Flexible MXene/Carbon Nanotube Composite Paper with High Volumetric Capacitance

Zhao, Meng-Qiang; Ren, Chang E.; Ling, Zheng; Lukatskaya, Maria R.; Zhang, Chuanfang; Van Aken, Katherine L.; Barsoum, Michel W.; Gogotsi, Yury

doi:10.1002/adma.201404140

Title: Flexible MXene/Carbon Nanotube Composite Paper with High Volumetric Capacitance

Journal Article · Tue Nov 18 00:00:00 EST 2014 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201404140· OSTI ID:1265885

Zhao, Meng-Qiang ^[1]; Ren, Chang E. ^[1]; Ling, Zheng ^[2]; Lukatskaya, Maria R. ^[1]; Zhang, Chuanfang ^[3]; Van Aken, Katherine L. ^[1]; Barsoum, Michel W. ^[1]; Gogotsi, Yury ^[1]

Drexel Univ., Philadelphia, PA (United States)
Drexel Univ., Philadelphia, PA (United States); Dalian Univ. of Technology (China)
Drexel Univ., Philadelphia, PA (United States); East China Univ. of Science and Technology, Shanghai (China)

Electrochemical capacitors attract attention because of their high power densities and long cycle lives. Moreover, with increasing demand for portable and wearable electronics, recent research has focused primarily on improving the energy density per unit of volume of electrochemical capacitors. But, the volumetric capacitances of carbon-based electrodes is limited at around 60 F cm ^-3 for commercial devices, and at best in the range of 300 F cm ^-3 for low-density porous carbons (<0.5–1 g cm ^-3 ). Although extremely high capacitances of 1000–1500 F cm ^-3 can be achieved for hydrated ruthenium oxide, RuO₂ , its high cost limits its wide-spread applications.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265885

Journal Information:: Advanced Materials, Vol. 27, Issue 2; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 943 works

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Heterostructures of MXenes and N-doped graphene as highly active bifunctional electrocatalysts Zhou, Si; Yang, Xiaowei; Pei, Wei Nanoscale, Vol. 10, Issue 23 https://doi.org/10.1039/c8nr01090k	journal	January 2018
A nanoporous MXene film enables flexible supercapacitors with high energy storage Fan, Zhimin; Wang, Youshan; Xie, Zhimin Nanoscale, Vol. 10, Issue 20 https://doi.org/10.1039/c8nr01550c	journal	January 2018
Polyoxometalate-coupled MXene nanohybrid via poly(ionic liquid) linkers and its electrode for enhanced supercapacitive performance Chen, Shu; Xiang, Yuanfang; Banks, M. Katherine Nanoscale, Vol. 10, Issue 42 https://doi.org/10.1039/c8nr05760e	journal	January 2018
3D Ti ₃ C ₂ T _x aerogels with enhanced surface area for high performance supercapacitors Wang, Xinyu; Fu, Qishan; Wen, Jing Nanoscale, Vol. 10, Issue 44 https://doi.org/10.1039/c8nr06014b	journal	January 2018
A novel MnO ₂ /MXene composite prepared by electrostatic self-assembly and its use as an electrode for enhanced supercapacitive performance Chen, Shu; Xiang, Yuanfang; Xu, Weijian Inorganic Chemistry Frontiers, Vol. 6, Issue 1 https://doi.org/10.1039/c8qi00957k	journal	January 2019
A novel lithium-ion hybrid capacitor based on an aerogel-like MXene wrapped Fe ₂ O ₃ nanosphere anode and a 3D nitrogen sulphur dual-doped porous carbon cathode Tang, Xiao; Liu, Hao; Guo, Xin Materials Chemistry Frontiers, Vol. 2, Issue 10 https://doi.org/10.1039/c8qm00232k	journal	January 2018
Fe ₃ O ₄ @Ti ₃ C ₂ MXene hybrids with ultrahigh volumetric capacity as an anode material for lithium-ion batteries Wang, Yesheng; Li, Yanyan; Qiu, Zhipeng Journal of Materials Chemistry A, Vol. 6, Issue 24 https://doi.org/10.1039/c8ta00122g	journal	January 2018
Tunable pseudocapacitance storage of MXene by cation pillaring for high performance sodium-ion capacitors Luo, Jianmin; Fang, Cong; Jin, Chengbin Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta02068j	journal	January 2018
Carbon-intercalated Ti ₃ C ₂ T _x MXene for high-performance electrochemical energy storage Shen, Lei; Zhou, Xiaoya; Zhang, Xinglin Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/c8ta09600g	journal	January 2018
Integrating MXene nanosheets with cobalt-tipped carbon nanotubes for an efficient oxygen reduction reaction Chen, Jianian; Yuan, Xiaolei; Lyu, Fenglei Journal of Materials Chemistry A, Vol. 7, Issue 3 https://doi.org/10.1039/c8ta10574j	journal	January 2019
Interface engineering in the BNNS@Ti ₃ C ₂ intercalation structure for enhanced electrocatalytic hydrogen evolution Ai, Zizheng; Chang, Bin; Xu, Chengwei New Journal of Chemistry, Vol. 43, Issue 22 https://doi.org/10.1039/c9nj01504c	journal	January 2019
Synthesis of (V _2/3 Sc _1/3 ) ₂ AlC i-MAX phase and V _2−x C MXene scrolls Thörnberg, Jimmy; Halim, Joseph; Lu, Jun Nanoscale, Vol. 11, Issue 31 https://doi.org/10.1039/c9nr02354b	journal	January 2019
A facile method for synthesizing CuS decorated Ti ₃ C ₂ MXene with enhanced performance for asymmetric supercapacitors Pan, Zhihu; Cao, Fa; Hu, Xing Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta00085b	journal	January 2019
Pursuit of a high-capacity and long-life Mg-storage cathode by tailoring sandwich-structured MXene@carbon nanosphere composites Liu, Fanfan; Liu, Yongchang; Zhao, Xudong Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta02212k	journal	January 2019
Few-layered Ti ₃ C ₂ T _x MXenes coupled with Fe ₂ O ₃ nanorod arrays grown on carbon cloth as anodes for flexible asymmetric supercapacitors Li, Fei; Liu, Yi-Lin; Wang, Gui-Gen Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta08144e	journal	January 2019
Synthesis and Li-ion electrode properties of layered MAB phases Ni _n+1 ZnB _n ( n = 1, 2) Rezaie, Amir A.; Yan, Zheng; Scheifers, Jan P. Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta12937e	journal	January 2020
Superionic liquids in conducting nanoslits: A variety of phase transitions and ensuing charging behavior Dudka, Maxym; Kondrat, Svyatoslav; Bénichou, Olivier The Journal of Chemical Physics, Vol. 151, Issue 18 https://doi.org/10.1063/1.5127851	journal	November 2019
Surface-agnostic highly stretchable and bendable conductive MXene multilayers An, Hyosung; Habib, Touseef; Shah, Smit Science Advances, Vol. 4, Issue 3 https://doi.org/10.1126/sciadv.aaq0118	journal	March 2018
High-Voltage Symmetric Supercapacitor Based on 2D Titanium Carbide (MXene, Ti ₂ CT _x )/Carbon Nanosphere Composites in a Neutral Aqueous Electrolyte Melchior, Sharona A.; Raju, Kumar; Ike, Innocent S. Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.0401803jes	journal	January 2018
A Highly Flexible Supercapacitor Based on MnO2/RGO Nanosheets and Bacterial Cellulose-Filled Gel Electrolyte Fei, Haojie; Saha, Nabanita; Kazantseva, Natalia Materials, Vol. 10, Issue 11 https://doi.org/10.3390/ma10111251	journal	October 2017
Synthesis and Characterization of 2D Molybdenum Carbide (MXene) Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R. Advanced Functional Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adfm.201505328	journal	February 2016
Layer-by-Layer Assembly of Cross-Functional Semi-transparent MXene-Carbon Nanotubes Composite Films for Next-Generation Electromagnetic Interference Shielding Weng, Guo-Ming; Li, Jinyang; Alhabeb, Mohamed Advanced Functional Materials, Vol. 28, Issue 44 https://doi.org/10.1002/adfm.201803360	journal	September 2018
Engineering 3D Ion Transport Channels for Flexible MXene Films with Superior Capacitive Performance Wang, Yuanming; Wang, Xue; Li, Xiaolong Advanced Functional Materials, Vol. 29, Issue 14 https://doi.org/10.1002/adfm.201900326	journal	February 2019
Chemically Crosslinked Hydrogel Film Leads to Integrated Flexible Supercapacitors with Superior Performance Wang, Kai; Zhang, Xiong; Li, Chen Advanced Materials, Vol. 27, Issue 45 https://doi.org/10.1002/adma.201503543	journal	October 2015
A Metal-Free Supercapacitor Electrode Material with a Record High Volumetric Capacitance over 800 F cm ⁻³ Xu, Yue; Tao, Ying; Zheng, Xiaoyu Advanced Materials, Vol. 27, Issue 48 https://doi.org/10.1002/adma.201504151	journal	November 2015
Ultrathin MXene-Micropattern-Based Field-Effect Transistor for Probing Neural Activity Xu, Bingzhe; Zhu, Minshen; Zhang, Wencong Advanced Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adma.201504657	journal	February 2016
Photoluminescent Ti ₃ C ₂ MXene Quantum Dots for Multicolor Cellular Imaging Xue, Qi; Zhang, Huijie; Zhu, Minshen Advanced Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adma.201604847	journal	February 2017
Battery-Supercapacitor Hybrid Devices: Recent Progress and Future Prospects Zuo, Wenhua; Li, Ruizhi; Zhou, Cheng Advanced Science, Vol. 4, Issue 7 https://doi.org/10.1002/advs.201600539	journal	February 2017
Ultrastrong and Highly Conductive MXene‐Based Films for High‐Performance Electromagnetic Interference Shielding Liu, Ji; Liu, Zhangshuo; Zhang, Hao‐Bin Advanced Electronic Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aelm.201901094	journal	November 2019
Flexible All-Solid-State Supercapacitors with High Volumetric Capacitances Boosted by Solution Processable MXene and Electrochemically Exfoliated Graphene Li, Hongyan; Hou, Yang; Wang, Faxing Advanced Energy Materials, Vol. 7, Issue 4 https://doi.org/10.1002/aenm.201601847	journal	November 2016
2D Metal Carbides and Nitrides (MXenes) as High-Performance Electrode Materials for Lithium-Based Batteries Tang, Xiao; Guo, Xin; Wu, Wenjian Advanced Energy Materials, Vol. 8, Issue 33 https://doi.org/10.1002/aenm.201801897	journal	September 2018
Antimonene Engineered Highly Deformable Freestanding Electrode with Extraordinarily Improved Energy Storage Performance Yu, Jiali; Zhou, Jie; Yao, Pingping Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902462	journal	October 2019
Ultrathin Titanate Nanosheets/Graphene Films Derived from Confined Transformation for Excellent Na/K Ion Storage Zeng, Cheng; Xie, Fangxi; Yang, Xianfeng Angewandte Chemie, Vol. 130, Issue 28 https://doi.org/10.1002/ange.201803511	journal	June 2018
2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications Navarro-Suárez, Adriana M.; Maleski, Kathleen; Makaryan, Taron Batteries & Supercaps, Vol. 1, Issue 1 https://doi.org/10.1002/batt.201800014	journal	April 2018
Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage Ren, Chang E.; Zhao, Meng-Qiang; Makaryan, Taron ChemElectroChem, Vol. 3, Issue 5 https://doi.org/10.1002/celc.201600059	journal	February 2016
Two-Step Oxidation of Mxene in the Synthesis of Layer-Stacked Anatase Titania with Enhanced Lithium-Storage Performance Tang, Huang; Zhuang, Shihao; Bao, Zhihao ChemElectroChem, Vol. 3, Issue 6 https://doi.org/10.1002/celc.201600078	journal	April 2016
Fabrication of Cobaltosic Oxide Nanoparticle‐Doped 3 D MXene/Graphene Hybrid Porous Aerogels for All‐Solid‐State Supercapacitors Liu, Rui; Zhang, Aitang; Tang, Jianguo Chemistry – A European Journal, Vol. 25, Issue 21 https://doi.org/10.1002/chem.201806342	journal	March 2019
Synthesis of Grain-like MoS ₂ for High-Performance Sodium-Ion Batteries Yao, Kai; Xu, Zhanwei; Li, Zhi ChemSusChem, Vol. 11, Issue 13 https://doi.org/10.1002/cssc.201800512	journal	June 2018
Recent Progress of MXene-Based Nanomaterials in Flexible Energy Storage and Electronic Devices Yang, Qi; Wang, Yukun; Li, Xinliang Energy & Environmental Materials, Vol. 1, Issue 4 https://doi.org/10.1002/eem2.12023	journal	December 2018
Facile Solution Processing of Stable MXene Dispersions towards Conductive Composite Fibers Seyedin, Shayan; Zhang, Jizhen; Usman, Ken Aldren S. Global Challenges, Vol. 3, Issue 10 https://doi.org/10.1002/gch2.201900037	journal	July 2019
MXene‐Based Nonlinear Optical Information Converter for All‐Optical Modulator and Switcher Wu, Leiming; Jiang, Xiantao; Zhao, Jinlai Laser & Photonics Reviews, Vol. 12, Issue 12 https://doi.org/10.1002/lpor.201800215	journal	October 2018
Ultrafast Fabrication of TiO ₂ -Inlaid Multilayered Carbon for Supercapacitor Wang, Qingtao; Zhang, Zhonghao; Wang, Lipeng ChemistrySelect, Vol. 3, Issue 38 https://doi.org/10.1002/slct.201802576	journal	October 2018
Production of Two-Dimensional Nanomaterials via Liquid-Based Direct Exfoliation Niu, Liyong; Coleman, Jonathan N.; Zhang, Hua Small, Vol. 12, Issue 3 https://doi.org/10.1002/smll.201502207	journal	December 2015
High-Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors Wang, Zhiyu; Qin, Si; Seyedin, Shayan Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201802225	journal	August 2018
Room‐Temperature Liquid Metal Confined in MXene Paper as a Flexible, Freestanding, and Binder‐Free Anode for Next‐Generation Lithium‐Ion Batteries Wei, Chuanliang; Fei, Huifang; Tian, Yuan Small, Vol. 15, Issue 46 https://doi.org/10.1002/smll.201903214	journal	October 2019
Recent advances in MXene: Preparation, properties, and applications Lei, Jin-Cheng; Zhang, Xu; Zhou, Zhen Frontiers of Physics, Vol. 10, Issue 3 https://doi.org/10.1007/s11467-015-0493-x	journal	June 2015
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
Hierarchical porous carbons with layer-by-layer motif architectures from confined soft-template self-assembly in layered materials Wang, Jie; Tang, Jing; Ding, Bing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15717	journal	June 2017
In situ atomistic insight into the growth mechanisms of single layer 2D transition metal carbides Sang, Xiahan; Xie, Yu; Yilmaz, Dundar E. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04610-0	journal	June 2018
One-step Solution Processing of Ag, Au and Pd@MXene Hybrids for SERS Satheeshkumar, Elumalai; Makaryan, Taron; Melikyan, Armen Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep32049	journal	August 2016
H ₂ O ₂ assisted room temperature oxidation of Ti ₂ C MXene for Li-ion battery anodes Ahmed, Bilal; Anjum, Dalaver H.; Hedhili, Mohamed N. Nanoscale, Vol. 8, Issue 14 https://doi.org/10.1039/c6nr00002a	journal	January 2016
Recent progress in layered transition metal carbides and/or nitrides (MXenes) and their composites: synthesis and applications Hong Ng, Vincent Ming; Huang, Hui; Zhou, Kun Journal of Materials Chemistry A, Vol. 5, Issue 7 https://doi.org/10.1039/c6ta06772g	journal	January 2017
Highly conductive and flexible molybdenum oxide nanopaper for high volumetric supercapacitor electrode Huang, Liang; Yao, Bin; Sun, Jiyu Journal of Materials Chemistry A, Vol. 5, Issue 6 https://doi.org/10.1039/c6ta10433a	journal	January 2017
Titanium carbide sheet based high performance wire type solid state supercapacitors Krishnamoorthy, Karthikeyan; Pazhamalai, Parthiban; Sahoo, Surjit Journal of Materials Chemistry A, Vol. 5, Issue 12 https://doi.org/10.1039/c6ta11198j	journal	January 2017
Latest advances in supercapacitors: from new electrode materials to novel device designs Wang, Faxing; Wu, Xiongwei; Yuan, Xinhai Chemical Society Reviews, Vol. 46, Issue 22 https://doi.org/10.1039/c7cs00205j	journal	January 2017
Sb ₂ O ₃ /MXene(Ti ₃ C ₂ T _x ) hybrid anode materials with enhanced performance for sodium-ion batteries Guo, Xin; Xie, Xiuqiang; Choi, Sinho Journal of Materials Chemistry A, Vol. 5, Issue 24 https://doi.org/10.1039/c7ta02689g	journal	January 2017
Freestanding CoSeO ₃ ·H ₂ O nanoribbon/carbon nanotube composite paper for 2.4 V high-voltage, flexible, solid-state supercapacitors Jiang, Yingchang; Wu, Zeyi; Jiang, Le Nanoscale, Vol. 10, Issue 25 https://doi.org/10.1039/c8nr02924e	journal	January 2018
A comparative study on the oxidation of two-dimensional Ti ₃ C ₂ MXene structures in different environments Lotfi, Roghayyeh; Naguib, Michael; Yilmaz, Dundar E. Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta01468j	journal	January 2018
Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance VahidMohammadi, Armin; Moncada, Jorge; Chen, Hengze Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta05807e	journal	January 2018
A flexible VOCs sensor based on a 3D Mxene framework with a high sensing performance Yuan, Wenjing; Yang, Kai; Peng, Huifen Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/c8ta06928j	journal	January 2018
Mo ₂ B, an MBene member with high electrical and thermal conductivities, and satisfactory performances in lithium ion batteries Zha, Xian-Hu; Xu, Pengxiang; Huang, Qing Nanoscale Advances, Vol. 2, Issue 1 https://doi.org/10.1039/c9na00610a	journal	January 2020
A high-performance trace level acetone sensor using an indispensable V ₄ C ₃ T _x MXene Zhao, Wei-Na; Yun, Na; Dai, Zhen-Hua RSC Advances, Vol. 10, Issue 3 https://doi.org/10.1039/c9ra09069j	journal	January 2020
Fabrication of novel MXene (Ti ₃ C ₂ )/polyacrylamide nanocomposite hydrogels with enhanced mechanical and drug release properties Zhang, Peng; Yang, Xiu-Jie; Li, Peng Soft Matter, Vol. 16, Issue 1 https://doi.org/10.1039/c9sm01985e	journal	January 2020
Solution-processed single-wall carbon nanotube transistor arrays for wearable display backplanes Kang, Byeong-Cheol; Ha, Tae-Jun AIP Advances, Vol. 8, Issue 1 https://doi.org/10.1063/1.5017794	journal	January 2018
Effects of biaxial strain and functional groups on SiC/ti ₃ C ₂ heterostructure: a first principle calculation Li, Chenliang; Tian, Bingkun; Yang, Yong Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab49c8	journal	November 2019
Composites of TiO ₂ Nanoparticles Deposited on Ti ₃ C ₂ MXene Nanosheets with Enhanced Electrochemical Performance Zhu, JianFeng; Tang, Yi; Yang, ChenHui Journal of The Electrochemical Society, Vol. 163, Issue 5 https://doi.org/10.1149/2.0981605jes	journal	January 2016
Stretchable Supercapacitor with Adjustable Volumetric Capacitance Based on 3D Interdigital Electrodes Li, Fengwang; Chen, Jitao; Wang, Xusheng Advanced Functional Materials, Vol. 25, Issue 29 https://doi.org/10.1002/adfm.201500718	journal	June 2015
Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance Yan, Jun; Ren, Chang E.; Maleski, Kathleen Advanced Functional Materials, Vol. 27, Issue 30 https://doi.org/10.1002/adfm.201701264	journal	June 2017
Highly Conductive Transition Metal Carbide/Carbonitride(MXene)@polystyrene Nanocomposites Fabricated by Electrostatic Assembly for Highly Efficient Electromagnetic Interference Shielding Sun, Renhui; Zhang, Hao-Bin; Liu, Ji Advanced Functional Materials, Vol. 27, Issue 45 https://doi.org/10.1002/adfm.201702807	journal	October 2017
High-Performance Ultrathin Flexible Solid-State Supercapacitors Based on Solution Processable Mo _1.33 C MXene and PEDOT:PSS Qin, Leiqiang; Tao, Quanzheng; El Ghazaly, Ahmed Advanced Functional Materials, Vol. 28, Issue 2 https://doi.org/10.1002/adfm.201703808	journal	November 2017
Flexible Ti ₃ C ₂ T _x @Al electrodes with Ultrahigh Areal Capacitance: In Situ Regulation of Interlayer Conductivity and Spacing Guo, Miao; Liu, Chengbin; Zhang, Zezhong Advanced Functional Materials, Vol. 28, Issue 37 https://doi.org/10.1002/adfm.201803196	journal	July 2018
Infiltrated Porous Polymer Sheets as Free-Standing Flexible Lithium-Sulfur Battery Electrodes Wu, Feixiang; Zhao, Enbo; Gordon, Daniel Advanced Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adma.201600757	journal	May 2016
Interwoven MXene Nanosheet/Carbon-Nanotube Composites as Li-S Cathode Hosts Liang, Xiao; Rangom, Yverick; Kwok, Chun Yuen Advanced Materials, Vol. 29, Issue 3 https://doi.org/10.1002/adma.201603040	journal	November 2016
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes) Hantanasirisakul, Kanit; Gogotsi, Yury Advanced Materials, Vol. 30, Issue 52 https://doi.org/10.1002/adma.201804779	journal	November 2018
Highly Stretchable and Self‐Healable MXene/Polyvinyl Alcohol Hydrogel Electrode for Wearable Capacitive Electronic Skin Zhang, Jiaqi; Wan, Lijia; Gao, Yang Advanced Electronic Materials, Vol. 5, Issue 7 https://doi.org/10.1002/aelm.201900285	journal	May 2019
Functional MXene Materials: Progress of Their Applications Li, Xiuqin; Wang, Chengyin; Cao, Yu Chemistry - An Asian Journal, Vol. 13, Issue 19 https://doi.org/10.1002/asia.201800543	journal	August 2018
Hierarchical Cobalt Borate/MXenes Hybrid with Extraordinary Electrocatalytic Performance in Oxygen Evolution Reaction Liu, Jiapeng; Chen, Tao; Juan, Peng ChemSusChem, Vol. 11, Issue 21 https://doi.org/10.1002/cssc.201802098	journal	October 2018
A Flexible Si@C Electrode with Excellent Stability Employing an MXene as a Multifunctional Binder for Lithium‐Ion Batteries Zhang, Peng; Zhu, Qizhen; Guan, Zhaoruxin ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201901497	journal	August 2019
Niobium carbide/reduced graphene oxide hybrid porous aerogel as high capacity and long‐life anode material for Li‐ion batteries Butt, Rehman; Siddique, Ahmad Hassan; Bokhari, Syeda Wishal International Journal of Energy Research, Vol. 43, Issue 9 https://doi.org/10.1002/er.4598	journal	May 2019
Self‐Standing Hybrid Film of SnO ₂ Nanotubes and MXene as A High‐Performance Anode Material for Thin Film Lithium‐Ion Batteries Wang, Kexin; Zhu, Xiaodong; Wang, Chuang ChemistrySelect, Vol. 4, Issue 41 https://doi.org/10.1002/slct.201903537	journal	November 2019
Chemically Integrated Inorganic-Graphene Two-Dimensional Hybrid Materials for Flexible Energy Storage Devices Peng, Lele; Zhu, Yue; Li, Hongsen Small, Vol. 12, Issue 45 https://doi.org/10.1002/smll.201602109	journal	October 2016
Recent Advances in Layered Ti ₃ C ₂ T _x MXene for Electrochemical Energy Storage Xiong, Dongbin; Li, Xifei; Bai, Zhimin Small, Vol. 14, Issue 17 https://doi.org/10.1002/smll.201703419	journal	February 2018
Facile synthesis of MXene/MnO2 composite with high specific capacitance Wang, Qingtao; Zhang, Zhonghao; Zhang, Zhao Journal of Solid State Electrochemistry, Vol. 23, Issue 2 https://doi.org/10.1007/s10008-018-4143-4	journal	November 2018
Highly conductive dodecaborate/MXene composites for high performance supercapacitors Li, Zhenxing; Ma, Chang; Wen, Yangyang Nano Research, Vol. 13, Issue 1 https://doi.org/10.1007/s12274-019-2597-z	journal	December 2019
Vibrational properties of Ti ₃ C ₂ and Ti ₃ C ₂ T ₂ (T = O, F, OH) monosheets by first-principles calculations: a comparative study Hu, Tao; Wang, Jiemin; Zhang, Hui Physical Chemistry Chemical Physics, Vol. 17, Issue 15 https://doi.org/10.1039/c4cp05666c	journal	January 2015
Self-assembled Ti ₃ C ₂ T _x MXene film with high gravimetric capacitance Hu, Minmin; Li, Zhaojin; Zhang, Hui Chemical Communications, Vol. 51, Issue 70 https://doi.org/10.1039/c5cc04722f	journal	January 2015
3D assembly of Ti ₃ C ₂ -MXene directed by water/oil interfaces Bian, Renji; Lin, Ruizhi; Wang, Guilin Nanoscale, Vol. 10, Issue 8 https://doi.org/10.1039/c7nr07346a	journal	January 2018
In situ synthesis of CNTs@Ti ₃ C ₂ hybrid structures by microwave irradiation for high-performance anodes in lithium ion batteries Zheng, W.; Zhang, P.; Chen, J. Journal of Materials Chemistry A, Vol. 6, Issue 8 https://doi.org/10.1039/c7ta10394h	journal	January 2018
Effect of glycine functionalization of 2D titanium carbide (MXene) on charge storage Chen, Chi; Boota, Muhammad; Urbankowski, Patrick Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/c7ta11347a	journal	January 2018
MXene-supported Co ₃ O ₄ quantum dots for superior lithium storage and oxygen evolution activities Wang, Chuang; Zhu, Xiao-Dong; Mao, Ya-Chun Chemical Communications, Vol. 55, Issue 9 https://doi.org/10.1039/c8cc09699f	journal	January 2019
Flexible Ti ₃ C ₂ T _x /PEDOT:PSS films with outstanding volumetric capacitance for asymmetric supercapacitors Li, Lu; Zhang, Na; Zhang, Mingyi Dalton Transactions, Vol. 48, Issue 5 https://doi.org/10.1039/c8dt04374d	journal	January 2019
Sulfur nanodots as MoS ₂ antiblocking agent for stable sodium ion battery anodes Xu, Zhanwei; Yao, Kai; Li, Zhi Journal of Materials Chemistry A, Vol. 6, Issue 22 https://doi.org/10.1039/c8ta02339e	journal	January 2018
MXene and MXene-based composites: synthesis, properties and environment-related applications Zhan, Xiaoxue; Si, Chen; Zhou, Jian Nanoscale Horizons, Vol. 5, Issue 2 https://doi.org/10.1039/c9nh00571d	journal	January 2020
Improving the performance of a titanium carbide MXene in supercapacitors by partial oxidation treatment Zhang, Miao; Chen, Xifan; Sui, Jinyi Inorganic Chemistry Frontiers, Vol. 7, Issue 5 https://doi.org/10.1039/c9qi01588d	journal	January 2020
A general way to fabricate transition metal dichalcogenide/oxide-sandwiched MXene nanosheets as flexible film anodes for high-performance lithium storage Wang, Chuang; Zhu, Xiao-Dong; Wang, Ke-Xin Sustainable Energy & Fuels, Vol. 3, Issue 10 https://doi.org/10.1039/c9se00635d	journal	January 2019
Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors Dong, Liubing; Yang, Wang; Yang, Wu Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta02678a	journal	January 2019
A wearable, self-adhesive, long-lastingly moist and healable epidermal sensor assembled from conductive MXene nanocomposites Wu, Xiaoxuan; Liao, Hui; Ma, Di Journal of Materials Chemistry C, Vol. 8, Issue 5 https://doi.org/10.1039/c9tc05575d	journal	January 2020
Peaked dielectric responses in Ti ₃ C ₂ MXene nanosheets enabled composites with efficient microwave absorption Luo, Heng; Feng, Wanlin; Liao, Congwei Journal of Applied Physics, Vol. 123, Issue 10 https://doi.org/10.1063/1.5008323	journal	March 2018
A perspective on two-dimensional materials for planar micro-supercapacitors Qin, Jieqiong; Das, Pratteek; Zheng, Shuanghao APL Materials, Vol. 7, Issue 9 https://doi.org/10.1063/1.5113940	journal	September 2019
Pseudocapacitive materials for electrochemical capacitors: from rational synthesis to capacitance optimization Wang, Jie; Dong, Shengyang; Ding, Bing National Science Review, Vol. 4, Issue 1 https://doi.org/10.1093/nsr/nww072	journal	December 2016
Fabrication of Flexible, Lightweight, Magnetic Mushroom Gills and Coral-Like MXene–Carbon Nanotube Nanocomposites for EMI Shielding Application Raagulan, Kanthasamy; Braveenth, Ramanaskanda; Ro Lee, Lee Nanomaterials, Vol. 9, Issue 4 https://doi.org/10.3390/nano9040519	journal	April 2019
Hierarchical Ni-Co Hydroxide Petals on Mechanically Robust Graphene Petal Foam for High-Energy Asymmetric Supercapacitors Xiong, Guoping; He, Pingge; Wang, Dini Advanced Functional Materials, Vol. 26, Issue 30 https://doi.org/10.1002/adfm.201600879	journal	May 2016
Waterproof, Ultrahigh Areal-Capacitance, Wearable Supercapacitor Fabrics Yang, Yu; Huang, Qiyao; Niu, Liyong Advanced Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adma.201606679	journal	February 2017
Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance Zhang, Chuanfang John; Anasori, Babak; Seral-Ascaso, Andrés Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201702678	journal	July 2017
Facile Synthesis of Crumpled Nitrogen-Doped MXene Nanosheets as a New Sulfur Host for Lithium-Sulfur Batteries Bao, Weizhai; Liu, Lin; Wang, Chengyin Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702485	journal	January 2018
MXene Aerogel Scaffolds for High‐Rate Lithium Metal Anodes Zhang, Xinyue; Lv, Ruijing; Wang, Aoxuan Angewandte Chemie, Vol. 130, Issue 46 https://doi.org/10.1002/ange.201808714	journal	October 2018
An Ultrafast Conducting Polymer@MXene Positive Electrode with High Volumetric Capacitance for Advanced Asymmetric Supercapacitors Li, Ke; Wang, Xuehang; Li, Shuo Small, Vol. 16, Issue 4 https://doi.org/10.1002/smll.201906851	journal	December 2019
Ultrathin and Flexible CNTs/MXene/Cellulose Nanofibrils Composite Paper for Electromagnetic Interference Shielding Cao, Wentao; Ma, Chang; Tan, Shuo Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0304-y	journal	September 2019
Rational control of the interlayer space inside two-dimensional titanium carbides for highly efficient uranium removal and imprisonment Wang, Lin; Tao, Wuqing; Yuan, Liyong Chemical Communications, Vol. 53, Issue 89 https://doi.org/10.1039/c7cc06740b	journal	January 2017
2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes) Urbankowski, Patrick; Anasori, Babak; Hantanasirisakul, Kanit Nanoscale, Vol. 9, Issue 45 https://doi.org/10.1039/c7nr06721f	journal	January 2017
“All-in-Gel” design for supercapacitors towards solid-state energy devices with thermal and mechanical compliance Yin, Chengyao; Liu, Xinhua; Wei, Junjie Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta01155b	journal	January 2019
Nitrogen and Sulfur Co-Doped 2D Titanium Carbides for Enhanced Electrochemical Performance Yang, Chenhui; Que, Wenxiu; Tang, Yi Journal of The Electrochemical Society, Vol. 164, Issue 9 https://doi.org/10.1149/2.1091709jes	journal	January 2017
Measurement and Analysis of Thermal Conductivity of Ti3C2Tx MXene Films Chen, Lin; Shi, Xuguo; Yu, Nanjie Materials, Vol. 11, Issue 9 https://doi.org/10.3390/ma11091701	journal	September 2018
Recent advances in flexible supercapacitors based on carbon nanotubes and graphene Li, Kang; Zhang, Jintao Science China Materials, Vol. 61, Issue 2 https://doi.org/10.1007/s40843-017-9154-2	journal	December 2017
Bio-inspired high-performance solid-state supercapacitors with the electrolyte, separator, binder and electrodes entirely from kelp Zeng, Juan; Wei, Lu; Guo, Xin Journal of Materials Chemistry A, Vol. 5, Issue 48 https://doi.org/10.1039/c7ta08095f	journal	January 2017
Two-dimensional MXene-reinforced robust surface superhydrophobicity with self-cleaning and photothermal-actuating binary effects Cao, Wen-Tao; Feng, Wei; Jiang, Ying-Ying Materials Horizons, Vol. 6, Issue 5 https://doi.org/10.1039/c8mh01566j	journal	January 2019
2D Ti3C2Tx (MXene)-reinforced polyvinyl alcohol (PVA) nanofibers with enhanced mechanical and electrical properties Sobolčiak, Patrik; Ali, Adnan; Hassan, Mohammad K. PLOS ONE, Vol. 12, Issue 8 https://doi.org/10.1371/journal.pone.0183705	journal	August 2017
Amine-Assisted Delamination of Nb ₂ C MXene for Li-Ion Energy Storage Devices Mashtalir, Olha; Lukatskaya, Maria R.; Zhao, Meng-Qiang Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500604	journal	April 2015
Bifunctional Hybrid Ni/Ni ₂ P Nanoparticles Encapsulated by Graphitic Carbon Supported with N, S Modified 3D Carbon Framework for Highly Efficient Overall Water Splitting Sun, Yiqiang; Zhang, Tao; Li, Xinyang Advanced Materials Interfaces, Vol. 5, Issue 15 https://doi.org/10.1002/admi.201800473	journal	June 2018
Emergent Pseudocapacitance of 2D Nanomaterials Yu, Xu; Yun, Sol; Yeon, Jeong Seok Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702930	journal	February 2018
2 D MXene‐based Energy Storage Materials: Interfacial Structure Design and Functionalization Fang, Ruyi; Lu, Chengwei; Chen, Anqi ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201902537	journal	March 2020
Flexible 3D Porous MXene Foam for High‐Performance Lithium‐Ion Batteries Zhao, Qian; Zhu, Qizhen; Miao, Jiawei Small, Vol. 15, Issue 51 https://doi.org/10.1002/smll.201904293	journal	October 2019
Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers Chen, Chi; Boota, Muhammad; Xie, Xiuqiang Journal of Materials Chemistry A, Vol. 5, Issue 11 https://doi.org/10.1039/c7ta00149e	journal	January 2017
Conjugated systems of porphyrin–carbon nanoallotropes: a review S., Supriya; Shetti, Vijayendra S.; Hegde, Gurumurthy New Journal of Chemistry, Vol. 42, Issue 15 https://doi.org/10.1039/c8nj02254b	journal	January 2018
Out-of-plane ion transport makes nitrogenated holey graphite a promising high-rate anode for both Li and Na ion batteries Huang, He; Wu, Hong-Hui; Chi, Cheng Nanoscale, Vol. 11, Issue 40 https://doi.org/10.1039/c9nr06011a	journal	January 2019
Carbon–metal compound composite electrodes for capacitive deionization: synthesis, development and applications Tang, Kexin; Hong, Terence Zhi Xiang; You, Liming Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta08663c	journal	January 2019
Preparation of Ti3C2Tx/NiZn Ferrite Hybrids with Improved Electromagnetic Properties Zhou, Xiaobing; Li, Youbing; Huang, Qing Materials, Vol. 13, Issue 4 https://doi.org/10.3390/ma13040820	journal	February 2020
Deformation and Failure of MXene Nanosheets Zeleniakiene, Daiva; Monastyreckis, Gediminas; Aniskevich, Andrey Materials, Vol. 13, Issue 5 https://doi.org/10.3390/ma13051253	journal	March 2020

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