CO Oxidation and Subsequent CO2 Chemisorption on Alkaline Zirconates: Li2 ZrO3 and Na2 ZrO3

Alcántar-Vázquez, Brenda; Duan, Yuhua; Pfeiffer, Heriberto

doi:10.1021/acs.iecr.6b02257

Title: CO Oxidation and Subsequent CO₂ Chemisorption on Alkaline Zirconates: Li₂ ZrO₃ and Na₂ ZrO₃

Journal Article · Fri Aug 26 00:00:00 EDT 2016 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.6b02257· OSTI ID:1335455

Alcántar-Vázquez, Brenda ^[1]; Duan, Yuhua ^[2]; Pfeiffer, Heriberto ^[3]

Univ. Nacional Autonoma de Mexico (UNAM), Mexico City (Mexico). Inst. de Ingenieria, Coordinacion de Ingenieria Ambiental
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
Univ. Nacional Autonoma de Mexico (UNAM), Mexico City (Mexico). Inst. de Investigaciones en Materiales

Here, two different alkaline zirconates (Li₂ZrO₃ and Na₂ZrO₃) were studied as possible bifunctional catalytic-captor materials for CO oxidation and the subsequent CO₂ chemisorption process. Initially, CO oxidation reactions were analyzed in a catalytic reactor coupled to a gas chromatograph, using Li₂ZrO₃ and Na₂ZrO₃, under different O₂ partial flows. We found results clearly showed that Na₂ZrO₃ possesses much better catalytic properties than Li₂ZrO₃. After the CO-O₂ oxidation catalytic analysis, CO2 chemisorption process was analyzed by thermogravimetric analysis, only for the Na₂ZrO₃ ceramic. The results confirmed that Na₂ZrO₃ is able to work as a bifunctional material (CO oxidation and subsequent CO₂ chemisorption), although the kinetic CO₂ capture process was not the best one under the physicochemical condition used in this case. For Na₂ZrO₃, the best CO conversions were found between 445 and 580 °C (100%), while Li₂ZrO₃ only showed a 35% of efficiency between 460 and 503 °C. However, in the Na₂ZrO₃ case, at temperatures higher than 580 °C its catalytic activity gradually decreases as a result of CO₂ capture process. Finally, all these experiments were compared and supported with theoretical thermodynamic data.

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

OSTI ID:: 1335455

Report Number(s):: NETL-PUB-20375

Journal Information:: Industrial and Engineering Chemistry Research, Vol. 55, Issue 37; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 36 works

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CO2–CO capture and kinetic analyses of sodium cobaltate under various partial pressures Vera, Elizabeth; García, Susana; Maroto-Valer, M. Mercedes Adsorption, Vol. 26, Issue 5 https://doi.org/10.1007/s10450-019-00167-6	journal	September 2019
Recent advances in lithium containing ceramic based sorbents for high-temperature CO ₂ capture Zhang, Yu; Gao, Yanshan; Pfeiffer, Heriberto Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c8ta08932a	journal	January 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO oxidation
sodium zirconate
lithium zirconate
CO2 chemisorption
thermal analysis
ab initio thermodynamics

Title: CO Oxidation and Subsequent CO2 Chemisorption on Alkaline Zirconates: Li2 ZrO3 and Na2 ZrO3

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Title: CO Oxidation and Subsequent CO₂ Chemisorption on Alkaline Zirconates: Li₂ ZrO₃ and Na₂ ZrO₃