skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of Two-Dimensional Materials for Capacitive Energy Storage

Abstract

The unique properties and great variety of two-dimensional (2D) nanomaterials make them highly attractive for energy storage applications. Here, an insight into the progress made towards the application of 2D nanomaterials for capacitive energy storage is provided. Moreover, synthesis methods, and electrochemical performance of various classes of 2D nanomaterials, particularly based on graphene, transition metal oxides, dichalcogenides, and carbides, are presented. Some factors that directly influence capacitive performance are discussed throughout the text and include nanosheet composition, morphology and texture, electrode architecture, and device configuration. Recent progress in the fabrication of 2D-nanomaterials-based microsupercapacitors and flexible and free-standing supercapacitors is presented. The main electrode manufacturing techniques with emphasis on scalability and cost-effectiveness are discussed, and include laser scribing, printing, and roll-to-roll manufacture. Some various issues that prevent the use of the full energy-storage potential of 2D nanomaterials and how they have been tackled are discussed, and include nanosheet aggregation and the low electrical conductivity of some 2D nanomaterials. In particular, the design of hybrid and hierarchical 2D and 3D structures based on 2D nanomaterials is presented. Other challenges and opportunities are discussed and include: control of nanosheets size and thickness, chemical and electrochemical instability, and scale-up of electrode films.

Authors:
 [1];  [2]
  1. François Rabelais Univ., Tours (France)
  2. Drexel Univ., Philadelphia, PA (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1286986
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 28; Journal Issue: 29; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 2D materials; electrode architecture; hierarchical structure; hybrid devices; supercapacitors

Citation Formats

Mendoza-Sánchez, Beatriz, and Gogotsi, Yury. Synthesis of Two-Dimensional Materials for Capacitive Energy Storage. United States: N. p., 2016. Web. doi:10.1002/adma.201506133.
Mendoza-Sánchez, Beatriz, & Gogotsi, Yury. Synthesis of Two-Dimensional Materials for Capacitive Energy Storage. United States. https://doi.org/10.1002/adma.201506133
Mendoza-Sánchez, Beatriz, and Gogotsi, Yury. 2016. "Synthesis of Two-Dimensional Materials for Capacitive Energy Storage". United States. https://doi.org/10.1002/adma.201506133. https://www.osti.gov/servlets/purl/1286986.
@article{osti_1286986,
title = {Synthesis of Two-Dimensional Materials for Capacitive Energy Storage},
author = {Mendoza-Sánchez, Beatriz and Gogotsi, Yury},
abstractNote = {The unique properties and great variety of two-dimensional (2D) nanomaterials make them highly attractive for energy storage applications. Here, an insight into the progress made towards the application of 2D nanomaterials for capacitive energy storage is provided. Moreover, synthesis methods, and electrochemical performance of various classes of 2D nanomaterials, particularly based on graphene, transition metal oxides, dichalcogenides, and carbides, are presented. Some factors that directly influence capacitive performance are discussed throughout the text and include nanosheet composition, morphology and texture, electrode architecture, and device configuration. Recent progress in the fabrication of 2D-nanomaterials-based microsupercapacitors and flexible and free-standing supercapacitors is presented. The main electrode manufacturing techniques with emphasis on scalability and cost-effectiveness are discussed, and include laser scribing, printing, and roll-to-roll manufacture. Some various issues that prevent the use of the full energy-storage potential of 2D nanomaterials and how they have been tackled are discussed, and include nanosheet aggregation and the low electrical conductivity of some 2D nanomaterials. In particular, the design of hybrid and hierarchical 2D and 3D structures based on 2D nanomaterials is presented. Other challenges and opportunities are discussed and include: control of nanosheets size and thickness, chemical and electrochemical instability, and scale-up of electrode films.},
doi = {10.1002/adma.201506133},
url = {https://www.osti.gov/biblio/1286986}, journal = {Advanced Materials},
issn = {0935-9648},
number = 29,
volume = 28,
place = {United States},
year = {Thu Jun 02 00:00:00 EDT 2016},
month = {Thu Jun 02 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 495 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions
journal, January 2015


Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
journal, March 2013


What Nano Can Do for Energy Storage
journal, May 2014


Graphene-Based Ultracapacitors
journal, October 2008


Two dimensional nanomaterials for flexible supercapacitors
journal, January 2014


The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013


Two-Dimensional Transition Metal Carbides
journal, January 2012


Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011


25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013


Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
journal, September 2013


Materials for electrochemical capacitors
journal, November 2008


Solving the Capacitive Paradox of 2D MXene using Electrochemical Quartz-Crystal Admittance and In Situ Electronic Conductance Measurements
journal, August 2014


Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors
journal, January 2014


The rise of graphene
journal, March 2007


Two-dimensional gas of massless Dirac fermions in graphene
journal, November 2005


Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004


Breakdown of the adiabatic Born–Oppenheimer approximation in graphene
journal, February 2007


Flexible and conductive MXene films and nanocomposites with high capacitance
journal, November 2014


Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials
journal, March 2015


Atomically Thin MoS2 A New Direct-Gap Semiconductor
journal, September 2010


Regulating the Electrical Behaviors of 2D Inorganic Nanomaterials for Energy Applications
journal, October 2014


Crumpled Nitrogen-Doped Graphene for Supercapacitors with High Gravimetric and Volumetric Performances
journal, September 2015


Stretchable and High-Performance Supercapacitors with Crumpled Graphene Papers
journal, October 2014


Graphene Double-Layer Capacitor with ac Line-Filtering Performance
journal, September 2010


Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011


Flexible Holey Graphene Paper Electrodes with Enhanced Rate Capability for Energy Storage Applications
journal, October 2011


Exploration of Nanostructured Functional Materials Based on Hybridization of Inorganic 2D Nanosheets
journal, January 2014


Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010


Anchoring Hydrous RuO2 on Graphene Sheets for High-Performance Electrochemical Capacitors
journal, August 2010


Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)
journal, December 2015


Metal dichalcogenide nanosheets: preparation, properties and applications
journal, January 2013


Experimental observation of the quantum Hall effect and Berry's phase in graphene
journal, November 2005


A study of graphenes prepared by different methods: characterization, properties and solubilization
journal, January 2008


Graphene-based electrochemical supercapacitors
journal, January 2008


2D materials: to graphene and beyond
journal, January 2011


Graphene: synthesis and applications
journal, March 2012


Graphene and Graphene Oxide: Synthesis, Properties, and Applications
journal, June 2010


Graphene based materials: Past, present and future
journal, October 2011


Graphene-Based Materials: Synthesis, Characterization, Properties, and Applications
journal, June 2011


Graphene and graphite nanoribbons: Morphology, properties, synthesis, defects and applications
journal, August 2010


All in the graphene family – A recommended nomenclature for two-dimensional carbon materials
journal, December 2013


Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids
journal, April 2014


High-yield production of graphene by liquid-phase exfoliation of graphite
journal, August 2008


High-Concentration, Surfactant-Stabilized Graphene Dispersions
journal, May 2010


Ultrathin Planar Graphene Supercapacitors
journal, April 2011


Differential Capacitance Study of Stress-Annealed Pyrolytic Graphite Electrodes
journal, January 1971


Carbon nanosheets as the electrode material in supercapacitors
journal, December 2009


Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007


The Route to Functional Graphene Oxide
journal, May 2010


The role of microwave absorption on formation of graphene from graphite oxide
journal, August 2012


Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors
journal, June 2010


Supercapacitor Devices Based on Graphene Materials
journal, July 2009


Low-Temperature Exfoliated Graphenes: Vacuum-Promoted Exfoliation and Electrochemical Energy Storage
journal, October 2009


Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors
journal, January 2012


Flexible Nano-felts of Carbide-Derived Carbon with Ultra-high Power Handling Capability
journal, April 2011


Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties
journal, May 2009


Large-Scale Growth and Characterizations of Nitrogen-Doped Monolayer Graphene Sheets
journal, April 2011


Nitrogen-doped reduced graphene oxide electrodes for electrochemical supercapacitors
journal, January 2014


Controllable graphene N-doping with ammonia plasma
journal, March 2010


Crumpled Nitrogen-Doped Graphene Nanosheets with Ultrahigh Pore Volume for High-Performance Supercapacitor
journal, August 2012


Nitrogen-doped and crumpled graphene sheets with improved supercapacitance
journal, January 2014


Pyrolytic synthesis and characterization of N-doped carbon nanoflakes for electrochemical applications
journal, September 2015


Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010


Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor
journal, March 2013


Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources
journal, January 2011


Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

  • Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069
  • https://doi.org/10.1021/ja1072299

Three-Dimensional Nitrogen and Boron Co-doped Graphene for High-Performance All-Solid-State Supercapacitors
journal, July 2012


Interaction between Nitrogen and Sulfur in Co-Doped Graphene and Synergetic Effect in Supercapacitor
journal, April 2015


True Performance Metrics in Electrochemical Energy Storage
journal, November 2011


Quantum capacitance and compressibility of graphene: The role of Coulomb interactions
journal, February 2015


On the influence of polarization effects in predicting the interfacial structure and capacitance of graphene-like electrodes in ionic liquids
journal, January 2015


Quantum capacitance and density of states of graphene
journal, April 2010


Measuring the local quantum capacitance of graphene using a strongly coupled graphene nanoribbon
journal, March 2015


Nitrogen doping of graphene and its effect on quantum capacitance, and a new insight on the enhanced capacitance of N-doped carbon
journal, January 2012


Measurement of the quantum capacitance of graphene
journal, July 2009


Observation of electron–hole puddles in graphene using a scanning single-electron transistor
journal, November 2007


Desolvation of Ions in Subnanometer Pores and Its Effect on Capacitance and Double-Layer Theory
journal, April 2008


Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor
journal, March 2008


Theoretical Model for Nanoporous Carbon Supercapacitors
journal, January 2008


A Universal Model for Nanoporous Carbon Supercapacitors Applicable to Diverse Pore Regimes, Carbon Materials, and Electrolytes
journal, July 2008


Capacitance Performance of Sub-2 nm Graphene Nanochannels in Aqueous Electrolyte
journal, October 2015


Preparation of Ruthenic Acid Nanosheets and Utilization of Its Interlayer Surface for Electrochemical Energy Storage
journal, September 2003


Electrochemical Capacitor Behavior of Layered Ruthenic Acid Hydrate
journal, January 2004


Towards Implantable Bio-Supercapacitors: Pseudocapacitance of Ruthenium Oxide Nanoparticles and Nanosheets in Acids, Buffered Solutions, and Bioelectrolytes
journal, January 2015


Fabrication of Thin-Film, Flexible, and Transparent Electrodes Composed of Ruthenic Acid Nanosheets by Electrophoretic Deposition and Application to Electrochemical Capacitors
journal, January 2006


RuO2/graphene hybrid material for high performance electrochemical capacitor
journal, February 2014


Redoxable Nanosheet Crystallites of MnO 2 Derived via Delamination of a Layered Manganese Oxide
journal, March 2003


Synthesis and Delamination of Layered Manganese Oxide Nanobelts
journal, December 2007


Electrochemical characterization of single-layer MnO2 nanosheets as a high-capacitance pseudocapacitor electrode
journal, January 2012


Room-Temperature Synthesis of Manganese Oxide Monosheets
journal, November 2008


Ultrathin amorphous manganese dioxide nanosheets synthesized with controllable width
journal, January 2013


Manganese oxide nanosheets and a 2D hybrid of graphene–manganese oxide nanosheets synthesized by liquid-phase exfoliation
journal, May 2015


Performance of Manganese Oxide/CNTs Composites as Electrode Materials for Electrochemical Capacitors
journal, January 2005


Synthesis and Capacitive Properties of Manganese Oxide Nanosheets Dispersed on Functionalized Graphene Sheets
journal, March 2011


Co3O4 Nanowire@MnO2 Ultrathin Nanosheet Core/Shell Arrays: A New Class of High-Performance Pseudocapacitive Materials
journal, March 2011


Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors
journal, January 2010


Production of Molybdenum Trioxide Nanosheets by Liquid Exfoliation and Their Application in High-Performance Supercapacitors
journal, February 2014


Hierarchical Co3O4 nanoflowers assembled from nanosheets: facile synthesis and their application in supercapacitors
journal, March 2015


Nanosheet-Constructed Porous TiO2-B for Advanced Lithium Ion Batteries
journal, May 2012


Carbon-supported ultra-thin anatase TiO2 nanosheets for fast reversible lithium storage
journal, January 2011


To Be or Not To Be Pseudocapacitive?
journal, January 2015


Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014


Where Do Batteries End and Supercapacitors Begin?
journal, March 2014


Building 3D Structures of Vanadium Pentoxide Nanosheets and Application as Electrodes in Supercapacitors
journal, October 2013


Intercalation chemistry of molybdenum disulfide
journal, January 2002


Photoluminescence from Chemically Exfoliated MoS2
journal, December 2011


Single-Layer Semiconducting Nanosheets: High-Yield Preparation and Device Fabrication
journal, October 2011


Transition metal dichalcogenides (MoS2, MoSe2, WS2 and WSe2) exfoliation technique has strong influence upon their capacitance
journal, July 2015


Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
journal, November 2014


Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)
journal, August 2015


Transition metal carbides go 2D
journal, August 2015


Resolving the Structure of Ti 3 C 2 T x MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function
journal, December 2015


Intercalation and delamination of layered carbides and carbonitrides
journal, April 2013


Amine-Assisted Delamination of Nb 2 C MXene for Li-Ion Energy Storage Devices
journal, April 2015


Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”
journal, January 2015


Probing the Mechanism of High Capacitance in 2D Titanium Carbide Using In Situ X-Ray Absorption Spectroscopy
journal, May 2015


High capacitance of surface-modified 2D titanium carbide in acidic electrolyte
journal, November 2014


Two-Dimensional Vanadium Carbide (MXene) as Positive Electrode for Sodium-Ion Capacitors
journal, June 2015


Capacitance of two-dimensional titanium carbide (MXene) and MXene/carbon nanotube composites in organic electrolytes
journal, February 2016


Graphene-Based Supercapacitor with an Ultrahigh Energy Density
journal, December 2010


Direct laser writing of micro-supercapacitors on hydrated graphite oxide films
journal, July 2011


Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
journal, March 2012


Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage
journal, February 2013


Direct Laser-Patterned Micro-Supercapacitors from Paintable MoS 2 Films
journal, April 2013


Metallic Few-Layered VS 2 Ultrathin Nanosheets: High Two-Dimensional Conductivity for In-Plane Supercapacitors
journal, November 2011


Facilitated Ion Transport in All-Solid-State Flexible Supercapacitors
journal, August 2011


Shape-Tailorable Graphene-Based Ultra-High-Rate Supercapacitor for Wearable Electronics
journal, May 2015


Aqueous Manganese Dioxide Ink for Paper-Based Capacitive Energy Storage Devices
journal, April 2015


Transparent and Stretchable High-Performance Supercapacitors Based on Wrinkled Graphene Electrodes
journal, December 2013


Large-Scale Fabrication of Pseudocapacitive Glass Windows that Combine Electrochromism and Energy Storage
journal, September 2014


Compression and Aggregation-Resistant Particles of Crumpled Soft Sheets
journal, October 2011


Gravure printing of hybrid MoS 2 @S-rGO interdigitated electrodes for flexible microsupercapacitors
journal, July 2015


Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide
journal, April 2011


Direct printing and reduction of graphite oxide for flexible supercapacitors
journal, August 2014


Large Area Electronics Using Printing Methods
journal, July 2005


Efficient Inkjet Printing of Graphene
journal, May 2013


Graphene nanosheets as ink particles for inkjet printing on flexible board
journal, August 2013


Characteristics of Inkjet-Printed Separators in Graphene-Based Supercapacitors
journal, August 2014


Roll-to-roll production of 30-inch graphene films for transparent electrodes
journal, June 2010


Production of a 100-m-long high-quality graphene transparent conductive film by roll-to-roll chemical vapor deposition and transfer process
journal, January 2013


High-speed roll-to-roll manufacturing of graphene using a concentric tube CVD reactor
journal, May 2015


Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors
journal, October 2013


Hydrogen-Incorporated TiS 2 Ultrathin Nanosheets with Ultrahigh Conductivity for Stamp-Transferrable Electrodes
journal, March 2013


A Facile Solution-Phase Approach to Transparent and Conducting ITO Nanocrystal Assemblies
journal, August 2012


Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS 2 Nanosheets
journal, May 2013


Intercalation of cations into partially reduced molybdenum oxide for high-rate pseudocapacitors
journal, November 2015


Unstable Single‐Layered Colloidal TiS 2 Nanodisks
journal, July 2008


Glucose-Assisted Growth of MoS2 Nanosheets on CNT Backbone for Improved Lithium Storage Properties
journal, October 2011


Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media
journal, January 2014


Ionic liquids as electrolytes
journal, August 2006


A study of the charge storage properties of a MoSe2 nanoplatelets/SWCNTs electrode in a Li-ion based electrolyte
journal, February 2016


Synthesis of Large-Area MoS2 Atomic Layers with Chemical Vapor Deposition
journal, March 2012


Large-Area Graphene Single Crystals Grown by Low-Pressure Chemical Vapor Deposition of Methane on Copper
journal, March 2011


Selling graphene by the ton
journal, October 2009


Black Phosphorus: Narrow Gap, Wide Applications
journal, October 2015


Graphene’s cousin silicene makes transistor debut
journal, February 2015


XPD and STM investigation of hexagonal boron nitride on Ni(111)
journal, June 1999


Preparation of Ruthenic Acid Nanosheets and Utilization of Its Interlayer Surface for Electrochemical Energy Storage
journal, September 2003


Single-Layer Semiconducting Nanosheets: High-Yield Preparation and Device Fabrication
journal, October 2011


Quantum capacitance and density of states of graphene
journal, January 2012


Theoretical Model for Nanoporous Carbon Supercapacitors
journal, January 2008


Redoxable Nanosheet Crystallites of MnO2 Derived via Delamination of a Layered Manganese Oxide.
journal, June 2003


Graphene Synthesis and Applications
book, August 2015


Works referencing / citing this record:

Epitaxial Stitching and Stacking Growth of Atomically Thin Transition-Metal Dichalcogenides (TMDCs) Heterojunctions
journal, January 2017


Two-Dimensional Nanostructured Materials for Gas Sensing
journal, August 2017


Hydraulic Power Manufacturing for Highly Scalable and Stable 2D Nanosheet Dispersions and Their Film Electrode Application
journal, August 2018


Electrolyte‐Gated n‐Type Transistors Produced from Aqueous Inks of WS 2 Nanosheets
journal, December 2018


Asymmetric Supercapacitor Electrodes and Devices
journal, February 2017


Hollow MXene Spheres and 3D Macroporous MXene Frameworks for Na-Ion Storage
journal, July 2017


Layered Transition Metal Dichalcogenide‐Based Nanomaterials for Electrochemical Energy Storage
journal, September 2019


Atomically Thin 2D Transition Metal Oxides: Structural Reconstruction, Interaction with Substrates, and Potential Applications
journal, October 2018


2D Black Phosphorus: from Preparation to Applications for Electrochemical Energy Storage
journal, February 2018


On‐Chip MXene Microsupercapacitors for AC‐Line Filtering Applications
journal, May 2019


2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications
journal, April 2018


Exfoliating a Cd II –Purine Framework: Conversion of Nanosheets‐to‐Nanofibers and Studies of Elastic and Capacitive Properties
journal, April 2019


Porous lithium titanate nanosheets as an advanced anode material for sodium ion batteries
journal, December 2019


A facile one-pot method to prepare nitrogen and fluorine co-doped three-dimensional graphene-like materials for supercapacitors
journal, October 2019


Highly sensitive fluorescent sensing for intracellular glutathione based on Ti3C2 quantum dots
journal, December 2019


Few-layered MoSe 2 nanosheets as an efficient peroxidase nanozyme for highly sensitive colorimetric detection of H 2 O 2 and xanthine
journal, January 2018


B/N co-doped carbon nanosphere frameworks as high-performance electrodes for supercapacitors
journal, January 2018


Carbon–metal compound composite electrodes for capacitive deionization: synthesis, development and applications
journal, January 2019


Unexpected Stabilization of α -Ni(OH) 2 Nanoparticles in GO Nanocomposites
journal, December 2018


Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance
journal, June 2017


Toward Superior Capacitive Energy Storage: Recent Advances in Pore Engineering for Dense Electrodes
journal, March 2018


Scalable Manufacturing of Large and Flexible Sheets of MXene/Graphene Heterostructures
journal, March 2019


Selective Growth of Zn–Co–Se Nanostructures on Various Conductive Substrates for Asymmetric Flexible Hybrid Supercapacitor with Enhanced Performance
journal, December 2019


Liquid-Phase Exfoliated Metallic Antimony Nanosheets toward High Volumetric Sodium Storage
journal, May 2017


Antimonene: A Novel 2D Nanomaterial for Supercapacitor Applications
journal, December 2017


Scalable Water-Based Production of Highly Conductive 2D Nanosheets with Ultrahigh Volumetric Capacitance and Rate Capability
journal, March 2018


Three-Dimensional Architectures Constructed from Transition-Metal Dichalcogenide Nanomaterials for Electrochemical Energy Storage and Conversion
journal, December 2017


Molecular-Based Design of Microporous Carbon Nanosheets
journal, January 2019


Recent Advances in Layered Ti 3 C 2 T x MXene for Electrochemical Energy Storage
journal, February 2018


A review on metal nitrides/oxynitrides as an emerging supercapacitor electrode beyond oxide
journal, June 2018


Highly negative Poisson's ratio in a flexible two-dimensional tungsten carbide monolayer
journal, January 2018


Heteroatom-doped porous carbons derived from moxa floss of different storage years for supercapacitors
journal, January 2018


B 3 S monolayer: prediction of a high-performance anode material for lithium-ion batteries
journal, January 2019


A super-thermostable, flexible supercapacitor for ultralight and high performance devices
journal, January 2020


The development of 2D materials for electrochemical energy applications: A mechanistic approach
journal, March 2019


Novel mesoporous electrode materials for symmetric, asymmetric and hybrid supercapacitors
journal, March 2019


Strategies for improving the lithium-storage performance of 2D nanomaterials
journal, July 2017


The Synthesis of NiCo2O4–MnO2 Core–Shell Nanowires by Electrodeposition and Its Supercapacitive Properties
journal, October 2019


Facile synthesis and electrochemical performance of TiO2 nanowires/Ti3C2 composite
journal, January 2018


Flexible and integrated supercapacitor with tunable energy storage
journal, January 2017


Sb 2 O 3 /MXene(Ti 3 C 2 T x ) hybrid anode materials with enhanced performance for sodium-ion batteries
journal, January 2017


An easily manipulated protocol for patterning of MXenes on paper for planar micro-supercapacitors
journal, January 2017


Edge-oriented SnS 2 nanosheet arrays on carbon paper as advanced binder-free anodes for Li-ion and Na-ion batteries
journal, January 2017


Electronic Properties of Armchair Black Phosphorene Nanoribbons Edge-Modified by Transition Elements V, Cr, and Mn
journal, April 2019


Optically Sintered 2D RuO 2 Nanosheets: Temperature-Controlled NO 2 Reaction
journal, February 2017


Functionalized Hybridization of 2D Nanomaterials
journal, September 2019


Photochemical and oxidative cyclisation of tetraphenylpyrroles
journal, January 2017


Scalable transfer of vertical graphene nanosheets for flexible supercapacitor applications
journal, September 2017


Synthesis of Nitrogen-Doped Two-Dimensional Ti 3 C 2 with Enhanced Electrochemical Performance
journal, January 2017


Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
journal, January 2020


Emergent Pseudocapacitance of 2D Nanomaterials
journal, February 2018


Amorphous 2D materials containing a conjugated-polymer network
journal, August 2019


Recent advances in inorganic 2D materials and their applications in lithium and sodium batteries
journal, January 2017


Two dimensional oxygen-vacancy-rich Co 3 O 4 nanosheets with excellent supercapacitor performances
journal, January 2017


Silicon quantum dot-assisted synthesis of MoS 2 /rGO sandwich structures with excellent supercapacitive performance
journal, January 2019


2D Black Phosphorus: from Preparation to Applications for Electrochemical Energy Storage
journal, February 2018


Electronic Properties of Armchair Black Phosphorene Nanoribbons Edge-Modified by Transition Elements V, Cr, and Mn
journal, April 2019


A Review on Flexible and Transparent Energy Storage System
journal, November 2018