Elasticity and magnetocaloric effect in MnFe4Si3
Abstract
The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the infuence of the magnetic transition and the magnetocaloric effect on the lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low energy, ~5 neV, phonon modes. A significant infuence of the magnetic transition on the lattice dynamics is observed only in the low energy region. Here, MnFe4Si3 and other compounds in the Mn5-xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements and Moessbauer spectroscopy in order to study the magnetic transitions and to complement the obtained results on the lattice dynamics.
- Authors:
-
- Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Julich Centre for Neutron Science JCNS and Peter Grunberg Institut, Julich (Germany); Univ. de Liege, Liege (Belgium)
- Julich Centre for Neutron Science JCNS and Peter Grunberg Institut, Julich (Germany)
- Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
- Julich Centre for Neutron Science JCNS and Peter Grunberg Institut, Julich (Germany); Univ. de Liege, Liege (Belgium); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1242674
- Alternate Identifier(s):
- OSTI ID: 1242621
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 93; Journal Issue: 9; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Herlitschke, Marcus, Klobes, B., Sergueev, I., Hering, Paul, Persson, Joerg, and Hermann, Raphael P. Elasticity and magnetocaloric effect in MnFe4Si3. United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.93.094304.
Herlitschke, Marcus, Klobes, B., Sergueev, I., Hering, Paul, Persson, Joerg, & Hermann, Raphael P. Elasticity and magnetocaloric effect in MnFe4Si3. United States. https://doi.org/10.1103/PhysRevB.93.094304
Herlitschke, Marcus, Klobes, B., Sergueev, I., Hering, Paul, Persson, Joerg, and Hermann, Raphael P. 2016.
"Elasticity and magnetocaloric effect in MnFe4Si3". United States. https://doi.org/10.1103/PhysRevB.93.094304. https://www.osti.gov/servlets/purl/1242674.
@article{osti_1242674,
title = {Elasticity and magnetocaloric effect in MnFe4Si3},
author = {Herlitschke, Marcus and Klobes, B. and Sergueev, I. and Hering, Paul and Persson, Joerg and Hermann, Raphael P.},
abstractNote = {The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the infuence of the magnetic transition and the magnetocaloric effect on the lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low energy, ~5 neV, phonon modes. A significant infuence of the magnetic transition on the lattice dynamics is observed only in the low energy region. Here, MnFe4Si3 and other compounds in the Mn5-xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements and Moessbauer spectroscopy in order to study the magnetic transitions and to complement the obtained results on the lattice dynamics.},
doi = {10.1103/PhysRevB.93.094304},
url = {https://www.osti.gov/biblio/1242674},
journal = {Physical Review B},
issn = {2469-9950},
number = 9,
volume = 93,
place = {United States},
year = {Wed Mar 16 00:00:00 EDT 2016},
month = {Wed Mar 16 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Recent developments in magnetocaloric materials
journal, May 2005
- Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
- Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012
- Franco, V.; Blázquez, J. S.; Ingale, B.
- Annual Review of Materials Research, Vol. 42, Issue 1
Attainment of Temperatures Below 1° Absolute by Demagnetization of ·8 O
journal, May 1933
- Giauque, W. F.; MacDougall, D. P.
- Physical Review, Vol. 43, Issue 9
Theoretical aspects of the magnetocaloric effect
journal, April 2010
- de Oliveira, N. A.; von Ranke, P. J.
- Physics Reports, Vol. 489, Issue 4-5
Magnetocaloric effect from indirect measurements: Magnetization and heat capacity
journal, July 1999
- Pecharsky, V. K.; Gschneidner, K. A.
- Journal of Applied Physics, Vol. 86, Issue 1
Structure, Magnetism, and the Magnetocaloric Effect of MnFe 4 Si 3 Single Crystals and Powder Samples
journal, October 2015
- Hering, Paul; Friese, Karen; Voigt, Jörg
- Chemistry of Materials, Vol. 27, Issue 20
Anomalously high entropy change in FeRh alloy
journal, February 1996
- Annaorazov, M. P.; Nikitin, S. A.; Tyurin, A. L.
- Journal of Applied Physics, Vol. 79, Issue 3
Atomic and magnetic structure of Mn5–xFexSi3
journal, September 1973
- Bińczycka, H.; Dimitrijević, Ž.; Gajić, B.
- Physica Status Solidi (a), Vol. 19, Issue 1
Toward a better understanding of the magnetocaloric effect: An experimental and theoretical study of MnFe4Si3
journal, August 2014
- Gourdon, Olivier; Gottschlich, Michael; Persson, Joerg
- Journal of Solid State Chemistry, Vol. 216
Magnetic and Mössbauer effect studies of Mn5Si3:Fe5Si3 solid solutions
journal, March 1972
- Johnson, Vancliff; Weiher, J. F.; Frederick, C. G.
- Journal of Solid State Chemistry, Vol. 4, Issue 2
Resonant ultrasound spectroscopic techniques for measurement of the elastic moduli of solids
journal, January 1993
- Migliori, A.; Sarrao, J. L.; Visscher, William M.
- Physica B: Condensed Matter, Vol. 183, Issue 1-2
Magnetic phase transition and magnetocaloric effect in Mn5−xFexSi3
journal, February 2002
- Songlin, ; Tegus, O.
- Journal of Alloys and Compounds, Vol. 334, Issue 1-2
Revised magnetic phase diagram for FexMn5−xSi3 intermetallics
journal, June 2004
- Candini, A.; Moze, O.; Kockelmann, W.
- Journal of Applied Physics, Vol. 95, Issue 11
Itinerant Electron Magnetism
journal, August 1984
- Moriya, T.; Takahashi, Y.
- Annual Review of Materials Science, Vol. 14, Issue 1
Magnetic properties of crystallineand amorphous alloys: A systematic discussion based on the Rhodes-Wohlfarth plot
journal, January 1978
- Wohlfarth, E. P.
- Journal of Magnetism and Magnetic Materials, Vol. 7, Issue 1-4
Electrical resistivity and magnetic susceptibility studies of the system Mn5Si3-Fe5Si3
journal, January 1980
- Haug, R.; Kappel, G.; Jaegle, A.
- Journal of Physics and Chemistry of Solids, Vol. 41, Issue 6
Nobel Lecture: From spin waves to giant magnetoresistance and beyond
journal, December 2008
- Grünberg, Peter A.
- Reviews of Modern Physics, Vol. 80, Issue 4
Mössbauer spectral study of the magnetocaloric compounds
journal, December 2004
- Hermann, Raphaël P.; Tegus, O.; Brück, E.
- Physical Review B, Vol. 70, Issue 21
Mössbauer Spectroscopy and Transition Metal Chemistry: Fundamentals and Applications
book, January 2011
- Gütlich, Philipp; Bill, Eckhard; Trautwein, Alfred X.
A structural, magnetic and Mössbauer spectral study of the magnetocaloric Mn 1.1 Fe 0.9 P 1− x Ge x compounds
journal, October 2008
- Sougrati, Moulay T.; Hermann, Raphaël P.; Grandjean, Fernande
- Journal of Physics: Condensed Matter, Vol. 20, Issue 47
Element-Resolved Thermodynamics of Magnetocaloric
journal, February 2015
- Gruner, M. E.; Keune, W.; Roldan Cuenya, B.
- Physical Review Letters, Vol. 114, Issue 5
Measuring velocity of sound with nuclear resonant inelastic x-ray scattering
journal, March 2003
- Hu, Michael Y.; Sturhahn, Wolfgang; Toellner, Thomas S.
- Physical Review B, Vol. 67, Issue 9
Phonon spectroscopy in a Bi2Te3 nanowire array
journal, January 2013
- Bessas, Dimitrios; Töllner, William; Aabdin, Zainul
- Nanoscale, Vol. 5, Issue 21
Phase stability and physical properties of compounds from first-principles calculations
journal, September 2009
- Tao, Xiaoma; Jund, Philippe; Colinet, Catherine
- Physical Review B, Vol. 80, Issue 10
The Elastic Behaviour of a Crystalline Aggregate
journal, May 1952
- Hill, R.
- Proceedings of the Physical Society. Section A, Vol. 65, Issue 5
Magnetism and bonding in a D88 structure; Mössbauer and magnetic investigation of the system Mn5Si3-Fe5Si3
journal, July 1970
- Narasimhan, K. S. V. L.; Reiff, W. M.; Steinfink, H.
- Journal of Physics and Chemistry of Solids, Vol. 31, Issue 7
Mixed Magnetism for Refrigeration and Energy Conversion
journal, September 2011
- Dung, Nguyen H.; Ou, Zhi Qiang; Caron, Luana
- Advanced Energy Materials, Vol. 1, Issue 6
Magnetic Disorder as a First-Order Phase Transformation
journal, April 1962
- Bean, C. P.; Rodbell, D. S.
- Physical Review, Vol. 126, Issue 1
Elastic anomalies associated with structural and magnetic phase transitions in single crystal hexagonal YMnO 3
journal, January 2014
- Thomson, R. I.; Chatterji, T.; Howard, C. J.
- Journal of Physics: Condensed Matter, Vol. 26, Issue 4
Lattice instabilities in bulk EuTiO
journal, October 2013
- Bessas, D.; Rushchanskii, K. Z.; Kachlik, M.
- Physical Review B, Vol. 88, Issue 14
Anisotropic lattice dynamics and intermediate-phase magnetism in delafossite
journal, July 2015
- Klobes, B.; Herlitschke, M.; Rushchanskii, K. Z.
- Physical Review B, Vol. 92, Issue 1
Magnetically tunable sound velocity in iron borate
journal, October 1980
- Wettling, W.; Jantz, W.; Dötsch, H.
- Applied Physics, Vol. 23, Issue 2
Magnetism and magnetic materials: by J.M.D. Coey, Cambridge, Cambridge University Press, 2018, 617 pp., £59.99 (paperback), ISBN 9781108717519. Scope: review. Level: advanced undergraduate, postgraduate, early career researcher, researcher.
journal, October 2019
- Howard, Eric
- Contemporary Physics, Vol. 60, Issue 4
Magnetische Untersuchungen
journal, January 1889
- Wiedemann, G.
- Annalen der Physik, Vol. 273, Issue 8
Mössbauer Spectroscopy and Transition Metal Chemistry
book, January 1978
- Gütlich, Philipp; Link, Rainer; Trautwein, Alfred X.
- Inorganic Chemistry Concepts
Magnetische Untersuchungen
journal, February 1960
- Höhl, Martin
- International Journal of Materials Research, Vol. 51, Issue 2
Electrical resistivity and magnetic susceptibility studies of the system Mn5Si3 - Fe5Si3
journal, March 1980
- Haug, R.; Kappel, G.; Jaegle, A.
- Solid State Communications, Vol. 33, Issue 12
Magnetism and Magnetic Materials
journal, October 1959
- Sucksmith, W.
- Physics Bulletin, Vol. 10, Issue 10
Mixed Magnetism for Refrigeration and Energy Conversion
text, January 2012
- Dung, N. H.; Ou, Z. Q.; Caron, L.
- arXiv
Lattice instabilities in bulk EuTiO3
text, January 2013
- Bessas, D.; Rushchanskii, K. Z.; Kachlik, M.
- arXiv
Works referencing / citing this record:
Lattice dynamics across the magnetic transition in
journal, March 2018
- Bessas, D.; Maschek, M.; Yibole, H.
- Physical Review B, Vol. 97, Issue 9
Lattice dynamics and elasticity in thermoelectric
journal, February 2019
- Klobes, Benedikt; de Boor, Johannes; Alatas, Ahmet
- Physical Review Materials, Vol. 3, Issue 2