Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution

Lu, Qi; Hutchings, Gregory S.; Yu, Weiting; Zhou, Yang; Forest, Robert V.; Tao, Runzhe; Rosen, Jonathan; Yonemoto, Bryan T.; Cao, Zeyuan; Zheng, Haimei; Xiao, John Q.; Jiao, Feng; Chen, Jingguang G.

doi:10.1038/ncomms7567

Title: Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution

Journal Article · Mon Mar 16 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms7567· OSTI ID:1256016

Lu, Qi ^[1];

^[2]; Yu, Weiting ^[3]; Zhou, Yang ^[2]; Forest, Robert V. ^[2]; Tao, Runzhe ^[4]; Rosen, Jonathan ^[2]; Yonemoto, Bryan T. ^[2]; Cao, Zeyuan ^[2]; Zheng, Haimei ^[4]; Xiao, John Q. ^[2]; Jiao, Feng ^[2]; Chen, Jingguang G. ^[3]

Univ. of Delaware, Newark, DE (United States); Columbia Univ., New York, NY (United States)
Univ. of Delaware, Newark, DE (United States)
Columbia Univ., New York, NY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

One of the key components of carbon dioxide-free hydrogen production is a robust and efficient non-precious metal catalyst for the hydrogen evolution reaction. We report that a hierarchical nanoporous copper-titanium bimetallic electrocatalyst is able to produce hydrogen from water under a mild overpotential at more than twice the rate of state-of-the- art carbon-supported platinum catalyst. Although both copper and titanium are known to be poor hydrogen evolution catalysts, the combination of these two elements creates unique copper-copper-titanium hollow sites, which have a hydrogen-binding energy very similar to that of platinum, resulting in an exceptional hydrogen evolution activity. Moreover, the hierarchical porosity of the nanoporous-copper titanium catalyst also contributes to its high hydrogen evolution activity, because it provides a large-surface area for electrocatalytic hydrogen evolution, and improves the mass transport properties. Moreover, the catalyst is self-supported, eliminating the overpotential associated with the catalyst/support interface.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-13ER16381; SC0009476

OSTI ID:: 1256016

Journal Information:: Nature Communications, Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 400 works

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Direct deposition of MoSe ₂ nanocrystals onto conducting substrates: towards ultra-efficient electrocatalysts for hydrogen evolution Damien, Dijo; Anil, Athira; Chatterjee, Dipanwita Journal of Materials Chemistry A, Vol. 5, Issue 26 https://doi.org/10.1039/c6ta09645j	journal	January 2017
Conducting polymer nanofiber-supported Pt alloys: unprecedented materials for methanol oxidation with enhanced electrocatalytic performance and stability Ghosh, Srabanti; Bera, Susmita; Bysakh, Sandip Sustainable Energy & Fuels, Vol. 1, Issue 5 https://doi.org/10.1039/c7se00126f	journal	January 2017
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Highly conductive and metallic cobalt–nickel selenide nanorods supported on Ni foam as an efficient electrocatalyst for alkaline water splitting Liu, Shu; Jiang, Yimin; Yang, Miao Nanoscale, Vol. 11, Issue 16 https://doi.org/10.1039/c8nr10545f	journal	January 2019
Quasi-single-crystalline CoO hexagrams with abundant defects for highly efficient electrocatalytic water oxidation Liang, Zuozhong; Huang, Zhehao; Yuan, Haitao Chemical Science, Vol. 9, Issue 34 https://doi.org/10.1039/c8sc02294a	journal	January 2018
On the role of hydroxide species in sulphur- and nitrogen-doped cobalt-based carbon catalysts for the oxygen evolution reaction Shahraei, Ali; Kuebler, Markus; Martinaiou, Ioanna Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta05769a	journal	January 2018
3D nanoporous Ni/V ₂ O ₃ hybrid nanoplate assemblies for highly efficient electrochemical hydrogen evolution Ming, Mei; Ma, Yuling; Zhang, Yun Journal of Materials Chemistry A, Vol. 6, Issue 43 https://doi.org/10.1039/c8ta07701k	journal	January 2018
Transition metal modification and carbon vacancy promoted Cr ₂ CO ₂ (MXenes): a new opportunity for a highly active catalyst for the hydrogen evolution reaction Cheng, Yu-Wen; Dai, Jian-Hong; Zhang, Yu-Min Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/c8ta07749e	journal	January 2018
A substrate-free Mo ₂ C-based electrocatalyst by facile glucose-blowing for efficient hydrogen production Li, Xiao; Hu, Xiao-Li; Wang, Xin-Long New Journal of Chemistry, Vol. 43, Issue 48 https://doi.org/10.1039/c9nj04598h	journal	January 2019
Synthesis of Ni _4.5 Fe _4.5 S ₈ /Ni ₃ S ₂ film on Ni ₃ Fe alloy foam as an excellent electrocatalyst for the oxygen evolution reaction Qin, Shili; Lei, Jinlong; Xiong, Yun RSC Advances, Vol. 9, Issue 18 https://doi.org/10.1039/c9ra00724e	journal	January 2019
Rational construction of macroporous CoFeP triangular plate arrays from bimetal–organic frameworks as high-performance overall water-splitting catalysts Zhang, Ling; Wang, Xingyue; Li, Ang Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta05282h	journal	January 2019
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Electrospun Carbon Nanofibers with Embedded Co-Ceria Nanoparticles for Efficient Hydrogen Evolution and Overall Water Splitting Woo, Seongwon; Lee, Jooyoung; Lee, Dong Sub Materials, Vol. 13, Issue 4 https://doi.org/10.3390/ma13040856	journal	February 2020

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