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Title: Domain Wall Motion Across Various Grain Boundaries in Ferroelectric Thin Films

Journal Article · · Journal of the American Ceramic Society
DOI:https://doi.org/10.1111/jace.13535· OSTI ID:1286790
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  1. Pennsylvania State Univ., University Park, PA (United States). Department of Materials Science and Engineering and Materials Research Inst.
  2. Univ. of Sheffield (United Kingdom). Dept. of Materials Science and Engineering
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)

Domain wall movement at and near engineered 10°, 15°, and 24° tilt and 10° and 30° twist grain boundaries was measured by band excitation piezoresponse force microscopy for Pb(Zr,Ti)O3 films with Zr/Ti ratio of 45/55 and 52/48. A minimum in nonlinear response was observed at the grain boundary for the highest angle twist and tilt grain boundaries, while a maximum in nonlinear response was observed at the 10° tilt grain boundaries. Lastly, the observed nonlinear response was correlated to the domain structure imaged in cross section by transmission electron microscopy.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC05-00OR22725; DMR-1005771; CNMS2011-022; CNMS2011-223; CNMS2013-127; EP/I038934/1
OSTI ID:
1286790
Journal Information:
Journal of the American Ceramic Society, Vol. 98, Issue 6; ISSN 0002-7820
Publisher:
American Ceramic SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 28 works
Citation information provided by
Web of Science

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Achieving ultrahigh energy storage performance in bismuth magnesium titanate film capacitors via amorphous-structure engineering journal January 2019
Scaling Effects in Perovskite Ferroelectrics: Fundamental Limits and Process-Structure-Property Relations journal July 2016

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