Structural manipulation approaches towards enhanced sodium ionic conductivity in Na-rich antiperovskites

Wang, Yonggang; Wang, Qingfei; Liu, Zhenpu; Zhou, Zhengyang; Li, Shuai; Zhu, Jinlong; Zou, Ruqiang; Wang, Yingxia; Lin, Jianhua; Zhao, Yusheng

doi:10.1016/j.jpowsour.2015.06.002

Title: Structural manipulation approaches towards enhanced sodium ionic conductivity in Na-rich antiperovskites

Journal Article · Wed Jun 10 00:00:00 EDT 2015 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2015.06.002· OSTI ID:1332398

Wang, Yonggang ^[1]; Wang, Qingfei ^[2]; Liu, Zhenpu ^[2]; Zhou, Zhengyang ^[2]; Li, Shuai ^[3]; Zhu, Jinlong ^[3]; Zou, Ruqiang ^[2]; Wang, Yingxia ^[2]; Lin, Jianhua ^[2]; Zhao, Yusheng ^[3]

Peking Univ., Beijing (China); Univ. of Nevada, Las Vegas, NV (United States)
Peking Univ., Beijing (China)
Univ. of Nevada, Las Vegas, NV (United States)

High-performance solid electrolytes are critical for realizing all-solid-state batteries with enhance safety and cycling efficiency. However, currently available candidates (sulfides and the NASICON-typ ceramics) still suffer from drawbacks such as inflammability, high-cost and unfavorable machinability Here we present the structural manipulation approaches to improve the sodium ionic conductivity in series of affordable Na-rich antiperovskites. Experimentally, the whole solid solutions of Na₃OX (X ¼ Cl Br, I) are synthesized via a facile and timesaving route from the cheapest raw materials (Na, NaOH an NaX). The materials are nonflammable, suitable for thermoplastic processing due to low melting temperature (<300° C) without decomposing. Notably, owing to the flexibility of perovskite-type structure it's feasible to control the local structure features by means of size-mismatch substitution an unequivalent-doping for a favorable sodium ionic diffusion pathway. Enhancement of sodium ioni conductivity by 2 magnitudes is demonstrated by these chemical tuning methods. The optimized sodiu ionic conductivity in Na_2.9Sr_0.05OBr_0.6I_0.4 bulk samples reaches 1.9 10^{- 3} S/cm at 200° C and even highe at elevated temperature. Here, we believe further chemical tuning efforts on Na-rich antiperovskites wil promote their performance greatly for practical all-solid state battery applications.

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Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001982

OSTI ID:: 1332398

Journal Information:: Journal of Power Sources, Vol. 293, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 72 works

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References (24)

Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
A review of advanced and practical lithium battery materials Marom, Rotem; Amalraj, S. Francis; Leifer, Nicole Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c0jm04225k	journal	January 2011
Functional Materials for Rechargeable Batteries Cheng, Fangyi; Liang, Jing; Tao, Zhanliang Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201003587	journal	March 2011
Inorganic solid Li ion conductors: An overview Knauth, Philippe Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916 https://doi.org/10.1016/j.ssi.2009.03.022	journal	June 2009
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Crystal structure of a superionic conductor, Li7P3S11 Yamane, H.; Shibata, M.; Shimane, Y. Solid State Ionics, Vol. 178, Issue 15-18 https://doi.org/10.1016/j.ssi.2007.05.020	journal	June 2007
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1843	journal	January 2012
Anomalous High Ionic Conductivity of Nanoporous β-Li₃PS₄ Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978 https://doi.org/10.1021/ja3110895	journal	January 2013
Conductivity measurements on nasicon and nasicon-modified materials Bohnke, O. Solid State Ionics, Vol. 122, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00062-4	journal	July 1999
Li ₁₄ Ln ₅ [Si ₁₁ N ₁₉ O ₅ ]O ₂ F ₂ with Ln = Ce, Nd—Representatives of a Family of Potential Lithium Ion Conductors Lupart, Saskia; Gregori, Giuliano; Maier, Joachim Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja302255d	journal	June 2012
Superionic Conductivity in Lithium-Rich Anti-Perovskites Zhao, Yusheng; Daemen, Luke L. Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja305709z	journal	August 2012
Solid Electrolyte Behavior of NaMgF3: Geophysical Implications O'Keeffe, M.; Bovin, J. -O. Science, Vol. 206, Issue 4418 https://doi.org/10.1126/science.206.4418.599	journal	November 1979
Thermal expansion and structural distortion of perovskite — data for NaMgF3 perovskite. Part I Zhao, Yusheng; Weidner, Donald J.; Parise, John B. Physics of the Earth and Planetary Interiors, Vol. 76, Issue 1-2 https://doi.org/10.1016/0031-9201(93)90051-A	journal	February 1993
Crystal Chemistry and Phase Transitions of Perovskite inP–T–XSpace: Data for (KxNa1−x)MgF3Perovskites Zhao, Yusheng Journal of Solid State Chemistry, Vol. 141, Issue 1 https://doi.org/10.1006/jssc.1998.7927	journal	November 1998
Electrical Conductivities and Conduction Mechanisms of Perovskite-type Na1-xKxMgF3 (x = 0, 0.1, 1) and KZnF3 Yoshiasa, Akira; Sakamoto, Daisuke; Okudera, Hiroki Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 631, Issue 2-3 https://doi.org/10.1002/zaac.200400358	journal	February 2005
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
A rechargeable room-temperature sodium superoxide (NaO₂) battery Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš Nature Materials, Vol. 12, Issue 3, p. 228-232 https://doi.org/10.1038/nmat3486	journal	December 2012
Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail L. Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl502759z	journal	October 2014
Phosphorus-Graphene Nanosheet Hybrids as Lithium-Ion Anode with Exceptional High-Temperature Cycling Stability Yu, Zhaoxin; Song, Jiangxuan; Gordin, Mikhail L. Advanced Science, Vol. 2, Issue 1-2 https://doi.org/10.1002/advs.201400020	journal	January 2015
The crystal structure of kogarkoite, Na ₃ SO ₄ F Fanfani, L.; Giuseppetti, G.; Tadini, C. Mineralogical Magazine, Vol. 43, Issue 330 https://doi.org/10.1180/minmag.1980.043.330.08	journal	June 1980
(CN)ONa3, Kristallstruktur und Natriumionenleitf�higkeit M�ller, Winfried; Jansen, Martin Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 591, Issue 1 https://doi.org/10.1002/zaac.19905910105	journal	December 1990
�ber die quasi-bin�ren Systeme NaNO2/Na2O und NaCN/Na2O. Phasendiagramme und Natrium-Ionenleitung in Na3O(NO2) und Na3O(CN) Jansen, M.; Feldmann, C.; M�ller, W. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 611, Issue 5 https://doi.org/10.1002/zaac.19926110502	journal	May 1992

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Title: Structural manipulation approaches towards enhanced sodium ionic conductivity in Na-rich antiperovskites

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