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Title: MOF-253-Pd(OAc)2 : a recyclable MOF for transition-metal catalysis in water

Journal Article · · RSC Advances
DOI:https://doi.org/10.1039/c6ra12746k· OSTI ID:1326831
 [1];  [2];  [2];  [1]
  1. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
  2. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry; Ames Lab., Ames, IA (United States)
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We report palladium(II)-functionalized MOF-253 (MOF-253-Pd(OAc)2) as a recyclable catalyst to form all-carbon quaternary centers via conjugate additions of arylboronic acids to β,β-disubstituted enones in aqueous media. We demonstrate MOF-253-Pd(OAc)2 can be reused 8 times to form ketone products in yields above 75% while maintaining its crystallinity. Additions of a range of stereoelectronically diverse arylboronic acids to a variety of β,β-disubstituted enones catalyzed by MOF-253-Pd(OAc)2 occur in modest-to-high yields (34–95%).

Research Organization:
Ames Lab., Ames, IA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
1326831
Report Number(s):
IS-J-9053; RSCACL
Journal Information:
RSC Advances, Vol. 6, Issue 61; ISSN 2046-2069
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

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Rational Design of Catalytic Centers in Crystalline Frameworks journal June 2018

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
organic frameworks
conjugate addition
aqueous media
palladium
quaternary center