its Application as Potential CO2 Hydrogenation Catalysts Guzmán-Cruz, M. A.; Ramesh-Kumar, Ch.; Acosta-Alejandro, M. Catalysis Letters, Vol. 149, Issue 12 https://doi.org/10.1007/s10562-019-02902-8	journal	July 2019
A theoretical study of the reverse water‐gas shift reaction on Ni(111) and Ni(311) surfaces Zhang, Min; Zijlstra, Bart; Filot, Ivo A. W. The Canadian Journal of Chemical Engineering, Vol. 98, Issue 3 https://doi.org/10.1002/cjce.23655	journal	November 2019
Highly Efficient Carbon Dioxide Hydrogenation to Methanol Catalyzed by Zigzag Platinum-Cobalt Nanowires Bai, Shuxing; Shao, Qi; Feng, Yonggang Small, Vol. 13, Issue 22 https://doi.org/10.1002/smll.201604311	journal	April 2017

Similar Records

A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces

Journal Article · Thu Jan 12 00:00:00 EST 2012 · Journal of Physical Chemistry C · OSTI ID:1341672

Liu, P; Yang, Y; White, M G

Optimizing Binding Energies of Key Intermediates for CO₂ Hydrogenation to Methanol over Oxide-Supported Copper

Journal Article · Mon Aug 29 00:00:00 EDT 2016 · Journal of the American Chemical Society · OSTI ID:1341672

Kattel, Shyam; Yan, Binhang; Yang, Yixiong; +2 more

Cesium-Induced Active Sites for C–C Coupling and Ethanol Synthesis from CO₂ Hydrogenation on Cu/ZnO(000$\bar{1}$) Surfaces

Journal Article · Fri Jul 23 00:00:00 EDT 2021 · Journal of the American Chemical Society · OSTI ID:1341672

Wang, Xuelong; Ramírez, Pedro J.; Liao, Wenjie; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2 activation
Selectivity
Activity
Kinetics
DFT
Platinum

Title: CO2 hydrogenation on Pt, Pt/SiO2 and Pt/TiO2: Importance of synergy between Pt and oxide support

Citation Formats

References (72)

Cited By (16)

Similar Records

Related Subjects

Title: CO₂ hydrogenation on Pt, Pt/SiO₂ and Pt/TiO₂: Importance of synergy between Pt and oxide support