Local coexistence of VO2 phases revealed by deep data analysis

Strelcov, Evgheni; Ievlev, Anton; Tselev, Alexander; Kolmakov, Andrei; Kalinin, Sergei V.

doi:10.1038/srep29216

Title: Local coexistence of VO₂ phases revealed by deep data analysis

Abstract

We report a synergistic approach of micro-Raman spectroscopic mapping and deep data analysis to study the distribution of crystallographic phases and ferroelastic domains in a defected Al-doped VO₂ microcrystal. Bayesian linear unmixing revealed an uneven distribution of the T phase, which is stabilized by the surface defects and uneven local doping that went undetectable by other classical analysis techniques such as PCA and SIMPLISMA. This work demonstrates the impact of information recovery via statistical analysis and full mapping in spectroscopic studies of vanadium dioxide systems, which is commonly substituted by averaging or single point-probing approaches, both of which suffer from information misinterpretation due to low resolving power.

Authors:

Strelcov, Evgheni ^[1]; Ievlev, Anton ^[2]; Tselev, Alexander ^[2]; Kolmakov, Andrei ^[3]; Kalinin, Sergei V. ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)

Publication Date:: Thu Jul 07 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1324095

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 6; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Nanowires; Raman spectroscopy

Citation Formats


                    Strelcov, Evgheni, Ievlev, Anton, Tselev, Alexander, Kolmakov, Andrei, and Kalinin, Sergei V. Local coexistence of VO2 phases revealed by deep data analysis.  United States: N. p., 2016. 
        Web.  doi:10.1038/srep29216.

Copy to clipboard


                    Strelcov, Evgheni, Ievlev, Anton, Tselev, Alexander, Kolmakov, Andrei, & Kalinin, Sergei V. Local coexistence of VO2 phases revealed by deep data analysis.  United States.  https://doi.org/10.1038/srep29216

Copy to clipboard


                    Strelcov, Evgheni, Ievlev, Anton, Tselev, Alexander, Kolmakov, Andrei, and Kalinin, Sergei V. 2016.  
        "Local coexistence of VO2 phases revealed by deep data analysis".  United States.  https://doi.org/10.1038/srep29216.  https://www.osti.gov/servlets/purl/1324095.

Copy to clipboard


                    
@article{osti_1324095,

  title        = {Local coexistence of VO2 phases revealed by deep data analysis},

  author       = {Strelcov, Evgheni and Ievlev, Anton and Tselev, Alexander and Kolmakov, Andrei and Kalinin, Sergei V.},

  abstractNote = {We report a synergistic approach of micro-Raman spectroscopic mapping and deep data analysis to study the distribution of crystallographic phases and ferroelastic domains in a defected Al-doped VO2 microcrystal. Bayesian linear unmixing revealed an uneven distribution of the T phase, which is stabilized by the surface defects and uneven local doping that went undetectable by other classical analysis techniques such as PCA and SIMPLISMA. This work demonstrates the impact of information recovery via statistical analysis and full mapping in spectroscopic studies of vanadium dioxide systems, which is commonly substituted by averaging or single point-probing approaches, both of which suffer from information misinterpretation due to low resolving power.},

  doi          = {10.1038/srep29216},

  url          = {https://www.osti.gov/biblio/1324095},
  journal      = {Scientific Reports},

  issn         = {2045-2322},

  number       = ,

  volume       = 6,

  place        = {United States},

  year         = {Thu Jul 07 00:00:00 EDT 2016},

  month        = {Thu Jul 07 00:00:00 EDT 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1038/srep29216

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Features of the operation of a bolometer based on a vanadium dioxide film in a temperature interval that includes a phase transition
journal, January 1999

Zerov, V. Yu.; Kulikov, Yu. V.; Leonov, V. N.
Journal of Optical Technology, Vol. 66, Issue 5
https://doi.org/10.1364/JOT.66.000387

Characterizations of VO2-based uncooled microbolometer linear array
journal, May 2001

Chen, Changhong; Yi, Xinjian; Zhao, Xingrong
Sensors and Actuators A: Physical, Vol. 90, Issue 3
https://doi.org/10.1016/s0924-4247(01)00495-2

Nanoceramic VO2 thermochromic smart glass: A review on progress in solution processing
journal, March 2012

Gao, Yanfeng; Luo, Hongjie; Zhang, Zongtao
Nano Energy, Vol. 1, Issue 2
https://doi.org/10.1016/j.nanoen.2011.12.002

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met
journal, March 2012

Li, S. -Y.; Niklasson, G. A.; Granqvist, C. G.
Thin Solid Films, Vol. 520, Issue 10
https://doi.org/10.1016/j.tsf.2011.10.053

Electromechanical Actuation and Current-Induced Metastable States in Suspended Single-Crystalline VO ₂ Nanoplatelets
journal, August 2011

Tselev, Alexander; Budai, John D.; Strelcov, Evgheni
Nano Letters, Vol. 11, Issue 8
https://doi.org/10.1021/nl200493k

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine
journal, February 2013

Wang, Kevin; Cheng, Chun; Cardona, Edy
ACS Nano, Vol. 7, Issue 3
https://doi.org/10.1021/nn305419e

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs
journal, February 2012

Liu, Kai; Cheng, Chun; Cheng, Zhenting
Nano Letters, Vol. 12, Issue 12
https://doi.org/10.1021/nl303405g

Optical switching in VO2 films by below-gap excitation
journal, May 2008

Rini, M.; Hao, Z.; Schoenlein, R. W.
Applied Physics Letters, Vol. 92, Issue 18
https://doi.org/10.1063/1.2921784

Gas Sensor Based on Metal−Insulator Transition in VO ₂ Nanowire Thermistor
journal, June 2009

Strelcov, Evgheni; Lilach, Yigal; Kolmakov, Andrei
Nano Letters, Vol. 9, Issue 6
https://doi.org/10.1021/nl900676n

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition
journal, December 2011

Byon, Ji Won; Kim, Min-Bin; Kim, Myung Hwa
The Journal of Physical Chemistry C, Vol. 116, Issue 1
https://doi.org/10.1021/jp2080989

Field-effect modulation of conductance in VO ₂ nanobeam transistors with HfO ₂ as the gate dielectric
journal, August 2011

Sengupta, Shamashis; Wang, Kevin; Liu, Kai
Applied Physics Letters, Vol. 99, Issue 6
https://doi.org/10.1063/1.3624896

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition
journal, February 2012

Liu, Kai; Fu, Deyi; Cao, Jinbo
Nano Letters, Vol. 12, Issue 12
https://doi.org/10.1021/nl303379t

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry
journal, December 2008

Ko, Changhyun; Ramanathan, Shriram
Applied Physics Letters, Vol. 93, Issue 25
https://doi.org/10.1063/1.3050464

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors
journal, June 2010

Hormoz, S.; Ramanathan, S.
Solid-State Electronics, Vol. 54, Issue 6
https://doi.org/10.1016/j.sse.2010.01.006

Collective bulk carrier delocalization driven by electrostatic surface charge accumulation
journal, July 2012

Nakano, M.; Shibuya, K.; Okuyama, D.
Nature, Vol. 487, Issue 7408
https://doi.org/10.1038/nature11296

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide
journal, November 2010

Tselev, A.; Luk’yanchuk, I. A.; Ivanov, I. N.
Nano Letters, Vol. 10, Issue 11
https://doi.org/10.1021/nl1020443

Measurement of a solid-state triple point at the metal–insulator transition in VO2
journal, August 2013

Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan
Nature, Vol. 500, Issue 7463
https://doi.org/10.1038/nature12425

New aspects of the metal–insulator transition in single-domain vanadium dioxide nanobeams
journal, May 2009

Wei, Jiang; Wang, Zenghui; Chen, Wei
Nature Nanotechnology, Vol. 4, Issue 7
https://doi.org/10.1038/nnano.2009.141

Metallization of vanadium dioxide driven by large phonon entropy
journal, November 2014

Budai, John D.; Hong, Jiawang; Manley, Michael E.
Nature, Vol. 515, Issue 7528
https://doi.org/10.1038/nature13865

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy
journal, February 2009

Chou, J. Y.; Lensch-Falk, J. L.; Hemesath, E. R.
Journal of Applied Physics, Vol. 105, Issue 3
https://doi.org/10.1063/1.3075763

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO ₂ Nanobeam
journal, December 2009

Zhang, Shixiong; Chou, Jung Yen; Lauhon, Lincoln J.
Nano Letters, Vol. 9, Issue 12
https://doi.org/10.1021/nl9028973

In situ probing of doping- and stress-mediated phase transitions in a single-crystalline VO2 nanobeam by spatially resolved Raman spectroscopy
journal, January 2014

Chang, Sung-Jin; Park, Jong Bae; Lee, Gaehang
Nanoscale, Vol. 6, Issue 14
https://doi.org/10.1039/c4nr01118j

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy
journal, June 2014

Tselev, Alexander; Ivanov, Ilia N.; Lavrik, Nickolay V.
Fuel, Vol. 126
https://doi.org/10.1016/j.fuel.2014.02.029

Doping-Based Stabilization of the M2 Phase in Free-Standing VO ₂ Nanostructures at Room Temperature
journal, February 2012

Strelcov, Evgheni; Tselev, Alexander; Ivanov, Ilia
Nano Letters, Vol. 12, Issue 12
https://doi.org/10.1021/nl303065h

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO ₂ Nanowires and Nanoplatelets
journal, March 2011

Strelcov, Evgheni; Davydov, Albert V.; Lanke, Uday
ACS Nano, Vol. 5, Issue 4
https://doi.org/10.1021/nn2007089

Big data and deep data in scanning and electron microscopies: deriving functionality from multidimensional data sets
journal, May 2015

Belianinov, Alex; Vasudevan, Rama; Strelcov, Evgheni
Advanced Structural and Chemical Imaging, Vol. 1, Issue 1
https://doi.org/10.1186/s40679-015-0006-6

Interactive self-modeling mixture analysis
journal, July 1991

Windig, Willem.; Guilment, Jean.
Analytical Chemistry, Vol. 63, Issue 14
https://doi.org/10.1021/ac00014a016

Self-modeling mixture analysis of categorized pyrolysis mass spectral data with the SIMPLISMA approach
journal, April 1992

Windig, W.; Heckler, C. E.; Agblevor, F. A.
Chemometrics and Intelligent Laboratory Systems, Vol. 14, Issue 1-3
https://doi.org/10.1016/0169-7439(92)80104-C

Spectral mixture analysis of EELS spectrum-images
journal, September 2012

Dobigeon, Nicolas; Brun, Nathalie
Ultramicroscopy, Vol. 120
https://doi.org/10.1016/j.ultramic.2012.05.006

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining
journal, May 2014

Strelcov, Evgheni; Belianinov, Alexei; Hsieh, Ying-Hui
ACS Nano, Vol. 8, Issue 6
https://doi.org/10.1021/nn502029b

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures
journal, August 2015

Strelcov, Evgheni; Belianinov, Alexei; Hsieh, Ying-Hui
Nano Letters, Vol. 15, Issue 10
https://doi.org/10.1021/acs.nanolett.5b02472

Optical properties of $V_{1 - x} {Cr}_{x} O_{2}$ compounds under high pressure
journal, June 2008

Marini, C.; Arcangeletti, E.; Di Castro, D.
Physical Review B, Vol. 77, Issue 23
https://doi.org/10.1103/PhysRevB.77.235111

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy
journal, June 2014

Tselev, Alexander; Ivanov, Ilia N.; Lavrik, Nickolay V.
Fuel, Vol. 126
https://doi.org/10.1016/j.fuel.2014.02.029

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors
journal, June 2010

Hormoz, S.; Ramanathan, S.
Solid-State Electronics, Vol. 54, Issue 6
https://doi.org/10.1016/j.sse.2010.01.006

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met
journal, March 2012

Li, S. -Y.; Niklasson, G. A.; Granqvist, C. G.
Thin Solid Films, Vol. 520, Issue 10
https://doi.org/10.1016/j.tsf.2011.10.053

Characterizations of VO2-based uncooled microbolometer linear array
journal, May 2001

Chen, Changhong; Yi, Xinjian; Zhao, Xingrong
Sensors and Actuators A: Physical, Vol. 90, Issue 3
https://doi.org/10.1016/s0924-4247(01)00495-2

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures
journal, August 2015

Strelcov, Evgheni; Belianinov, Alexei; Hsieh, Ying-Hui
Nano Letters, Vol. 15, Issue 10
https://doi.org/10.1021/acs.nanolett.5b02472

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition
journal, December 2011

Byon, Ji Won; Kim, Min-Bin; Kim, Myung Hwa
The Journal of Physical Chemistry C, Vol. 116, Issue 1
https://doi.org/10.1021/jp2080989

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide
journal, November 2010

Tselev, A.; Luk’yanchuk, I. A.; Ivanov, I. N.
Nano Letters, Vol. 10, Issue 11
https://doi.org/10.1021/nl1020443

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition
journal, February 2012

Liu, Kai; Fu, Deyi; Cao, Jinbo
Nano Letters, Vol. 12, Issue 12
https://doi.org/10.1021/nl303379t

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs
journal, February 2012

Liu, Kai; Cheng, Chun; Cheng, Zhenting
Nano Letters, Vol. 12, Issue 12
https://doi.org/10.1021/nl303405g

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO ₂ Nanobeam
journal, December 2009

Zhang, Shixiong; Chou, Jung Yen; Lauhon, Lincoln J.
Nano Letters, Vol. 9, Issue 12
https://doi.org/10.1021/nl9028973

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO ₂ Nanowires and Nanoplatelets
journal, March 2011

Strelcov, Evgheni; Davydov, Albert V.; Lanke, Uday
ACS Nano, Vol. 5, Issue 4
https://doi.org/10.1021/nn2007089

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine
journal, February 2013

Wang, Kevin; Cheng, Chun; Cardona, Edy
ACS Nano, Vol. 7, Issue 3
https://doi.org/10.1021/nn305419e

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining
journal, May 2014

Strelcov, Evgheni; Belianinov, Alexei; Hsieh, Ying-Hui
ACS Nano, Vol. 8, Issue 6
https://doi.org/10.1021/nn502029b

Metallization of vanadium dioxide driven by large phonon entropy
journal, November 2014

Budai, John D.; Hong, Jiawang; Manley, Michael E.
Nature, Vol. 515, Issue 7528
https://doi.org/10.1038/nature13865

Optical switching in VO2 films by below-gap excitation
journal, May 2008

Rini, M.; Hao, Z.; Schoenlein, R. W.
Applied Physics Letters, Vol. 92, Issue 18
https://doi.org/10.1063/1.2921784

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry
journal, December 2008

Ko, Changhyun; Ramanathan, Shriram
Applied Physics Letters, Vol. 93, Issue 25
https://doi.org/10.1063/1.3050464

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy
journal, February 2009

Chou, J. Y.; Lensch-Falk, J. L.; Hemesath, E. R.
Journal of Applied Physics, Vol. 105, Issue 3
https://doi.org/10.1063/1.3075763

Joint Bayesian endmember extraction and linear unmixing for hyperspectral imagery
text, January 2009

Dobigeon, Nicolas; Moussaoui, Said; Coulon, Martial
arXiv
https://doi.org/10.48550/arxiv.0903.3060

Measurement of a solid-state triple point at the metal-insulator transition in VO2
text, January 2013

Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan
arXiv
https://doi.org/10.48550/arxiv.1308.4741

Works referencing / citing this record:

Development of VO ₂ -Nanoparticle-Based Metal-Insulator Transition Electronic Ink
journal, March 2019

Vaseem, Mohammad; Zhen, Su; Yang, Shuai
Advanced Electronic Materials, Vol. 5, Issue 5
https://doi.org/10.1002/aelm.201800949

VO ₂ as a natural optical metamaterial
journal, January 2018

Eaton, Miller; Catellani, Alessandra; Calzolari, Arrigo
Optics Express, Vol. 26, Issue 5
https://doi.org/10.1364/oe.26.005342

Synthesis and thermochromic property studies on W doped VO2 films fabricated by sol-gel method
journal, July 2017

Pan, Guoping; Yin, Jinhua; Ji, Keli
Scientific Reports, Vol. 7, Issue 1
https://doi.org/10.1038/s41598-017-05229-9

Similar records in OSTI.GOV collections:

Redox-driven atomic-scale changes in mixed catalysts: VO_X / WO_X / α-TiO₂ (110)

Journal Article Feng, Z.; McBriarty, M.; Mane, A.; ... - RSC Advances

X-ray studies of vanadium–tungsten mixed-monolayer-oxide catalysts grown on the rutile α-TiO₂(110) single crystal surface show redox behavior not observed for lone supported vanadium or tungsten oxides. Two cases are presented: sub-monolayer (sub-ML) vanadium oxide (vanadia) grown on ML tungsten oxide and ML vanadia grown on sub-ML tungsten oxide. The X-ray standing wave (XSW) and X-ray photoelectron spectroscopy (XPS) observations for both cases show coverage-dependent reversible redox-induced atomic-scale structural and chemical state changes. Atomic force microscopy shows that the mixed VO_X/WO_X overlayers have a conformal film-like structure in the as-deposited state. XSW analysis in light of XPS reveals that the Vmore »« less
Cited by 7
https://doi.org/10.1039/c4ra14140g

Full Text Available
Controlling the Temperature and Speed of the Phase Transition of VO₂ Microcrystals

Journal Article Yoon, Joonseok; Kim, Howon; Chen, Xian; ... - ACS Applied Materials and Interfaces

Here, we investigated the control of two important parameters of vanadium dioxide (VO₂ ) microcrystals, the phase transition temperature and speed, by varying microcrystal width. By using the reflectivity change between insulating and metallic phases, phase transition temperature is measured by optical microscopy. As the width of square cylinder-shaped microcrystals decreases from ~70 to ~1 μm, the phase transition temperature (67 °C for bulk) varied as much as 26.1 °C (19.7 °C) during heating (cooling). In addition, the propagation speed of phase boundary in the microcrystal, i.e., phase transition speed, is monitored at the onset of phase transition by usingmore »« less
Cited by 36
https://doi.org/10.1021/acsami.5b11144

Full Text Available
Interplay between Ferroelastic and Metal-Insulator Phase Transitions in Strained Quasi-2D VO[subscript 2] Nanoplatelets

Journal Article Tselev, Alexander; Strelcov, Evgheni; Lukyanchuk, Igor; ... - Nano Lett.

Formation of ferroelastic twin domains in vanadium dioxide (VO{sub 2}) nanosystems can strongly affect local strain distributions, and hence couple to the strain-controlled metal-insulator transition. Here we report polarized-light optical and scanning microwave microscopy studies of interrelated ferroelastic and metal-insulator transitions in single-crystalline VO{sub 2} quasi-two-dimensional (quasi-2D) nanoplatelets (NPls). In contrast to quasi-1D single-crystalline nanobeams, the 2D geometric frustration results in emergence of several possible families of ferroelastic domains in NPls, thus allowing systematic studies of strain-controlled transitions in the presence of geometrical frustration. We demonstrate the possibility of controlling the ferroelastic domain population by the strength of the NPl-substratemore »« less
https://doi.org/10.1021/nl1008794
Interplay between Ferroelastic and Metal-Insulator Phase Transitions in Strained Quasi-2D VO[subscript 2] Nanoplatelets

Journal Article Tselev, Alexander; Strelcov, Evgheni; Lukyanchuk, Igor; ... - Nano Lett.

Formation of ferroelastic twin domains in vanadium dioxide (VO{sub 2}) nanosystems can strongly affect local strain distributions, and hence couple to the strain-controlled metal-insulator transition. Here we report polarized-light optical and scanning microwave microscopy studies of interrelated ferroelastic and metal-insulator transitions in single-crystalline VO{sub 2} quasi-two-dimensional (quasi-2D) nanoplatelets (NPls). In contrast to quasi-1D single-crystalline nanobeams, the 2D geometric frustration results in emergence of several possible families of ferroelastic domains in NPls, thus allowing systematic studies of strain-controlled transitions in the presence of geometrical frustration. We demonstrate the possibility of controlling the ferroelastic domain population by the strength of the NPl-substratemore »« less
https://doi.org/10.1021/nl1008794
Structural study of VO {sub x} doped aluminium fluoride and aluminium oxide catalysts

Journal Article Scheurell, Kerstin; Scholz, Gudrun; Kemnitz, Erhard - Journal of Solid State Chemistry

The structural properties of vanadium doped aluminium oxyfluorides and aluminium oxides, prepared by a modified sol-gel synthesis route, were thoroughly investigated. The influence of the preparation technique and the calcination temperature on the coordination of vanadium, aluminium and fluorine was analysed by different spectroscopic methods such as Raman, MAS NMR and ESR spectroscopy. In all samples calcined at low temperatures (350 deg. C), vanadium coexists in two oxidation states V{sup IV} and V{sup V}, with V{sup IV} as dominating species in the vanadium doped aluminium oxyfluorides. In the fluoride containing solids aluminium as well as vanadium are coordinated by fluorinemore »« less
https://doi.org/10.1016/j.jssc.2006.12.003

Similar Records

Title: Local coexistence of VO2 phases revealed by deep data analysis

Abstract

Citation Formats

Features of the operation of a bolometer based on a vanadium dioxide film in a temperature interval that includes a phase transition journal, January 1999

Characterizations of VO2-based uncooled microbolometer linear array journal, May 2001

Nanoceramic VO2 thermochromic smart glass: A review on progress in solution processing journal, March 2012

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met journal, March 2012

Electromechanical Actuation and Current-Induced Metastable States in Suspended Single-Crystalline VO 2 Nanoplatelets journal, August 2011

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine journal, February 2013

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs journal, February 2012

Optical switching in VO2 films by below-gap excitation journal, May 2008

Gas Sensor Based on Metal−Insulator Transition in VO 2 Nanowire Thermistor journal, June 2009

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition journal, December 2011

Field-effect modulation of conductance in VO 2 nanobeam transistors with HfO 2 as the gate dielectric journal, August 2011

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition journal, February 2012

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry journal, December 2008

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors journal, June 2010

Collective bulk carrier delocalization driven by electrostatic surface charge accumulation journal, July 2012

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide journal, November 2010

Measurement of a solid-state triple point at the metal–insulator transition in VO2 journal, August 2013

New aspects of the metal–insulator transition in single-domain vanadium dioxide nanobeams journal, May 2009

Metallization of vanadium dioxide driven by large phonon entropy journal, November 2014

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy journal, February 2009

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO 2 Nanobeam journal, December 2009

In situ probing of doping- and stress-mediated phase transitions in a single-crystalline VO2 nanobeam by spatially resolved Raman spectroscopy journal, January 2014

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy journal, June 2014

Doping-Based Stabilization of the M2 Phase in Free-Standing VO 2 Nanostructures at Room Temperature journal, February 2012

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO 2 Nanowires and Nanoplatelets journal, March 2011

Big data and deep data in scanning and electron microscopies: deriving functionality from multidimensional data sets journal, May 2015

Interactive self-modeling mixture analysis journal, July 1991

Self-modeling mixture analysis of categorized pyrolysis mass spectral data with the SIMPLISMA approach journal, April 1992

Spectral mixture analysis of EELS spectrum-images journal, September 2012

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining journal, May 2014

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures journal, August 2015

Optical properties of V 1 − x Cr x O 2 compounds under high pressure journal, June 2008

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy journal, June 2014

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors journal, June 2010

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met journal, March 2012

Characterizations of VO2-based uncooled microbolometer linear array journal, May 2001

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures journal, August 2015

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition journal, December 2011

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide journal, November 2010

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition journal, February 2012

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs journal, February 2012

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO 2 Nanobeam journal, December 2009

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO 2 Nanowires and Nanoplatelets journal, March 2011

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine journal, February 2013

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining journal, May 2014

Metallization of vanadium dioxide driven by large phonon entropy journal, November 2014

Optical switching in VO2 films by below-gap excitation journal, May 2008

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry journal, December 2008

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy journal, February 2009

Joint Bayesian endmember extraction and linear unmixing for hyperspectral imagery text, January 2009

Measurement of a solid-state triple point at the metal-insulator transition in VO2 text, January 2013

Development of VO 2 -Nanoparticle-Based Metal-Insulator Transition Electronic Ink journal, March 2019

VO 2 as a natural optical metamaterial journal, January 2018

Synthesis and thermochromic property studies on W doped VO2 films fabricated by sol-gel method journal, July 2017

Title: Local coexistence of VO₂ phases revealed by deep data analysis

Features of the operation of a bolometer based on a vanadium dioxide film in a temperature interval that includes a phase transition
journal, January 1999

Characterizations of VO2-based uncooled microbolometer linear array
journal, May 2001

Nanoceramic VO2 thermochromic smart glass: A review on progress in solution processing
journal, March 2012

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met
journal, March 2012

Electromechanical Actuation and Current-Induced Metastable States in Suspended Single-Crystalline VO ₂ Nanoplatelets
journal, August 2011

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine
journal, February 2013

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs
journal, February 2012

Optical switching in VO2 films by below-gap excitation
journal, May 2008

Gas Sensor Based on Metal−Insulator Transition in VO ₂ Nanowire Thermistor
journal, June 2009

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition
journal, December 2011

Field-effect modulation of conductance in VO ₂ nanobeam transistors with HfO ₂ as the gate dielectric
journal, August 2011

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition
journal, February 2012

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry
journal, December 2008

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors
journal, June 2010

Collective bulk carrier delocalization driven by electrostatic surface charge accumulation
journal, July 2012

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide
journal, November 2010

Measurement of a solid-state triple point at the metal–insulator transition in VO2
journal, August 2013

New aspects of the metal–insulator transition in single-domain vanadium dioxide nanobeams
journal, May 2009

Metallization of vanadium dioxide driven by large phonon entropy
journal, November 2014

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy
journal, February 2009

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO ₂ Nanobeam
journal, December 2009

In situ probing of doping- and stress-mediated phase transitions in a single-crystalline VO2 nanobeam by spatially resolved Raman spectroscopy
journal, January 2014

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy
journal, June 2014

Doping-Based Stabilization of the M2 Phase in Free-Standing VO ₂ Nanostructures at Room Temperature
journal, February 2012

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO ₂ Nanowires and Nanoplatelets
journal, March 2011

Big data and deep data in scanning and electron microscopies: deriving functionality from multidimensional data sets
journal, May 2015

Interactive self-modeling mixture analysis
journal, July 1991

Self-modeling mixture analysis of categorized pyrolysis mass spectral data with the SIMPLISMA approach
journal, April 1992

Spectral mixture analysis of EELS spectrum-images
journal, September 2012

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining
journal, May 2014

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures
journal, August 2015

Optical properties of $V_{1 - x} {Cr}_{x} O_{2}$ compounds under high pressure
journal, June 2008

Mapping internal structure of coal by confocal micro-Raman spectroscopy and scanning microwave microscopy
journal, June 2014

Limits on vanadium oxide Mott metal–insulator transition field-effect transistors
journal, June 2010

Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met
journal, March 2012

Characterizations of VO2-based uncooled microbolometer linear array
journal, May 2001

Constraining Data Mining with Physical Models: Voltage- and Oxygen Pressure-Dependent Transport in Multiferroic Nanostructures
journal, August 2015

Electrothermally Induced Highly Responsive and Highly Selective Vanadium Oxide Hydrogen Sensor Based on Metal–Insulator Transition
journal, December 2011

Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide
journal, November 2010

Dense Electron System from Gate-Controlled Surface Metal–Insulator Transition
journal, February 2012

Giant-Amplitude, High-Work Density Microactuators with Phase Transition Activated Nanolayer Bimorphs
journal, February 2012

Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO ₂ Nanobeam
journal, December 2009

In Situ Monitoring of the Growth, Intermediate Phase Transformations and Templating of Single Crystal VO ₂ Nanowires and Nanoplatelets
journal, March 2011

Performance Limits of Microactuation with Vanadium Dioxide as a Solid Engine
journal, February 2013

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining
journal, May 2014

Metallization of vanadium dioxide driven by large phonon entropy
journal, November 2014

Optical switching in VO2 films by below-gap excitation
journal, May 2008

Observation of electric field-assisted phase transition in thin film vanadium oxide in a metal-oxide-semiconductor device geometry
journal, December 2008

Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy
journal, February 2009

Joint Bayesian endmember extraction and linear unmixing for hyperspectral imagery
text, January 2009

Measurement of a solid-state triple point at the metal-insulator transition in VO2
text, January 2013

Development of VO ₂ -Nanoparticle-Based Metal-Insulator Transition Electronic Ink
journal, March 2019

VO ₂ as a natural optical metamaterial
journal, January 2018

Synthesis and thermochromic property studies on W doped VO2 films fabricated by sol-gel method
journal, July 2017