Helium sequestration at nanoparticle-matrix interfaces in helium + heavy ion irradiated nanostructured ferritic alloys

Parish, Chad M.; Unocic, Kinga A.; Tan, Lizhen; Zinkle, S. J.; Kondo, Sosuke; Snead, Lance Lewis; Hoelzer, David T.; Katoh, Yutai

doi:10.1016/j.jnucmat.2016.10.038

Title: Helium sequestration at nanoparticle-matrix interfaces in helium + heavy ion irradiated nanostructured ferritic alloys

Journal Article · Mon Oct 24 00:00:00 EDT 2016 · Journal of Nuclear Materials

DOI:https://doi.org/10.1016/j.jnucmat.2016.10.038· OSTI ID:1333064

Parish, Chad M. ^[1]; Unocic, Kinga A. ^[1]; Tan, Lizhen ^[1]; Zinkle, S. J. ^[2]; Kondo, Sosuke ^[3]; Snead, Lance Lewis ^[4]; Hoelzer, David T. ^[1]; Katoh, Yutai ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Kyoto Univ. (Japan)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Here we irradiated four ferritic alloys with energetic Fe and He ions: one castable nanostructured alloy (CNA) containing Ti-W-Ta-carbides, and three nanostructured ferritic alloys (NFAs). The NFAs were: 9Cr containing Y-Ti-O nanoclusters, and two Fe-12Cr-5Al NFAs containing Y-Zr-O or Y-Hf-O clusters. All four were subjected to simultaneous dual-beam Fe + He ion implantation (650 °C, ~50 dpa, ~15 appm He/dpa), simulating fusion-reactor conditions. Examination using scanning/transmission electron microscopy (STEM) revealed high-number-density helium bubbles of ~8 nm, ~10²¹ m^-3 (CNA), and of ~3 nm, 10²³ m^-3 (NFAs). STEM combined with multivariate statistical analysis data mining suggests that the precipitate-matrix interfaces in all alloys survived ~50 dpa at 650 °C and serve as effective helium trapping sites. All alloys appear viable structural material candidates for fusion or advanced fission energy systems. Finally, among these developmental alloys the NFAs appear to sequester the helium into smaller bubbles and away from the grain boundaries more effectively than the early-generation CNA.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Nuclear Science User Facility (NSUF)

Sponsoring Organization:: USDOE Office of Science (SC), Fusion Energy Sciences (FES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1333064

Alternate ID(s):: OSTI ID: 1414023

Journal Information:: Journal of Nuclear Materials, Vol. 483; ISSN 0022-3115

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 36 works

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