Influence of dioxygen on the promotional effect of Bi during Pt-catalyzed oxidation of 1,6-hexanediol

Xie, Jiahan; Huang, Benjamin; Yin, Kehua; Pham, Hien N.; Unocic, Raymond R.; Datye, Abhaya K.; Davis, Robert J.

doi:10.1021/acscatal.6b00972

Title: Influence of dioxygen on the promotional effect of Bi during Pt-catalyzed oxidation of 1,6-hexanediol

Journal Article · Tue May 24 00:00:00 EDT 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.6b00972· OSTI ID:1261533

Xie, Jiahan ^[1]; Huang, Benjamin ^[1]; Yin, Kehua ^[1]; Pham, Hien N. ^[2]; Unocic, Raymond R. ^[3]; Datye, Abhaya K. ^[2]; Davis, Robert J. ^[1]

Univ. of Virginia, Charlottesville, VA (United States)
Univ. of New Mexico, Albuquerque, NM (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In this study, a series of carbon-supported, Bi-promoted Pt catalysts with various Bi/Pt atomic ratios was prepared by selectively depositing Bi on Pt nanoparticles. The catalysts were evaluated for 1,6-hexanediol oxidation activity in aqueous solvent under different dioxygen pressures. The rate of diol oxidation on the basis of Pt loading over a Bi-promoted catalyst was 3 times faster than that of an unpromoted Pt catalyst under 0.02 MPa of O₂, whereas the unpromoted catalyst was more active than the promoted catalyst under 1 MPa of O₂. After liquid-phase catalyst pretreatment and 1,6-hexanediol oxidation, migration of Bi on the carbon support was observed. The reaction order in O₂ was 0 over Bi-promoted Pt/C in comparison to 0.75 over unpromoted Pt/C in the range of 0.02–0.2 MPa of O₂. Under low O₂ pressure, rate measurements in D₂O instead of H₂O solvent revealed a moderate kinetic isotope effect (rate_H₂O/rate_D₂O) on 1,6-hexanediol oxidation over Pt/C (KIE = 1.4), whereas a negligible effect was observed on Bi-Pt/C (KIE = 0.9), indicating that the promotional effect of Bi could be related to the formation of surface hydroxyl groups from the reaction of dioxygen and water. No significant change in product distribution or catalyst stability was observed with Bi promotion, regardless of the dioxygen pressure.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261533

Journal Information:: ACS Catalysis, Vol. 6, Issue 7; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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References (68)

Selective oxidation of alcohols and aldehydes on metal catalysts Besson, Michèle; Gallezot, Pierre Catalysis Today, Vol. 57, Issue 1-2 https://doi.org/10.1016/S0920-5861(99)00315-6	journal	March 2000
Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts Mallat, Tamas; Baiker, Alfons Chemical Reviews, Vol. 104, Issue 6 https://doi.org/10.1021/cr0200116	journal	June 2004
Chemical Routes for the Transformation of Biomass into Chemicals Corma, Avelino; Iborra, Sara; Velty, Alexandra Chemical Reviews, Vol. 107, Issue 6, p. 2411-2502 https://doi.org/10.1021/cr050989d	journal	June 2007
A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose Kröger, Martin; Prüße, Ulf; Vorlop, Klaus‐Dieter Topics in Catalysis, Vol. 13, Issue 3, p. 237-242 https://doi.org/10.1023/A:1009017929727	journal	August 2000
Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide Carrettin, Silvio; McMorn, Paul; Johnston, Peter Chemical Communications, Issue 7 https://doi.org/10.1039/b201112n	journal	March 2002
Oxidation of glycerol using supported Pt, Pd and Au catalysts Carrettin, Silvio; McMorn, Paul; Johnston, Peter Physical Chemistry Chemical Physics, Vol. 5, Issue 6 https://doi.org/10.1039/b212047j	journal	February 2003
Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst: an insight into reaction selectivity Porta, Francesca; Prati, Laura Journal of Catalysis, Vol. 224, Issue 2 https://doi.org/10.1016/j.jcat.2004.03.009	journal	June 2004
Use of renewables for the production of chemicals: Glycerol oxidation over carbon supported gold catalysts Demirel, S.; Lehnert, K.; Lucas, M. Applied Catalysis B: Environmental, Vol. 70, Issue 1-4 https://doi.org/10.1016/j.apcatb.2005.11.036	journal	January 2007
Biomass into Chemicals: Aerobic Oxidation of 5-Hydroxymethyl-2-furfural into 2,5-Furandicarboxylic Acid with Gold Nanoparticle Catalysts Casanova, Onofre; Iborra, Sara; Corma, Avelino ChemSusChem, Vol. 2, Issue 12 https://doi.org/10.1002/cssc.200900137	journal	December 2009
Reactivity of the Gold/Water Interface During Selective Oxidation Catalysis Zope, B. N.; Hibbitts, D. D.; Neurock, M. Science, Vol. 330, Issue 6000 https://doi.org/10.1126/science.1195055	journal	September 2010
Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts Davis, Sara E.; Houk, Levi R.; Tamargo, Erin C. Catalysis Today, Vol. 160, Issue 1, p. 55-60 https://doi.org/10.1016/j.cattod.2010.06.004	journal	February 2011
Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure Gupta, Navneet Kumar; Nishimura, Shun; Takagaki, Atsushi Green Chemistry, Vol. 13, Issue 4 https://doi.org/10.1039/c0gc00911c	journal	January 2011
Inhibition of gold and platinum catalysts by reactive intermediates produced in the selective oxidation of alcohols in liquid water Zope, Bhushan N.; Davis, Robert J. Green Chemistry, Vol. 13, Issue 12 https://doi.org/10.1039/c1gc15953d	journal	January 2011
On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts Davis, Sara E.; Zope, Bhushan N.; Davis, Robert J. Green Chemistry, Vol. 14, Issue 1, p. 143-147 https://doi.org/10.1039/C1GC16074E	journal	January 2012
Perspectives on the kinetics of diol oxidation over supported platinum catalysts in aqueous solution Ide, Matthew S.; Davis, Robert J. Journal of Catalysis, Vol. 308 https://doi.org/10.1016/j.jcat.2013.05.017	journal	December 2013
Selective oxidation of alcohols and aldehydes over supported metal nanoparticles Davis, Sara E.; Ide, Matthew S.; Davis, Robert J. Green Chem., Vol. 15, Issue 1 https://doi.org/10.1039/C2GC36441G	journal	January 2013
Efficient aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran on supported Ru catalysts Nie, Junfang; Xie, Jiahan; Liu, Haichao Journal of Catalysis, Vol. 301 https://doi.org/10.1016/j.jcat.2013.01.007	journal	May 2013
Aqueous-phase selective aerobic oxidation of 5-hydroxymethylfurfural on Ru/C in the presence of base Xie, Jiahan; Nie, Junfang; Liu, Haichao Chinese Journal of Catalysis, Vol. 35, Issue 6 https://doi.org/10.1016/S1872-2067(14)60136-4	journal	June 2014
Influence of Reaction Conditions on Diacid Formation During Au-Catalyzed Oxidation of Glycerol and Hydroxymethylfurfural Zope, Bhushan N.; Davis, Sara E.; Davis, Robert J. Topics in Catalysis, Vol. 55, Issue 1-2, p. 24-32 https://doi.org/10.1007/s11244-012-9777-3	journal	February 2012
On the deactivation of supported platinum catalysts for selective oxidation of alcohols Ide, Matthew S.; Falcone, Derek D.; Davis, Robert J. Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.12.002	journal	March 2014
Selective oxidation with air on metal catalysts Gallezot, Pierre Catalysis Today, Vol. 37, Issue 4 https://doi.org/10.1016/S0920-5861(97)00024-2	journal	September 1997
Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO2 Chapman, Adrian O.; Akien, Geoffrey R.; Arrowsmith, Nicholas J. Green Chemistry, Vol. 12, Issue 2 https://doi.org/10.1039/b913434d	journal	January 2010
Role of Bi promotion and solvent in platinum-catalyzed alcohol oxidation probed by in situ X-ray absorption and ATR-IR spectroscopy Mondelli, Cecilia; Grunwaldt, Jan-Dierk; Ferri, Davide Physical Chemistry Chemical Physics, Vol. 12, Issue 20 https://doi.org/10.1039/b926833b	journal	January 2010
A simple discrimination of the promoter effect in alcohol oxidation and dehydrogenation over platinum and palladium Keresszegi, C. Journal of Catalysis, Vol. 225, Issue 1 https://doi.org/10.1016/j.jcat.2004.04.002	journal	July 2004
Partial oxidation of cinnamyl alcohol on bimetallic catalysts of improved resistance to self-poisoning Mallat, T.; Bodnar, Z.; Maciejewski, M. New Developments in Selective Oxidation II, Proceedings of the Second World Congress and Fourth European Workshop Meeting https://doi.org/10.1016/S0167-2991(08)63449-7	book	January 1994
Platinum-catalyzed oxidation of alcohols in aqueous solutions. The role of Bi-promotion in suppression of Catalyst Deactivation Mallat, T.; Bodnar, Z.; Brönnimann, C. Catalyst Deactivation 1994, Proceedings of the 6th International Symposium https://doi.org/10.1016/S0167-2991(08)62764-0	book	January 1994
Selective Oxidation of Cinnamyl Alcohol to Cinnamaldehyde with Air over Bi-Pt/Alumina Catalysts Mallat, T.; Bodnar, Z.; Hug, P. Journal of Catalysis, Vol. 153, Issue 1 https://doi.org/10.1006/jcat.1995.1115	journal	April 1995
Partial oxidation of water—insoluble alcohols over Bi—promoted Pt on alumina. Electrochemical characterization of the catalyst in its working state Mallat, T.; Bodnar, Z.; Baiker, A. Studies in Surface Science and Catalysis https://doi.org/10.1016/S0167-2991(08)63343-1	book	January 1993
Selective Oxidation of Alcohols to Carbonyl Compounds and Carboxylic Acids with Platinum Group Metal Catalysts Anderson, Ross; Griffin, Ken; Johnston, Peter Advanced Synthesis & Catalysis, Vol. 345, Issue 4 https://doi.org/10.1002/adsc.200390060	journal	April 2003
Platinum−Bismuth-Catalyzed Oxidation of Glycerol: Kinetics and the Origin of Selective Deactivation Worz, N.; Brandner, A.; Claus, P. The Journal of Physical Chemistry C, Vol. 114, Issue 2 https://doi.org/10.1021/jp909412h	journal	December 2009
Heterogeneous oxidation of 2-octanol on 5wt%Pt–1wt%Bi/Carbon catalyst Mounzer, H. N.; Wood, J.; Stitt, E. H. Chemical Engineering Science, Vol. 65, Issue 1 https://doi.org/10.1016/j.ces.2009.05.050	journal	January 2010
Heterogeneous electrocatalysis on well-defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms Fernandez-Vega, A.; Feliu, J. M.; Aldaz, A. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 305, Issue 2 https://doi.org/10.1016/0022-0728(91)85521-P	journal	May 1991
Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms Clavilier, J.; Fernandez-Vega, A.; Feliu, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 258, Issue 1 https://doi.org/10.1016/0022-0728(89)85164-2	journal	January 1989
Deactivation of metal catalysts in liquid phase organic reactions Besson, Michèle; Gallezot, Pierre Catalysis Today, Vol. 81, Issue 4 https://doi.org/10.1016/S0920-5861(03)00153-6	journal	July 2003
Highly Selective Electro-Oxidation of Glycerol to Dihydroxyacetone on Platinum in the Presence of Bismuth Kwon, Youngkook; Birdja, Yuvraj; Spanos, Ioannis ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200599g	journal	April 2012
Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed bed reactor Kimura, Hiroshi Applied Catalysis A: General, Vol. 105, Issue 2 https://doi.org/10.1016/0926-860X(93)80245-L	journal	November 1993
Aerobic oxidation of secondary pyridine-derivative alcohols in the presence of carbon-supported noble metal catalysts Frassoldati, Antonio; Pinel, Catherine; Besson, Michèle Catalysis Today, Vol. 203 https://doi.org/10.1016/j.cattod.2012.01.012	journal	March 2013
Synthesis of HCV Replicase Inhibitors: Base-Catalyzed Synthesis of Protected α-Hydrazino Esters and Selective Aerobic Oxidation with Catalytic Pt/Bi/C for Synthesis of Imidazole-4,5-dicarbaldehyde Bowman, Roy K.; Brown, Andrew D.; Cobb, Jannine H. The Journal of Organic Chemistry, Vol. 78, Issue 23 https://doi.org/10.1021/jo4014595	journal	November 2013
Direct alcohol fuel cells: Increasing platinum performance by modification with sp-group metals Figueiredo, Marta C.; Sorsa, Olli; Doan, Nguyet Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.034	journal	February 2015
Tailoring properties of platinum supported catalysts by irreversible adsorbed adatoms toward ethanol oxidation for direct ethanol fuel cells Figueiredo, Marta C.; Santasalo-Aarnio, Annukka; Vidal-Iglesias, Francisco J. Applied Catalysis B: Environmental, Vol. 140-141 https://doi.org/10.1016/j.apcatb.2013.04.038	journal	August 2013
Effect of Deposited Bismuth on the Potential of Maximum Entropy of Pt(111) Single-Crystal Electrodes Climent, V.; Garcia-Araez, N.; Compton, R. G. The Journal of Physical Chemistry B, Vol. 110, Issue 42 https://doi.org/10.1021/jp061982i	journal	October 2006
Evidence of Water Reorientation on Model Electrocatalytic Surfaces from Nanosecond-Laser-Pulsed Experiments García-Aráez, Nuria; Climent, Víctor; Feliu, Juan M. Journal of the American Chemical Society, Vol. 130, Issue 12 https://doi.org/10.1021/ja0761481	journal	March 2008
Direct ethanol fuel cell: Electrochemical performance at 90°C on Pt and PtSn/C electrocatalysts Purgato, F. L. S.; Pronier, S.; Olivi, P. Journal of Power Sources, Vol. 198 https://doi.org/10.1016/j.jpowsour.2011.09.060	journal	January 2012
Supported catalysts for alcohol oxidation synthesis and analysis of their catalytic activity Ramos, S. G.; Calafiore, A.; Bonesi, A. R. International Journal of Hydrogen Energy, Vol. 37, Issue 19 https://doi.org/10.1016/j.ijhydene.2012.01.171	journal	October 2012
Chemical reconstruction and catalysis of metal and bimetallic surfaces Tanaka, Ken-ichi Surface Science, Vol. 357-358 https://doi.org/10.1016/0039-6028(96)00253-1	journal	June 1996
Evolution of Structure and Chemistry of Bimetallic Nanoparticle Catalysts under Reaction Conditions Tao, Feng; Grass, Michael E.; Zhang, Yawen Journal of the American Chemical Society, Vol. 132, Issue 25 https://doi.org/10.1021/ja101502t	journal	June 2010
Designing nanoscopic, fluxional bimetallic Pt–Ru alloy hydrogenation catalysts for improved sulfur tolerance Stanley, Jessica N. G.; Worthington, Katy; Heinroth, Falk Catalysis Today, Vol. 178, Issue 1 https://doi.org/10.1016/j.cattod.2011.09.014	journal	December 2011
Potential-Dependent Restructuring and Hysteresis in the Structural and Electronic Transformations of Pt/C, Au(Core)-Pt(Shell)/C, and Pd(Core)-Pt(Shell)/C Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by in Situ X-ray Absorption Fine Structure Nagamatsu, Shin-ichi; Arai, Takashi; Yamamoto, Masakuni The Journal of Physical Chemistry C, Vol. 117, Issue 25 https://doi.org/10.1021/jp402438e	journal	June 2013
Island Formation on Pt/Pd(557) Surface Alloys in the Presence of Adsorbed CO: A Molecular Dynamics Study Michalka, Joseph R.; Gezelter, J. Daniel The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.5b03586	journal	June 2015
Straightforward synthesis of bimetallic Co/Pt nanoparticles in ionic liquid: atomic rearrangement driven by reduction–sulfidation processes and Fischer–Tropsch catalysis Silva, Dagoberto O.; Luza, Leandro; Gual, Aitor Nanoscale, Vol. 6, Issue 15 https://doi.org/10.1039/C4NR02018A	journal	January 2014
Nanocatalysis II: In Situ Surface Probes of Nano-Catalysts and Correlative Structure–Reactivity Studies Alayoglu, Selim; Somorjai, Gabor A. Catalysis Letters, Vol. 145, Issue 1 https://doi.org/10.1007/s10562-014-1398-y	journal	November 2014
Crotonaldehyde hydrogenation over alumina- and silica-supported Pt–Sn catalysts of different composition. In situ DRIFT study Coloma, Fernando; Llorca, Jordi; Homs, Narcís Physical Chemistry Chemical Physics, Vol. 2, Issue 13 https://doi.org/10.1039/b002005m	journal	January 2000
CO oxidation on PtSn nanoparticle catalysts occurs at the interface of Pt and Sn oxide domains formed under reaction conditions Michalak, William D.; Krier, James M.; Alayoglu, Selim Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.005	journal	April 2014
Restructuring of supported PtSn bimetallic catalysts during aqueous phase oxidation of 1,6-hexanediol Xie, Jiahan; Falcone, Derek D.; Davis, Robert J. Journal of Catalysis, Vol. 332 https://doi.org/10.1016/j.jcat.2015.09.011	journal	December 2015
Influence of Sn content on PtSn/C catalysts for electrooxidation of C1–C3 alcohols: Synthesis, characterization, and electrocatalytic activity Kim, Jae Hong; Choi, Sung Mook; Nam, Sang Hoon Applied Catalysis B: Environmental, Vol. 82, Issue 1-2 https://doi.org/10.1016/j.apcatb.2008.01.011	journal	July 2008
Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 Yeh, J. J.; Lindau, I. Atomic Data and Nuclear Data Tables, Vol. 32, Issue 1 https://doi.org/10.1016/0092-640X(85)90016-6	journal	January 1985
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Correct Application of the Sulphite Oxidation Methodology of Measuring the Volumetric Mass Transfer Coefficient kLa Under Non-Pressurized and Pressurized Conditions Maier, B.; Dietrich, C.; Büchs, J. Food and Bioproducts Processing, Vol. 79, Issue 2 https://doi.org/10.1205/096030801750286267	journal	June 2001
Underpotential deposition of metals on foreign metal substrates Szabó, S. International Reviews in Physical Chemistry, Vol. 10, Issue 2 https://doi.org/10.1080/01442359109353258	journal	April 1991
In situ FTIR, EXAFS, and activity studies of the effect of crystallite size on silica-supported Pt oxidation catalysts Gracia, F. J.; Bollmann, L.; Wolf, E. E. Journal of Catalysis, Vol. 220, Issue 2 https://doi.org/10.1016/S0021-9517(03)00296-3	journal	December 2003
Determination of CO, H2O and H2 coverage by XANES and EXAFS on Pt and Au during water gas shift reaction Guo, Neng; Fingland, Bradley R.; Williams, W. Damion Physical Chemistry Chemical Physics, Vol. 12, Issue 21 https://doi.org/10.1039/c000240m	journal	January 2010
Solubility of hydrogen in small particles of palladium Boudart, M. Journal of Catalysis, Vol. 39, Issue 1 https://doi.org/10.1016/0021-9517(75)90280-8	journal	July 1975
The Bi-Pt (Bismuth-Platinum) system Okamoto, H. Journal of Phase Equilibria, Vol. 12, Issue 2 https://doi.org/10.1007/BF02645718	journal	April 1991
Oxidative Transformation of Intermetallic Nanoparticles: An Alternative Pathway to Metal/Oxide Nanocomposites, Textured Ceramics, and Nanocrystalline Multimetal Oxides Dawood, Farah; Leonard, Brian M.; Schaak, Raymond E. Chemistry of Materials, Vol. 19, Issue 18 https://doi.org/10.1021/cm071147t	journal	September 2007
Structural and optical characteristics of bismuth oxide thin films Leontie, L.; Caraman, M.; Alexe, M. Surface Science, Vol. 507-510 https://doi.org/10.1016/S0039-6028(02)01289-X	journal	June 2002
Interpretation of Measurements in Experimental Catalysis Weisz, P. B.; Prater, C. D. Advances in Catalysis, Vol. 6, p. 143-196 https://doi.org/10.1016/S0360-0564(08)60390-9	book	January 1954
Selective Oxidation of Methyl α- d -Glucopyranoside with Oxygen over Supported Platinum: Kinetic Modeling in the Presence of Deactivation by Overoxidation of the Catalyst Vleeming, Johannes H.; Kuster, Ben F. M.; Marin, Guy B. Industrial & Engineering Chemistry Research, Vol. 36, Issue 9 https://doi.org/10.1021/ie9607659	journal	September 1997
Non-steady state behaviour of fixed bed catalytic reactors due to catalyst fouling Froment, G. F.; Bischoff, K. B. Chemical Engineering Science, Vol. 16, Issue 3-4 https://doi.org/10.1016/0009-2509(61)80030-4	journal	December 1961

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
alcohol oxidation
Bi
catalyst restructuring
dioxygen pressure
heterogeneous catalysts
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promotional effect
Pt

Title: Influence of dioxygen on the promotional effect of Bi during Pt-catalyzed oxidation of 1,6-hexanediol

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