Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition

Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R.; Parks, II, James E.; Dai, Sheng

doi:10.1002/anie.201506093

Title: Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition

Journal Article · Fri Sep 11 00:00:00 EDT 2015 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201506093· OSTI ID:1247937

Binder, Andrew J. ^[1]; Toops, Todd J. ^[1]; Unocic, Raymond R. ^[2]; Parks, II, James E. ^[2]; Dai, Sheng ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Platinum group metal (PGM) catalysts are the current standard for control of pollutants in automotive exhaust streams. Aside from their high cost, PGM catalysts struggle with CO oxidation at low temperatures (<200 °C) due to inhibition by hydrocarbons in exhaust streams. Here we present a ternary mixed oxide catalyst composed of copper oxide, cobalt oxide, and ceria (dubbed CCC) that outperforms synthesized and commercial PGM catalysts for CO oxidation in simulated exhaust streams while showing no signs of inhibition by propene. Diffuse reflectance IR (DRIFTS) and light-off data both indicate low interaction between propene and the CO oxidation active site on this catalyst, and a separation of adsorption sites is proposed as the cause of this inhibition resistance. In conclusion, this catalyst shows great potential as a low-cost component for low temperature exhaust streams that are expected to be a characteristic of future automotive systems.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1247937

Journal Information:: Angewandte Chemie (International Edition), Vol. 54, Issue 45; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 75 works

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