skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Removal of introduced inorganic content from chipped forest residues via air classification

Journal Article · · Fuel

Inorganic content in biomass decreases the efficiency of conversion processes, especially thermochemical conversions. The combined concentrations of specific ash forming elements are the primary attributes that cause pine residues to be considered a degraded energy conversion feedstock, as compared to clean pine. Air classification is a potentially effective and economical tool to isolate high inorganic content biomass fractions away from primary feedstock sources to reduce their ash content. In this work, loblolly pine forest residues were air classified into 10 fractions whose ash content and composition were measured. Ash concentrations were highest in the lightest fractions (5.8–8.5 wt%), and in a heavy fraction of the fines (8.9–15.1 wt%). The removal of fractions with high inorganic content resulted in a substantial reduction in the ash content of the remaining biomass in forest thinnings (1.69–1.07 wt%) and logging residues (1.09–0.68 wt%). These high inorganic content fractions from both forest residue types represented less than 7.0 wt% of the total biomass, yet they contained greater than 40% of the ash content by mass. Elemental analysis of the air classified fractions revealed the lightest fractions were comprised of high concentrations of soil elements (silicon, aluminum, iron, sodium, and titanium). However, the elements of biological origin including calcium, potassium, magnesium, sulfur, manganese, and phosphorous were evenly distributed throughout all air classified fractions, making them more difficult to isolate into fractions with high mineral concentrations. Under the conditions reported in this study, an economic analysis revealed air classification could be used for ash removal for as little as $2.23 per ton of product biomass. As a result, this study suggests air classification is a potentially attractive technology for the removal of introduced soil minerals from pine forest residues.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC07-05ID14517
OSTI ID:
1251416
Alternate ID(s):
OSTI ID: 1247733
Report Number(s):
INL/JOU-15-34523; PII: S0016236115007917
Journal Information:
Fuel, Vol. 160, Issue C; ISSN 0016-2361
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science

References (39)

Renewable fuels and chemicals by thermal processing of biomass journal March 2003
Pyrolysis Mechanisms of Biomass Materials journal August 2009
A review on gasification of biomass journal January 2009
Availability of logging residues and potential for electricity production and carbon displacement in the USA journal December 2006
Biomass as feedstock for a bioenergy and bioproducts industry: The technical feasibility of a billion-ton annual supply report April 2005
Bio-fuels from thermochemical conversion of renewable resources: A review journal February 2008
Review of fast pyrolysis of biomass and product upgrading journal March 2012
Molecular characterization of the pyrolysis of biomass journal March 1987
Biomass feedstocks for renewable fuel production: a review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors journal January 2014
Fast Pyrolysis of African and European Lignocellulosic Biomasses Using Py-GC/MS and Fluidized Bed Reactor journal February 2010
Influence of pretreatment for deashing of sugarcane bagasse on pyrolysis products journal November 2004
The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability journal June 2008
Influence of mineral matter on biomass pyrolysis characteristics journal December 1995
Survey of influence of biomass mineral matter in thermochemical conversion of short rotation willow coppice journal December 2008
Phosphorus catalysis in the pyrolysis behaviour of biomass journal November 2008
Influence of inorganic salts on the primary pyrolysis products of cellulose journal June 2010
A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass journal April 2011
Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies journal January 2008
Ash deposition during biomass and coal combustion: A mechanistic approach journal January 1993
Combustion properties of biomass journal March 1998
Chlorine in Solid Fuels Fired in Pulverized Fuel Boilers — Sources, Forms, Reactions, and Consequences: a Literature Review journal July 2009
The implications of chlorine-associated corrosion on the operation of biomass-fired boilers journal June 2000
Formulation, Pretreatment, and Densification Options to Improve Biomass Specifications for Co-Firing High Percentages with Coal journal June 2012
Ash Management Review—Applications of Biomass Bottom Ash journal October 2012
Fractionation of Forest Residues of Douglas-fir for Fermentable Sugar Production by SPORL Pretreatment journal May 2012
Improving Woody Biomass Feedstock Logistics by Reducing Ash and Moisture Content journal January 2014
In-wood grinding and screening of forest residues for biomass feedstock applications journal July 2013
Chemical forms of ash-forming elements in woody biomass fuels journal February 2010
Distribution of radiocesium and stable elements within a pine tree journal May 2011
Wood density within Norway spruce stems journal January 2008
Liquid uptake in Scots pine sapwood and hardwood visualized and quantified by neutron radiography journal June 2013
Assessing sapwood depth and wood properties in Eucalyptus and Corymbia spp. using visual methods and near infrared spectroscopy (NIR) journal January 2012
An overview of the chemical composition of biomass journal May 2010
Characterization of Pinus spp needles and evaluation of their potential use for energy journal June 2014
Characterization of Pinus sp of Needle to Assess Their Possible Industrial Applications journal April 2014
An overview of the composition and application of biomass ash. Part 1. Phase–mineral and chemical composition and classification journal March 2013
An overview of the organic and inorganic phase composition of biomass journal April 2012
Trace element concentrations and associations in some biomass ashes journal August 2014
Biomass properties in association with plant species and assortments. II: A synthesis based on literature data for ash elements journal June 2012

Cited By (4)

Assessment of municipal solid waste for valorization into biofuels journal June 2019
Sources of Biomass Feedstock Variability and the Potential Impact on Biofuels Production journal November 2015
Wear Properties of Ash Minerals in Biomass journal November 2018
An integrated sustainability evaluation of high‐octane gasoline production from lignocellulosic biomass journal August 2019