Mesoporous metal oxide graphene nanocomposite materials

Liu, Jun; Aksay, Ilhan A.; Kou, Rong; Wang, Donghai

Title: Mesoporous metal oxide graphene nanocomposite materials

Patent · Tue May 24 00:00:00 EDT 2016

OSTI ID:1254266

Liu, Jun; Aksay, Ilhan A.; Kou, Rong; Wang, Donghai

A nanocomposite material formed of graphene and a mesoporous metal oxide having a demonstrated specific capacity of more than 200 F/g with particular utility when employed in supercapacitor applications. A method for making these nanocomposite materials by first forming a mixture of graphene, a surfactant, and a metal oxide precursor, precipitating the metal oxide precursor with the surfactant from the mixture to form a mesoporous metal oxide. The mesoporous metal oxide is then deposited onto a surface of the graphene.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC06-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 9,346,680

Application Number:: 12/553,527

OSTI ID:: 1254266

Resource Relation:: Patent File Date: 2009 Sep 03

Country of Publication:: United States

Language:: English

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Nanocomposite of graphene and metal oxide materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8257867 US Patent Document 8,257,867	patent	September 2012
Lithium ion batteries with titania/graphene anodes Liu, Jun; Choi, Daiwon; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8450014 US Patent Document 8,450,014	patent	May 2013
Titania-graphene anode electrode paper Liu, Jun; Choi, Daiwon; Bennett, Wendy D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8557441 US Patent Document 8,557,441	patent	October 2013
Nanocomposite of graphene and metal oxide materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8557442 US Patent Document 8,557,442	patent	October 2013
Titania-graphene anode electrode paper Liu, Jun; Choi, Daiwon; Bennett, Wendy D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9040200 US Patent Document 9,040,200	patent	May 2015
Thin-film-like particles having skeleton constructed by carbons and isolated films Hirata, Masukazu; Horiuchi, Shigeo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20020022122 US Patent Application 09/923404; 20020022122	patent-application	February 2002
Graphite platelet nanostructures Mazurkiewicz, Marian https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20020054995 US Patent Application 09/951532; 20020054995	patent-application	May 2002
Phosphate powder compositions and methods for forming particles with complex anions Chaloner-Gill, Benjamin; Pinoli, Allison A.; Horne, Craig R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20020192137 US Patent Application 09/845985; 20020192137	patent-application	December 2002
Method for producing nanocarbon materials Kawakami, Soichiro; Yamamoto, Tomoya; Sano, Hitomi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030086859 US Patent Application 10/263754; 20030086859	patent-application	May 2003
Sorting of single-walled carbon nanotubes using optical dipole traps Zhang, Yuegang; Hannah, Eric; Koo, TAe-Woong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040120880 US Patent Application 10/669150; 20040120880	patent-application	June 2004
Mesoporous network electrode for electrochemical cell Sugnaux, Francois; Graetzel, Michael; Pappas, Nicholas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040131934 US Patent Application 10/472732; 20040131934	patent-application	July 2004
Electrospun mesoporous molecular sieve fibers Balkus, JR., Kenneth J.; Ferraris, John P.; Madhugiri, Sudha https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040137225 US Patent Application 10/601102; 20040137225	patent-application	July 2004
Nanocrystalline ceramic materials reinforced with single-wall carbon nanotubes Zhan, Guodong; Mukherjee, Amiya K.; Kuntz, Joshua D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040150140 US Patent Application 10/356729; 20040150140	patent-application	August 2004
Carbon fine powder coated with metal oxide, metal nitride or metal carbide, process for producing the sdame, and supercapacitor and secondary battery carbon fine powder Homma, Itaru; Hibino, Mitsuhiro https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060154071 US Patent Application 10/526669; 20060154071	patent-application	July 2006
Thermally exfoliated graphite oxide Prud'Homme, Robert K.; Aksay, Ilhan A.; Adamson, Douglas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070092432 US Patent Application 11/249404; 20070092432	patent-application	April 2007
Highly conductive nano-scaled graphene plate nanocomposites and products Song, Lulu; Guo, Jiusheng; Zhamu, Aruna https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070158618 US Patent Application 11/328880; 20070158618	patent-application	July 2007
Nanowire structures comprising carbon Niu, Chunming https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070212538 US Patent Application 11/601842; 20070212538	patent-application	September 2007
Metal Oxide/Hydroxide Materials Harbour, Peter James; Hartley, Patrick Gordon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070281854 US Patent Application 10/578620; 20070281854	patent-application	December 2007
Fullerene Nanotube Compositions Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080063585 US Patent Application 11/931031; 20080063585	patent-application	March 2008
Low-temperature method of producing nano-scaled graphene platelets and their nanocomposites Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080258359 US Patent Application 11/787442; 20080258359	patent-application	October 2008
Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080279756 US Patent Application 11/800728; 20080279756	patent-application	November 2008
Conductive ink containing thermally exfoliated graphite oxide and method of making a conductive circuit using the same Prud'Homme, Robert K.; Aksay, Ilhan A.; Adamson, Doughlas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080302561 US Patent Application 12/194030; 20080302561	patent-application	December 2008
Wire Coating Containing Thermally exfoliated Graphite Oxide Prud'homme, Robert K.; Aksay, Ilhan A.; Adamson, Douglas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080312368 US Patent Application 12/194007; 20080312368	patent-application	December 2008
Nano graphene platelet-based composite anode compositions for lithium ion batteries Zhamu, Aruna; Jang, Bor https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090117467 US Patent Application 11/982672; 20090117467	patent-application	May 2009
High Performance Batteries with Carbon Nanomaterials and Ionic Liquids Lu, Wen https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090246625 US Patent Application 12/412047; 20090246625	patent-application	October 2009
Volatile Chemical Substance Catching Device and Electronic Apparatus Doshoda, Hiroshi; Kagawa, Toshiaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090290897 US Patent Application 12/468257; 20090290897	patent-application	November 2009
Graphene-based structure, method of suspending graphene membrane, and method of depositing material onto graphene membrane Zettl, Alexander K.; Meyer, Jannick Christian https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090291270 US Patent Application 12/409938; 20090291270	patent-application	November 2009
Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries Deng, Haixia; Belharouak, Ilias; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090297947 US Patent Application 12/454748; 20090297947	patent-application	December 2009
Nanoporous Electrodes and Related Devices and Methods Nair, Vinod M. P.; Margolese, David; Anz, Samir J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090303660 US Patent Application 12/482056; 20090303660	patent-application	December 2009
Conductive nanocomposite-based electrodes for lithium batteries Shi, Jinjun; Zhamu, Aruna; Jang, Bor Z. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090305135 US Patent Application 12/156644; 20090305135	patent-application	December 2009
Nanocomposite of graphene and metal oxide materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100081057 US Patent Application 12/460993; 20100081057	patent-application	April 2010
Nano graphene reinforced nanocomposite particles for lithium battery electrodes Zhamu, Aruna; Jang, Bor; Shi, Jinjun https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100143798 US Patent Application 12/315555; 20100143798	patent-application	June 2010
Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices Shao-Horn, Yang; Lee, Seung Woo; Yabuuchi, Naoaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100159366 US Patent Application 12/541305; 20100159366	patent-application	June 2010
Process for producing nano graphene reinforced composite particles for lithium battery electrodes Zhamu, Aruna; Jang, Bor Z. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100176337 US Patent Application 12/319812; 20100176337	patent-application	July 2010
Self assembled multi-layer nanocomposite of graphene and metal oxide materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110033746 US Patent Application 12/462857; 20110033746	patent-application	February 2011
Self Assembled Multi-Layer Nanocomposite of Graphene and Metal Oxide Materials Liu, Jun; Choi, Daiwon; Kou, Rong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110045347 US Patent Application 12/852794; 20110045347	patent-application	February 2011
Layer-Layer Lithium Rich Complex Metal Oxides with High Specific Capacity and Excellent Cycling Lopez, Herman A.; Venkatachalam, Subramanian; Karthikeyan, Deepak Kumaar Kandasamy https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110052981 US Patent Application 12/869976; 20110052981	patent-application	March 2011
Lithium Ion Batteries with Titania/Graphene Anodes Liu, Jun; Choi, Daiwon; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110111299 US Patent Application 12/901526; 20110111299	patent-application	May 2011
Titania-Graphene Anode Electrode Paper Liu, Jun; Choi, Daiwon; Bennett, Wendy D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120088158 US Patent Application 12/901527; 20120088158	patent-application	April 2012
Mesoporous Metal Oxide Graphene Nanocomposite Materials Liu, Jun; Aksay, Ilhan A.; Kou, Rong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120295027 US Patent Application 13/559538; 20120295027	patent-application	November 2012
Nanocomposite of Graphene and Metal Oxide Materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120295096 US Patent Application 13/559528; 20120295096	patent-application	November 2012
Self Assembled Multi-Layer Nanocomposite of Graphene and Metal Oxide Materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120305165 US Patent Application 13/585741; 20120305165	patent-application	December 2012
Titania-Graphene Anode Electrode Paper Liu, Jun; Choi, Daiwon; Bennett, Wendy D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140023925 US Patent Application 14/040462; 20140023925	patent-application	January 2014
Nanocomposite of Graphene and Metal Oxide Materials Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140030181 US Patent Application 14/043707; 20140030181	patent-application	January 2014

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