Highly dispersed buckybowls as model carbocatalysts for C–H bond activation

Soykal, I. Ilgaz; Wang, Hui; Park, Jewook; Li, An-Ping; Liang, Chengdu; Schwartz, Viviane

doi:10.1039/C5TA00898K

Title: Highly dispersed buckybowls as model carbocatalysts for C–H bond activation

Journal Article · Thu Mar 19 00:00:00 EDT 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA00898K· OSTI ID:1261424

Soykal, I. Ilgaz ^[1]; Wang, Hui ^[1]; Park, Jewook ^[1]; Li, An-Ping ^[1]; Liang, Chengdu ^[1]; Schwartz, Viviane ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)

Buckybowl fractions dispersed on mesoporous silica constitute an ideal model for studying the catalysis of graphitic forms of carbon since the dispersed carbon nanostructures contain a high ratio of edge defects and curvature induced by non-six-membered rings. Dispersion of the active centers on an easily accessible high surface area material allowed for high density of surface active sites associated with oxygenated structures. This report illustrates a facile method of creating model polycyclic aromatic nano-structures that are not only active for alkane C-H bond activation and oxidative dehydrogenation but also can be practical catalysts to be eventually used in industry.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261424

Journal Information:: Journal of Materials Chemistry. A, Vol. 3, Issue 16; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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