Experimental study and thermodynamic modeling of the Al–Co–Cr–Ni system

Gheno, Thomas; Liu, Xuan L.; Lindwall, Greta; Liu, Zi -Kui; Gleeson, Brian

doi:10.1088/1468-6996/16/5/055001

Title: Experimental study and thermodynamic modeling of the Al–Co–Cr–Ni system

Journal Article · Mon Sep 21 00:00:00 EDT 2015 · Science and Technology of Advanced Materials

DOI:https://doi.org/10.1088/1468-6996/16/5/055001· OSTI ID:1239687

Gheno, Thomas ^[1]; Liu, Xuan L. ^[2]; Lindwall, Greta ^[2]; Liu, Zi -Kui ^[2]; Gleeson, Brian ^[1]

Univ. of Pittsburgh, Pittsburgh, PA (United States)
The Pennsylvania State Univ., University Park, PA (United States)

In this study, a thermodynamic database for the Al–Co–Cr–Ni system is built via the Calphad method by extrapolating re-assessed ternary subsystems. A minimum number of quaternary parameters are included, which are optimized using experimental phase equilibrium data obtained by electron probe micro-analysis and x-ray diffraction analysis of NiCoCrAlY alloys spanning a wide compositional range, after annealing at 900 °C, 1100 °C and 1200 °C, and water quenching. These temperatures are relevant to oxidation and corrosion resistant MCrAlY coatings, where M corresponds to some combination of nickel and cobalt. Comparisons of calculated and measured phase compositions show excellent agreement for the β–γ equilibrium, and good agreement for three-phase β–γ–σ and β–γ–α equilibria. An extensive comparison with existing Ni-base databases (TCNI6, TTNI8, NIST) is presented in terms of phase compositions.

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Research Organization:: Univ. of Pittsburgh, PA (United States); Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0024056

OSTI ID:: 1239687

Journal Information:: Science and Technology of Advanced Materials, Vol. 16, Issue 5; ISSN 1468-6996

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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References (32)

Nano-structures at martensite macrotwin interfaces in Ni65Al35 Boullay, Ph.; Schryvers, D.; Ball, J. M. Acta Materialia, Vol. 51, Issue 5 https://doi.org/10.1016/S1359-6454(02)00536-0	journal	March 2003
Cyclic oxidation of high temperature coatings on new γ′-strengthened cobalt-based alloys Vermaak, N.; Mottura, A.; Pollock, T. M. Corrosion Science, Vol. 75 https://doi.org/10.1016/j.corsci.2013.06.013	journal	October 2013
Cobalt-Base High-Temperature Alloys Sato, J. Science, Vol. 312, Issue 5770 https://doi.org/10.1126/science.1121738	journal	April 2006
The Thermo-Calc databank system Sundman, Bo; Jansson, Bo; Andersson, Jan-Olof Calphad, Vol. 9, Issue 2 https://doi.org/10.1016/0364-5916(85)90021-5	journal	April 1985
Designing oxidation-resistant coatings Nicholls, J. R. JOM, Vol. 52, Issue 1 https://doi.org/10.1007/s11837-000-0112-2	journal	January 2000
CALPHAD description of the Mo–Re system focused on the sigma phase modeling Mathieu, R.; Dupin, N.; Crivello, J. -C. Calphad, Vol. 43 https://doi.org/10.1016/j.calphad.2013.08.002	journal	December 2013
Investigation of phases in Al23Co15Cr23Cu8Fe15Ni16 and Al8Co17Cr17Cu8Fe17Ni33 high entropy alloys and comparison with equilibrium phases predicted by Thermo-Calc Manzoni, A.; Daoud, H.; Mondal, S. Journal of Alloys and Compounds, Vol. 552 https://doi.org/10.1016/j.jallcom.2012.11.074	journal	March 2013
Progress in coatings for gas turbine airfoils Goward, G. W. Surface and Coatings Technology, Vol. 108-109 https://doi.org/10.1016/S0257-8972(98)00667-7	journal	October 1998
First-Principles Calculations and CALPHAD Modeling of Thermodynamics Liu, Zi-Kui Journal of Phase Equilibria and Diffusion, Vol. 30, Issue 5 https://doi.org/10.1007/s11669-009-9570-6	journal	September 2009
On the stability of Cr carbides Lee, Byeong-Joo Calphad, Vol. 16, Issue 2 https://doi.org/10.1016/0364-5916(92)90002-F	journal	April 1992
Mechanisms controlling the durability of thermal barrier coatings Evans, A. G.; Mumm, D. R.; Hutchinson, J. W. Progress in Materials Science, Vol. 46, Issue 5 https://doi.org/10.1016/S0079-6425(00)00020-7	journal	January 2001
Creep properties of different γ′-strengthened Co-base superalloys Bauer, A.; Neumeier, S.; Pyczak, F. Materials Science and Engineering: A, Vol. 550 https://doi.org/10.1016/j.msea.2012.04.083	journal	July 2012
Computational Thermodynamics Aided High-Entropy Alloy Design Zhang, Chuan; Zhang, Fan; Chen, Shuanglin JOM, Vol. 64, Issue 7 https://doi.org/10.1007/s11837-012-0365-6	journal	June 2012
Thermodynamic re-assessment of the ternary system Al-Cr-Ni Dupin, N.; Ansara, I.; Sundman, B. Calphad, Vol. 25, Issue 2 https://doi.org/10.1016/S0364-5916(01)00049-9	journal	June 2001
High temperature oxidation of γ/γ′-strengthened Co-base superalloys Klein, L.; Bauer, A.; Neumeier, S. Corrosion Science, Vol. 53, Issue 5 https://doi.org/10.1016/j.corsci.2011.02.033	journal	May 2011
A thermodynamic database for Ni-base superalloys Dupin, N.; Sundman, B. Scandinavian Journal of Metallurgy, Vol. 30, Issue 3 https://doi.org/10.1034/j.1600-0692.2001.300309.x	journal	June 2001
Ductility enhancement by boron addition in Co–Al–W high-temperature alloys Shinagawa, Kazuya; Omori, Toshihiro; Oikawa, Katsunari Scripta Materialia, Vol. 61, Issue 6 https://doi.org/10.1016/j.scriptamat.2009.05.037	journal	September 2009
High-Entropy Alloys: A Critical Review Tsai, Ming-Hung; Yeh, Jien-Wei Materials Research Letters, Vol. 2, Issue 3 https://doi.org/10.1080/21663831.2014.912690	journal	April 2014
Theoretical and experimental study of the γ and γ′ equilibrium in Ni-based superalloys Brož, P.; Buršı́k, J.; Svoboda, M. Materials Science and Engineering: A, Vol. 324, Issue 1-2 https://doi.org/10.1016/S0921-5093(01)01278-3	journal	February 2002
Computational Thermodynamics Lukas, Hans; Fries, Suzana G.; Sundman, Bo https://doi.org/10.1017/CBO9780511804137	book	January 2007
Mechanical Properties of Co-Based L1<SUB>2</SUB> Intermetallic Compound Co<SUB>3</SUB>(Al,W) Miura, Seiji; Ohkubo, Kenji; Mohri, Tetsuo MATERIALS TRANSACTIONS, Vol. 48, Issue 9 https://doi.org/10.2320/matertrans.MAW200734	journal	January 2007
Thermodynamic investigation into the equilibrium phases in the NiCoCrAl system at elevated temperatures Ma, Kaka; Schoenung, Julie M. Surface and Coatings Technology, Vol. 205, Issue 7 https://doi.org/10.1016/j.surfcoat.2010.09.009	journal	December 2010
High-temperature strength and deformation of γ/γ′ two-phase Co–Al–W-base alloys Suzuki, A. Acta Materialia, Vol. 56, Issue 6 https://doi.org/10.1016/j.actamat.2007.11.014	journal	April 2008
Modelling of phase equilibria in MCrAlY coating systems Achar, D. R. G.; Munoz-Arroyo, R.; Singheiser, L. Surface and Coatings Technology, Vol. 187, Issue 2-3 https://doi.org/10.1016/j.surfcoat.2004.02.018	journal	October 2004
First-Principles Calculations, Experimental Study, and Thermodynamic Modeling of the Al-Co-Cr System Liu, Xuan L.; Gheno, Thomas; Lindahl, Bonnie B. PLOS ONE, Vol. 10, Issue 4 https://doi.org/10.1371/journal.pone.0121386	journal	April 2015
Theoretical and experimental study of the γ and γ′ equilibrium in the Ni–Al–Cr–Co system Brož, P.; Buršı́k, J.; Picha, R. Intermetallics, Vol. 10, Issue 6 https://doi.org/10.1016/S0966-9795(02)00044-4	journal	June 2002
The effect of grain boundaries on high temperature oxidation of new γ′-strengthened Co–Al–W–B superalloys Klein, L.; von Bartenwerffer, B.; Killian, M. S. Corrosion Science, Vol. 79 https://doi.org/10.1016/j.corsci.2013.10.022	journal	February 2014
New Co-based γ-γ′ high-temperature alloys Pollock, T. M.; Dibbern, J.; Tsunekane, M. JOM, Vol. 62, Issue 1 https://doi.org/10.1007/s11837-010-0013-y	journal	January 2010
Crystal chemistry and Calphad modeling of the σ phase Joubert, J. -M. Progress in Materials Science, Vol. 53, Issue 3 https://doi.org/10.1016/j.pmatsci.2007.04.001	journal	March 2008
Thermo-Calc & DICTRA, computational tools for materials science Andersson, J-O; Helander, Thomas; Höglund, Lars Calphad, Vol. 26, Issue 2 https://doi.org/10.1016/S0364-5916(02)00037-8	journal	June 2002
Microstructure and phase equilibria in Ni–Al–Cr–Co alloys Buršík, Jiří; Brož, Pavel; Popovič, Jiří Intermetallics, Vol. 14, Issue 10-11 https://doi.org/10.1016/j.intermet.2005.11.024	journal	October 2006
High-Entropy Alloys: A Critical Review Tsai, Ming-Hung; Yeh, Jien-Wei Taylor & Francis https://doi.org/10.6084/m9.figshare.1009576.v2	text	January 2014

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