skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

Journal Article · · Nature Communications
DOI:https://doi.org/10.1038/ncomms10683· OSTI ID:1243188

Here we demonstrate for the first time that planar Na-NiCl2 batteries can be operated at an intermediate temperature of 190°C with ultra-high energy density. A specific energy density of 350 Wh/kg, which is 3 times higher than that of conventional tubular Na-NiCl2 batteries operated at 280°C, was obtained for planar Na-NiCl2 batteries operated at 190°C over a long-term cell test (1000 cycles). The high energy density and superior cycle stability are attributed to the slower particle growth of the cathode materials (NaCl and Ni) at 190°C. The results reported in this work demonstrate that planar Na-NiCl2 batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
1243188
Report Number(s):
PNNL-SA-112622; TE1400000
Journal Information:
Nature Communications, Vol. 7; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 104 works
Citation information provided by
Web of Science

References (21)

Electrical Energy Storage for the Grid: A Battery of Choices journal November 2011
Electrochemical Energy Storage for Green Grid journal May 2011
High temperature sodium batteries: status, challenges and future trends journal January 2013
Sodium-Metal Halide and Sodium-Air Batteries journal June 2014
Battery Technologies for Large-Scale Stationary Energy Storage journal July 2011
Main Challenges for High Performance NAS Battery: Materials and Interfaces journal May 2012
Sodium-beta alumina batteries: Status and challenges journal September 2010
Alternate Cathodes for Sodium—Metal Chloride Batteries journal January 1991
An Advanced Na-FeCl 2 ZEBRA Battery for Stationary Energy Storage Application journal April 2015
High Temperature Sodium - Zinc Chloride Batteries With Sodium Beta - Alumina Solid Electrolyte conference January 2007
A novel low-cost sodium–zinc chloride battery journal January 2013
The sodium/nickel chloride (ZEBRA) battery journal November 2001
Advances in ZEBRA batteries journal March 2004
Cell degradation of a Na–NiCl2 (ZEBRA) battery journal January 2013
The effects of temperature on the electrochemical performance of sodium–nickel chloride batteries journal October 2012
Experimental evaluation of the performance of the sodium metal chloride battery below usual operating temperatures journal April 2014
The theory of Ostwald ripening journal January 1985
Temperature effects on the transition from nucleation and growth to Ostwald ripening journal July 2004
Solubility of nickel chloride in molten sodium tetrachloroaluminate saturated with sodium chloride over the temperature range 200–400 °C journal January 1993
Novel ternary molten salt electrolytes for intermediate-temperature sodium/nickel chloride batteries journal December 2012
Advanced rechargeable sodium batteries with novel cathodes journal February 1990

Cited By (14)

“Ni-Less” Cathodes for High Energy Density, Intermediate Temperature Na-NiCl 2 Batteries journal March 2018
An Ultralong Lifespan and Low-Temperature Workable Sodium-Ion Full Battery for Stationary Energy Storage journal March 2018
A Low‐Cost Durable Na‐FeCl 2 Battery with Ultrahigh Rate Capability journal March 2020
Self‐Formulated Na‐Based Dual‐Ion Battery Using Nonflammable SO 2 ‐Based Inorganic Liquid Electrolyte journal August 2019
Challenges and perspectives on high and intermediate-temperature sodium batteries journal June 2017
Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery journal September 2019
An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage journal July 2018
Disordered carbon tubes based on cotton cloth for modulating interface impedance in β′′-Al 2 O 3 -based solid-state sodium metal batteries journal January 2018
Decorating β′′-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures journal January 2018
Room-temperature liquid metal and alloy systems for energy storage applications journal January 2019
Advances in sodium secondary batteries utilizing ionic liquid electrolytes journal January 2019
Silica‐free sealing glass for sodium‐beta alumina battery journal August 2018
An Electrochemical Study on the Cathode of the Intermediate Temperature Tubular Sodium-Sulfur (NaS) Battery journal January 2019
Rechargeable Mg–Li hybrid batteries: status and challenges journal September 2016

Similar Records

Novel ternary molten salt electrolytes for intermediate-temperature sodium/nickel chloride batteries
Journal Article · Sat Dec 15 00:00:00 EST 2012 · Journal of Power Sources · OSTI ID:1243188

A novel low-cost sodium–zinc chloride battery
Journal Article · Tue Feb 19 00:00:00 EST 2013 · Energy & Environmental Science · OSTI ID:1243188

The effects of temperature on the electrochemical performance of sodium–nickel chloride batteries
Journal Article · Mon Oct 01 00:00:00 EDT 2012 · Journal of Power Sources · OSTI ID:1243188