Cyclic Corrosion and Chlorination of an FeCrAl Alloy in the Presence of KCl

Israelsson, Niklas; Unocic, Kinga A.; Hellström, K.; Svensson, J-E; Johansson, L-G

doi:10.1007/s11085-015-9554-3

Title: Cyclic Corrosion and Chlorination of an FeCrAl Alloy in the Presence of KCl

Journal Article · Sat May 30 00:00:00 EDT 2015 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-015-9554-3· OSTI ID:1265764

Israelsson, Niklas ^[1]; Unocic, Kinga A. ^[2]; Hellström, K. ^[1]; Svensson, J-E ^[1]; Johansson, L-G ^[1]

Chalmers Univ. of Tech., Goteborg (Sweden)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The KCl-induced corrosion of the FeCrAl alloy Kanthal® APMT in an O² + N² + H₂O environment was studied at 600 °C. The samples were pre-oxidized prior to exposure in order to investigate the protective nature of alumina scales in the present environment. The microstructure and composition of the corroded surface was investigated in detail. Corrosion started at flaws in the pre-formed α-alumina scales, i.e. α-alumina was protective in itself. Consequently, KCl-induced corrosion started locally and, subsequently, spread laterally. An electrochemical mechanism is proposed here by which a transition metal chloride forms in the alloy and K₂CrO₄ forms at the scale/gas interface. Scale de-cohesion is attributed to the formation of a sub-scale transition metal chloride.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265764

Journal Information:: Oxidation of Metals, Vol. 84, Issue 3-4; ISSN 0030-770X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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References (30)

The Influence of KCl on the Corrosion of an Austenitic Stainless Steel (304L) in Oxidizing Humid Conditions at 600 °C: A Microstructural Study Jonsson, T.; Froitzheim, J.; Pettersson, J. Oxidation of Metals, Vol. 72, Issue 3-4 https://doi.org/10.1007/s11085-009-9156-z	journal	May 2009
High temperature corrosion of coatings and boiler steels below chlorine-containing salt deposits Uusitalo, M. A.; Vuoristo, P. M. J.; Mäntylä, T. A. Corrosion Science, Vol. 46, Issue 6 https://doi.org/10.1016/j.corsci.2003.09.026	journal	June 2004
Alumina Scale Formation on a Powder Metallurgical FeCrAl Alloy (Kanthal APMT) at 900–1,100 °C in Dry O2 and in O2 + H2O Engkvist, J.; Canovic, S.; Hellström, K. Oxidation of Metals, Vol. 73, Issue 1-2 https://doi.org/10.1007/s11085-009-9177-7	journal	September 2009
Are NaCl and KCl equally corrosive on superheater materials of steam boilers? Enestam, Sonja; Bankiewicz, Dorota; Tuiremo, Johanna Fuel, Vol. 104 https://doi.org/10.1016/j.fuel.2012.07.020	journal	February 2013
Alkali Induced High Temperature Corrosion of Stainless Steel: The Influence of NaCl, KCl and CaCl2 Karlsson, S.; Pettersson, J.; Johansson, L. -G. Oxidation of Metals, Vol. 78, Issue 1-2 https://doi.org/10.1007/s11085-012-9293-7	journal	April 2012
An ESEM in situ investigation of initial stages of the KCl induced high temperature corrosion of a Fe–2.25Cr–1Mo steel at 400°C Jonsson, T.; Folkeson, N.; Svensson, J. -E. Corrosion Science, Vol. 53, Issue 6 https://doi.org/10.1016/j.corsci.2011.03.007	journal	June 2011
KCl-induced high temperature corrosion of the austenitic Fe–Cr–Ni alloys 304L and Sanicro 28 at 600°C Pettersson, C.; Pettersson, J.; Asteman, H. Corrosion Science, Vol. 48, Issue 6 https://doi.org/10.1016/j.corsci.2005.05.018	journal	June 2006
Two strategies to reduce gaseous KCl and chlorine in deposits during biomass combustion — injection of ammonium sulphate and co-combustion with peat Kassman, Håkan; Pettersson, Jesper; Steenari, Britt-Marie Fuel Processing Technology, Vol. 105 https://doi.org/10.1016/j.fuproc.2011.06.025	journal	January 2013
FactSage thermochemical software and databases — recent developments Bale, C. W.; Bélisle, E.; Chartrand, P. Calphad, Vol. 33, Issue 2 https://doi.org/10.1016/j.calphad.2008.09.009	journal	June 2009
Properties of Danish biofuels and the requirements for power production Sander, Bo Biomass and Bioenergy, Vol. 12, Issue 3 https://doi.org/10.1016/S0961-9534(96)00072-4	journal	January 1997
High temperature interaction of Al/Si-modified Fe–Cr alloys with KCl Li, Y. S.; Niu, Y.; Spiegel, M. Corrosion Science, Vol. 49, Issue 4 https://doi.org/10.1016/j.corsci.2006.10.019	journal	April 2007
Deposition and high temperature corrosion in a 10 MW straw fired boiler Michelsen, Hanne Philbert; Frandsen, Flemming; Dam-Johansen, Kim Fuel Processing Technology, Vol. 54, Issue 1-3 https://doi.org/10.1016/S0378-3820(97)00062-3	journal	March 1998
The formation of aluminum oxide scales on high-temperature alloys Prescott, R.; Graham, M. J. Oxidation of Metals, Vol. 38, Issue 3-4 https://doi.org/10.1007/BF00666913	journal	October 1992
Temperature dependence of metastable alumina formation during thermal oxidation of FeCrAl foils Berthomé, G.; N'Dah, E.; Wouters, Y. Materials and Corrosion, Vol. 56, Issue 6 https://doi.org/10.1002/maco.200403851	journal	June 2005
Biomass-fired power generation Bain, Richard L.; Overend, Ralph P.; Craig, Kevin R. Fuel Processing Technology, Vol. 54, Issue 1-3 https://doi.org/10.1016/S0378-3820(97)00058-1	journal	March 1998
Oxidation of FeCrAl alloy: influence of temperature and atmosphere on scale growth rate and mechanism Badini, C.; Laurella, F. Surface and Coatings Technology, Vol. 135, Issue 2-3 https://doi.org/10.1016/S0257-8972(00)00989-0	journal	January 2001
The behavior of inorganic material in biomass-fired power boilers: field and laboratory experiences Baxter, Larry L.; Miles, Thomas R.; Miles, Thomas R. Fuel Processing Technology, Vol. 54, Issue 1-3 https://doi.org/10.1016/S0378-3820(97)00060-X	journal	March 1998
Microstructural investigation of the breakdown of the protective oxide scale on a 304 steel in the presence of oxygen and water vapour at 600°C Halvarsson, M.; Tang, J. E.; Asteman, H. Corrosion Science, Vol. 48, Issue 8 https://doi.org/10.1016/j.corsci.2005.08.012	journal	August 2006
In-situ corrosion investigation at Masnedø CHP plant - a straw-fired power plant Montgomery, M.; Karlsson, A. Materials and Corrosion, Vol. 50, Issue 10 https://doi.org/10.1002/(SICI)1521-4176(199910)50:10<579::AID-MACO579>3.0.CO;2-M	journal	October 1999
Combustion properties of biomass Jenkins, B. M.; Baxter, L. L.; Miles, T. R. Fuel Processing Technology, Vol. 54, Issue 1-3 https://doi.org/10.1016/S0378-3820(97)00059-3	journal	March 1998
KCl-Induced Corrosion of the FeCrAl Alloy Kanthal ® AF at 600 °C and the Effect of H2O Israelsson, N.; Hellström, K.; Svensson, J. -E. Oxidation of Metals, Vol. 83, Issue 1-2 https://doi.org/10.1007/s11085-014-9506-3	journal	October 2014
KCl-Induced Corrosion of an FeCrAl Alloy at 600 °C in O2 + H2O Environment: The Effect of Pre-oxidation Israelsson, N.; Engkvist, J.; Hellström, K. Oxidation of Metals, Vol. 83, Issue 1-2 https://doi.org/10.1007/s11085-014-9507-2	journal	October 2014
Diffusion of the Chlorine Ion in Potassium Chloride Fuller, Robert G. Physical Review, Vol. 142, Issue 2 https://doi.org/10.1103/PhysRev.142.524	journal	February 1966
The effects of chlorides, hydrogen chloride, and sulfur dioxide in the oxidation of steels below deposits Grabke, H. J.; Reese, E.; Spiegel, M. Corrosion Science, Vol. 37, Issue 7 https://doi.org/10.1016/0010-938X(95)00011-8	journal	July 1995
High temperature corrosion of superheater steels by KCl and K2CO3 under dry and wet conditions Lehmusto, J.; Yrjas, P.; Skrifvars, B. -J. Fuel Processing Technology, Vol. 104 https://doi.org/10.1016/j.fuproc.2012.05.020	journal	December 2012
In-situ Impedence Spectroscopy Study of Electrical Conductivity and Ionic Transport in Thermally Grown Oxide Scales on a Commercial FeCrAl Alloy Öijerholm, J.; Pan, J.; Lu, Q. Oxidation of Metals, Vol. 68, Issue 5-6 https://doi.org/10.1007/s11085-007-9074-x	journal	October 2007
Corrosion of superheater materials in a waste-to-energy plant Viklund, Peter; Hjörnhede, Anders; Henderson, Pamela Fuel Processing Technology, Vol. 105 https://doi.org/10.1016/j.fuproc.2011.06.017	journal	January 2013
The Influence of Small Amounts of KCl(s) on the Initial Stages of the Corrosion of Alloy Sanicro 28 at 600 °C Pettersson, C.; Johansson, L. -G.; Svensson, J. -E. Oxidation of Metals, Vol. 70, Issue 5-6 https://doi.org/10.1007/s11085-008-9118-x	journal	August 2008
Initial Stages of the HCl-Induced High-Temperature Corrosion of Alloy 310 Folkeson, N.; Johansson, L. -G.; Svensson, J. -E. Journal of The Electrochemical Society, Vol. 154, Issue 9 https://doi.org/10.1149/1.2754174	journal	January 2007
Diffusion in alkali and alkaline earth halides Beniere, F. Diffusion in Non-Metallic Solids https://doi.org/10.1007/10542761_6	book	January 1999

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
FeCrAl
Pre-oxidation
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Water vapour
KCl

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