Out-of-equilibrium dynamics of photoexcited spin-state concentration waves

Marino, Andrea; Buron-Le Cointe, M.; Lorenc, M.; Toupet, L.; Henning, Robert W.; DiChiara, A. D.; Moffat, Keith; Brefuel, N.; Collet, E.

doi:10.1039/c4fd00164h

Title: Out-of-equilibrium dynamics of photoexcited spin-state concentration waves

Journal Article · Wed Jan 28 00:00:00 EST 2015 · Faraday Discussions

DOI:https://doi.org/10.1039/c4fd00164h· OSTI ID:1240682

Marino, Andrea ^[1]; Buron-Le Cointe, M. ^[2]; Lorenc, M. ^[2]; Toupet, L. ^[2]; Henning, Robert W. ^[3]; DiChiara, A. D. ^[4]; Moffat, Keith ^[3]; Brefuel, N. ^[5]; Collet, E. ^[2]

Univ. of Rennes, Rennes (France). Inst. of Physics
Univ. of Rennes, Rennes (France). Inst. of Physics
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources
Argonne National Lab. (ANL), Argonne, IL (United States)
National Centre for Scientific Research and Alternative Energies and Atomic Energy Commission (CEA-CNRS), Grenoble (France). Observatory for Micro and Nano Technologies (OMNT)

The spin crossover compound [Fe^IIH₂L^2-Me][PF₆]2 presents a two-step phase transition. In the intermediate phase, a spin state concentration wave (SSCW) appears resulting from a symmetry breaking (cell doubling) associated with a long-range order of alternating high and low spin molecular states. Lastly, by combining time-resolved optical and X-ray diffraction measurements on a single crystal, we study how such a system responds to femtosecond laser excitation and we follow in real time the erasing and rewriting of the SSCW

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Centre National de la Recherche Scientifique (CNRS); National Institutes of Health (NIH); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; ANR-13-BS04-0002

OSTI ID:: 1240682

Journal Information:: Faraday Discussions, Vol. 177; ISSN 1359-6640

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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Spectroscopy and Chemical Bonding in Transition Metal Complexes Hauser, Andreas; Reber, Christian Structure and Bonding https://doi.org/10.1007/430_2015_195	book	January 2016
Activation of coherent lattice phonon following ultrafast molecular spin-state photo-switching: A molecule-to-lattice energy transfer Marino, A.; Cammarata, M.; Matar, S. F. Structural Dynamics, Vol. 3, Issue 2 https://doi.org/10.1063/1.4936290	journal	November 2015
Formation of local spin-state concentration waves during the relaxation from a photoinduced state in a spin-crossover polymer Mariette, Céline; Trzop, Elzbieta; Zerdane, Serhane Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 73, Issue 4 https://doi.org/10.1107/s2052520617007685	journal	July 2017

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