Redox Non-Innocence of Nitrosobenzene at Nickel

Kundu, Subrata; Stieber, S. Chantal; Ferrier, Maryline Ghislaine; Kozimor, Stosh Anthony; Bertke, Jeffery A.; Warren, Timothy H.

doi:10.1002/anie.201605026

Title: Redox Non-Innocence of Nitrosobenzene at Nickel

Journal Article · Mon Aug 22 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201605026· OSTI ID:1304729

^[1]; Stieber, S. Chantal ^[2]; Ferrier, Maryline Ghislaine ^[3]; Kozimor, Stosh Anthony ^[3]; Bertke, Jeffery A. ^[1];

^[1]

Georgetown Univ., Washington, DC (United States). Dept. of Chemistry
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); California State Polytechnic Univ., Pomona, CA (United States). Dept. of Chemistry and Biochemistry
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Abstract Nitrosobenzene (PhNO) serves as a stable analogue of nitroxyl (HNO), a biologically relevant, redox‐active nitric oxide derivative. Capture of nitrosobenzene at the electron‐deficient β‐diketiminato nickel(I) complex [ ⁱ Pr ₂ NN _F6 ]Ni results in reduction of the PhNO ligand to a (PhNO) ^./− species coordinated to a square planar Ni ^II center in [ ⁱ Pr ₂ NN _F6 ]Ni(η ² ‐ONPh). Ligand centered reduction leads to the (PhNO) ²⁻ moiety bound to Ni ^II supported by XAS studies. Systematic investigation of structure–reactivity patterns of (PhNO) ^./− and (PhNO) ²⁻ ligands reveals parallels with superoxo (O ₂ ) ^./− and peroxo (O ₂ ) ²⁻ ligands, respectively, and forecasts reactivity patterns of the more transient HNO ligand.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC). Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC52-06NA25396; AC02-76SF00515; CHE-1459090; CHE-1337975

OSTI ID:: 1304729

Alternate ID(s):: OSTI ID: 1401002

Report Number(s):: LA-UR-16-23579

Journal Information:: Angewandte Chemie (International Edition), Vol. 55, Issue 35; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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