Long-range magnetic order and interchain interactions in the S=2 chain system MnCl3 (bpy)

Fishman, Randy S.; Shinozaki, Shin-ichi; Okutani, Akira; Yoshizawa, Daichi; Kida, Takanori; Hagiwara, Masayuki; Meisel, Mark W.

doi:10.1103/PhysRevB.94.104435

Title: Long-range magnetic order and interchain interactions in the $S = 2$ chain system ${MnCl}_{3}$ (bpy)

Journal Article · Wed Sep 28 00:00:00 EDT 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.94.104435· OSTI ID:1330539

Fishman, Randy S. ^[1]; Shinozaki, Shin-ichi ^[2]; Okutani, Akira ^[2]; Yoshizawa, Daichi ^[2]; Kida, Takanori ^[2]; Hagiwara, Masayuki ^[2]; Meisel, Mark W. ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Osaka Univ., Osaka (Japan)
Univ. of Florida, Gainesville, FL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here, a compound with very weakly interacting chains, MnCl₃(bpy), has attracted a great deal of attention as a possible $S = 2$ Haldane chain. However, long-range magnetic order of the chains prevents the Haldane gap from developing below 11.5 K. Based on a four-sublattice model, a description of the antiferromagnetic resonance (AFMR) spectrum up to frequencies of 1.5 THz and magnetic fields up to 50 T indicates that the interchain coupling is indeed quite small but that the Dzaloshinskii-Moriya interaction produced by broken inversion symmetry is substantial (0.12 meV). In addition, the antiferromagnetic, nearest-neighbor interaction within each chain (3.3 meV) is significantly stronger than previously reported. The excitation spectrum of this $S = 2$ compound is well described by a 1/S expansion about the classical limit.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1330539

Alternate ID(s):: OSTI ID: 1327070

Journal Information:: Physical Review B, Vol. 94, Issue 10; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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