Lanthanide(III) di- and tetra-nuclear complexes supported by a chelating tripodal tris(amidate) ligand

Brown, Jessie L.; Jones, Matthew B.; Gaunt, Andrew J.; Scott, Brian L.; MacBeth, Cora E.; Gordon, John C.

doi:10.1021/acs.inorgchem.5b00299

Title: Lanthanide(III) di- and tetra-nuclear complexes supported by a chelating tripodal tris(amidate) ligand

Journal Article · Mon Apr 06 00:00:00 EDT 2015 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.5b00299· OSTI ID:1239314

Brown, Jessie L. ^[1]; Jones, Matthew B. ^[1]; Gaunt, Andrew J. ^[1]; Scott, Brian L. ^[1]; MacBeth, Cora E. ^[2]; Gordon, John C. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Emory Univ., Atlanta, GA (United States)

Syntheses, structural, and spectroscopic characterization of multinuclear tris(amidate) lanthanide complexes is described. Addition of K₃[N(o-PhNC(O)^tBu)₃] to LnX₃ (LnX₃ = LaBr₃, CeI₃, and NdCl₃) in N,N-dimethylformamide (DMF) results in the generation of dinuclear complexes, [Ln(N(o-PhNC(O)^tBu)₃)(DMF)]₂(μ-DMF) (Ln = La (1), Ce (2), Nd(3)), in good yields. Syntheses of tetranuclear complexes, [Ln(N(o-PhNC(O)^tBu)₃)]₄ (Ln = Ce (4), Nd(5)), resulted from protonolysis of Ln[N(SiMe₃)₂]₃ (Ln = Ce, Nd) with N(o-PhNCH(O)^tBu)₃. As a result, in the solid-state, complexes 1–5 exhibit coordination modes of the tripodal tris(amidate) ligand that are unique to the 4f elements and have not been previously observed in transition metal systems.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1239314

Report Number(s):: LA-UR-15-20407

Journal Information:: Inorganic Chemistry, Vol. 54, Issue 8; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (65)

Dissociation of Diglycolamide Complexes of Ln ³⁺ (Ln = La–Lu) and An ³⁺ (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior Gong, Yu; Tian, Guoxin; Rao, Linfeng Inorganic Chemistry, Vol. 53, Issue 22 https://doi.org/10.1021/ic501985p	journal	October 2014
Covalency in the f-element–chalcogen bond Ingram, Kieran I. M.; Kaltsoyannis, Nikolas; Gaunt, Andrew J. Journal of Alloys and Compounds, Vol. 444-445 https://doi.org/10.1016/j.jallcom.2007.03.048	journal	October 2007
The remarkable efficiency of N-heterocyclic carbenes in lanthanide(iii)/actinide(iii) differentiation Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre Chemical Communications, Issue 22 https://doi.org/10.1039/b503526k	journal	January 2005
Structural and electrochemical characterization of a cerium( iv ) hydroxamate complex: implications for the beneficiation of light rare earth ores Lee, Heui Beom; Bogart, Justin A.; Carroll, Patrick J. Chem. Commun., Vol. 50, Issue 40 https://doi.org/10.1039/C3CC46486E	journal	January 2014
A review of the beneficiation of rare earth element bearing minerals Jordens, Adam; Cheng, Ying Ping; Waters, Kristian E. Minerals Engineering, Vol. 41 https://doi.org/10.1016/j.mineng.2012.10.017	journal	February 2013
Coordination of Lanthanide Triflates and Perchlorates with N , N , N ‘, N ‘-Tetramethylsuccinamide Rapko, Brian M.; McNamara, Bruce K.; Rogers, Robin D. Inorganic Chemistry, Vol. 39, Issue 21 https://doi.org/10.1021/ic000244k	journal	October 2000
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR ₂ ) ₂ ] ₃ Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) Gaunt, Andrew J.; Reilly, Sean D.; Enriquez, Alejandro E. Inorganic Chemistry, Vol. 47, Issue 1 https://doi.org/10.1021/ic701618a	journal	January 2008
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2013 Edelmann, Frank T. Coordination Chemistry Reviews, Vol. 284 https://doi.org/10.1016/j.ccr.2014.09.017	journal	February 2015
Review: Lanthanide coordination chemistry: from old concepts to coordination polymers Bünzli, Jean-Claude G. Journal of Coordination Chemistry, Vol. 67, Issue 23-24 https://doi.org/10.1080/00958972.2014.957201	journal	September 2014
Synthesis and Characterization of Nitrogen-Rich Macrocyclic Ligands and an Investigation of Their Coordination Chemistry with Lanthanum(III) Wilson, Justin J.; Birnbaum, Eva R.; Batista, Enrique R. Inorganic Chemistry, Vol. 54, Issue 1 https://doi.org/10.1021/ic501843c	journal	December 2014
Lower Denticity Leading to Higher Stability: Structural and Solution Studies of Ln(III)–OBETA Complexes Negri, Roberto; Baranyai, Zsolt; Tei, Lorenzo Inorganic Chemistry, Vol. 53, Issue 23 https://doi.org/10.1021/ic5020225	journal	November 2014
Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker Yakovenko, Marina V.; Cherkasov, Anton V.; Fukin, Georgy K. European Journal of Inorganic Chemistry, Vol. 2010, Issue 21 https://doi.org/10.1002/ejic.201000330	journal	June 2010
Differences in actinide metal–ligand orbital interactions: comparison of U(iv) and Pu(iv) β-ketoiminate N,O donor complexes Schnaars, David D.; Batista, Enrique R.; Gaunt, Andrew J. Chemical Communications, Vol. 47, Issue 27 https://doi.org/10.1039/c1cc12409a	journal	January 2011
Bonding Trends Traversing the Tetravalent Actinide Series: Synthesis, Structural, and Computational Analysis of An ^IV ( ^Ar acnac) ₄ Complexes (An = Th, U, Np, Pu; ^Ar acnac = Ar N C(Ph)CHC(Ph) O ; Ar = 3,5- ^t Bu ₂ C ₆ H ₃ ) Schnaars, David D.; Gaunt, Andrew J.; Hayton, Trevor W. Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic301109f	journal	July 2012
Excellent Selectivity for Actinides with a Tetradentate 2,9-Diamide-1,10-Phenanthroline Ligand in Highly Acidic Solution: A Hard–Soft Donor Combined Strategy Xiao, Cheng-Liang; Wang, Cong-Zhi; Yuan, Li-Yong Inorganic Chemistry, Vol. 53, Issue 3 https://doi.org/10.1021/ic402784c	journal	January 2014
Complexation of Lanthanides(III), Americium(III), and Uranium(VI) with Bitopic N,O Ligands: an Experimental and Theoretical Study Marie, Cécile; Miguirditchian, Manuel; Guillaumont, Dominique Inorganic Chemistry, Vol. 50, Issue 14 https://doi.org/10.1021/ic200271e	journal	July 2011
New Bitopic Ligands for the Group Actinide Separation by Solvent Extraction Marie, Cécile; Miguirditchian, Manuel; Guillaneux, Denis Solvent Extraction and Ion Exchange, Vol. 29, Issue 2 https://doi.org/10.1080/07366299.2011.556923	journal	March 2011
Rare-Earth Amidate Complexes. Easily Accessed Initiators For ε-Caprolactone Ring-Opening Polymerization Stanlake, Louisa J. E.; Beard, J. David; Schafer, Laurel L. Inorganic Chemistry, Vol. 47, Issue 18 https://doi.org/10.1021/ic8010635	journal	August 2008
Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization of rac-lactide Hu, Xiaolin; Lu, Chengrong; Wu, Bing Journal of Organometallic Chemistry, Vol. 732 https://doi.org/10.1016/j.jorganchem.2013.02.022	journal	May 2013
Synthesis and Reactivities of Guanidinate Dianion Complexes of Heterobimetallic Lanthanide−Lithium Cp ₂ Ln[(CyN) ₂ CNPh]Li(THF) ₃ Zheng, Pengzhi; Hong, Jianquan; Liu, Ruiting Organometallics, Vol. 29, Issue 5 https://doi.org/10.1021/om9010615	journal	March 2010
Reactivity of Organolanthanide and Organolithium Complexes Containing the Guanidinate Ligands toward Isocyanate or Carbodiimide: Synthesis and Crystal Structures Zhang, Jie; Zhou, Xigeng; Cai, Ruifang Inorganic Chemistry, Vol. 44, Issue 3 https://doi.org/10.1021/ic048683x	journal	February 2005
Yttrium (amidate) complexes for catalytic C–N bond formation. Rapid, room temperature amidation of aldehydes Thomson, Jaclyn A.; Schafer, Laurel L. Dalton Transactions, Vol. 41, Issue 26 https://doi.org/10.1039/c2dt30214d	journal	January 2012
Synthesis, structure, and catalytic activity of organoyttrium complexes with chiral binaphthyl-based amidate ligands Zhang, Furen; Zhang, Jiaxin; Song, Haibin Inorganic Chemistry Communications, Vol. 14, Issue 1 https://doi.org/10.1016/j.inoche.2010.09.034	journal	January 2011
Synthesis, structure, and catalytic activity of organolanthanides with chiral biphenyl-based tridentate amidate ligands Wang, Qiuwen; Zhang, Furen; Song, Haibin Journal of Organometallic Chemistry, Vol. 696, Issue 10 https://doi.org/10.1016/j.jorganchem.2010.11.032	journal	May 2011
Organolanthanide-Based Coordination and Insertion Reactivity of the Anion Formed by Deprotonation of ε-Caprolactam Evans, William J.; Fujimoto, Cy H.; Ziller, Joseph W. Organometallics, Vol. 20, Issue 22 https://doi.org/10.1021/om010403n	journal	October 2001
Syntheses of {(MeC5H4)2Ln[OC̄H2]}2 (Ln=Yb, Y, Er) and the X-ray crystal structure of the ytterbium complex Wang, Yaorong; Shen, Qi; Wu, Liping Journal of Organometallic Chemistry, Vol. 626, Issue 1-2 https://doi.org/10.1016/S0022-328X(01)00687-8	journal	April 2001
Bis- and Mono(amidate) Complexes of Yttrium: Synthesis, Characterization, and Use as Precatalysts for the Hydroamination of Aminoalkenes Stanlake, Louisa J. E.; Schafer, Laurel L. Organometallics, Vol. 28, Issue 14 https://doi.org/10.1021/om801190t	journal	June 2009
Insertion Reaction of Phenyl Isocyanate into the Ln−C σ-Bond of Organolanthanide Complexes: Synthesis, Characterization, and Crystal Structures of {(C ₅ H ₄ CH ₃ ) ₂ Ln[μ-η ¹ :η ³ -OC(R)NPh]} ₂ (Ln = Sm, Dy, Er, Ho; R = n -butyl, α-naphthyl) Zhou, Xi-geng; Zhang, Li-bei; Zhu, Ming Organometallics, Vol. 20, Issue 26 https://doi.org/10.1021/om010346y	journal	December 2001
Insertion Reactions of PhEtCCO and PhNCO into Ln-S (Ln = Er, Y, Yb) Bond of [Cp2Ln(μ-SEt)]2 Zhang, Chunmei; Lin, Yanghui; Chen, Zhenxia Journal of Rare Earths, Vol. 24, Issue 1 https://doi.org/10.1016/S1002-0721(06)60056-2	journal	February 2006
Synthetic, spectral and structural studies of mononuclear tris(κ2-amidate) aluminium complexes supported by tripodal ligands Jones, Matthew B.; Hardcastle, Kenneth I.; MacBeth, Cora E. Polyhedron, Vol. 29, Issue 1 https://doi.org/10.1016/j.poly.2009.06.013	journal	January 2010
Chelating tris(amidate) ligands: versatile scaffolds for nickel(ii) Jones, Matthew B.; Newell, Brian S.; Hoffert, Wesley A. Dalton Trans., Vol. 39, Issue 2 https://doi.org/10.1039/B914301G	journal	January 2010
Oxygen Activation and Intramolecular C–H Bond Activation by an Amidate-Bridged Diiron(II) Complex Jones, Matthew B.; Hardcastle, Kenneth I.; Hagen, Karl S. Inorganic Chemistry, Vol. 50, Issue 14 https://doi.org/10.1021/ic2007183	journal	July 2011
Tripodal Phenylamine-Based Ligands and Their Co ^II Complexes Jones, Matthew B.; MacBeth, Cora E. Inorganic Chemistry, Vol. 46, Issue 20 https://doi.org/10.1021/ic701289y	journal	October 2007
Synthesis, Characterization, and Reactivity of Iron Trisamidoamine Complexes That Undergo Both Metal- and Ligand-Centered Oxidative Transformations Çelenligil-Çetin, Remle; Paraskevopoulou, Patrina; Dinda, Rupam Inorganic Chemistry, Vol. 47, Issue 3 https://doi.org/10.1021/ic702154z	journal	January 2008
Crystal and molecular structure of the decacoordinate compound ((hydroxyethyl)ethylenediaminetriacetato)diaquolanthanum(III) trihydrate Fuller, Charles C.; Molzahn, David K.; Jacobson, Robert A. Inorganic Chemistry, Vol. 17, Issue 8 https://doi.org/10.1021/ic50186a020	journal	August 1978
Structural Studies of Rare Earth/Transition Metal Complex Ion Systems as a Basis for Understanding Their Thermal Decomposition to Mixed Oxides Brayshaw, Philippa A.; Hall, Annegret K.; Harrison, William T. A. European Journal of Inorganic Chemistry, Vol. 2005, Issue 6 https://doi.org/10.1002/ejic.200400863	journal	March 2005
First characterization of an uranium(III) complex with a carbonyl-containing ligand: Syntheses and X-ray crystal structures of the homoleptic dimethylformamide complexes [M(dmf)n]I3 (M=Ce, Nd and n=8; M=La, Ce, U and n=9) Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel Polyhedron, Vol. 25, Issue 7 https://doi.org/10.1016/j.poly.2005.11.010	journal	May 2006
A series of three-dimensional lanthanide(iii) coordination polymers of 2,5-dihydroxy-1,4-benzenedicarboxylic acid based on dinuclear lanthanide units Wang, Yu-Ling; Jiang, Yun-Liang; Liu, Qing-Yan CrystEngComm, Vol. 13, Issue 15 https://doi.org/10.1039/c1ce05069a	journal	January 2011
Reduction of structural dimensionality through incorporation of auxiliary ligands in lanthanide tetracyanoplatinates Stojanovic, Milorad; Robinson, Nicholas J.; Chen, Xi Inorganica Chimica Acta, Vol. 370, Issue 1 https://doi.org/10.1016/j.ica.2011.02.077	journal	May 2011
Structural and Density Functional Studies of Uranium(III) and Lanthanum(III) Complexes with a Neutral Tripodal N-Donor Ligand Suggesting the Presence of a U−N Back-Bonding Interaction Mazzanti, Marinella; Wietzke, Raphaël; Pécaut, Jacques Inorganic Chemistry, Vol. 41, Issue 9 https://doi.org/10.1021/ic010839v	journal	May 2002
A rare uranium(III) complex of a tripodal aromatic amine and its lanthanum analogue Wietzke, Raphaël; Mazzanti, Marinella; Latour, Jean-Marc Journal of the Chemical Society, Dalton Transactions, Issue 24 https://doi.org/10.1039/a807921h	journal	January 1998
X-ray and Multinuclear Magnetic Resonance Study of the Complexes of Lanthanum(III) with 2,2':6',2''-Terpyridine Frechette, Monique; Bensimon, Corinne Inorganic Chemistry, Vol. 34, Issue 13 https://doi.org/10.1021/ic00117a022	journal	June 1995
Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10-tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series Campello, M. Paula C.; Lacerda, Sara; Santos, Isabel C. Chemistry - A European Journal, Vol. 16, Issue 28 https://doi.org/10.1002/chem.201000320	journal	June 2010
Cerium(IV) alkoxides with functional alcohols: Synthesis and molecular structure of Ce2(OiPr)6(μ-OC2H4NMeC2H4NMe2)2 Hubert-Pfalzgraf, Liliane G.; El Khokh, Norddine; Daran, Jean-Claude Polyhedron, Vol. 11, Issue 1 https://doi.org/10.1016/S0277-5387(00)83260-X	journal	January 1992
Three novel lanthanide complexes with imidazole-4,5-dicarboxylate ligand: Hydrothermal syntheses, structural characterization, and properties Li, Zhao-Yang; Zhang, Zhi-Min; Dai, Jing-Wei Journal of Molecular Structure, Vol. 963, Issue 1 https://doi.org/10.1016/j.molstruc.2009.10.009	journal	January 2010
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Magnetic Properties versus Network Dimensionality of Cerium(III) Octacyanotungstate(V) Compounds Kozieł, Marcin; Pełka, Robert; Rams, Michał Inorganic Chemistry, Vol. 49, Issue 9 https://doi.org/10.1021/ic100158g	journal	April 2010
Lanthanide Coordination Polymers with Tetrafluoroterephthalate as a Bridging Ligand: Thermal and Optical Properties Seidel, Christiane; Lorbeer, Chantal; Cybińska, Joanna Inorganic Chemistry, Vol. 51, Issue 8 https://doi.org/10.1021/ic202655d	journal	March 2012
A molecular precursor approach to monodisperse scintillating CeF3 nanocrystals Mishra, Shashank; Jeanneau, Erwann; Bulin, Anne-Laure Dalton Transactions, Vol. 42, Issue 35 https://doi.org/10.1039/c3dt50605c	journal	January 2013
A tetranuclear neodymium cage which tightly binds sodium carbonate molecules B. Deacon, Glen; Feng, Tiecheng; C. R. Hockless, David Chemical Communications, Issue 4 https://doi.org/10.1039/a606743c	journal	January 1997
Selective formation of lanthanide(III) complexes with polyaminopolycarboxylate: Unprecedented tetranuclear neodymium(III) complex containing alkoxo and carboxylato bridges Miyashita, Yoshitaro; Sanada, Masateru; Islam, Md. Monirul Inorganic Chemistry Communications, Vol. 8, Issue 9 https://doi.org/10.1016/j.inoche.2005.06.008	journal	September 2005
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H. Organometallics, Vol. 29, Issue 9 https://doi.org/10.1021/om100106e	journal	May 2010
Facile synthesis, characterization, and evaluation of neurotoxicity effect of cerium oxide nanoparticles Darroudi, Majid; Hakimi, Mohammad; Sarani, Mina Ceramics International, Vol. 39, Issue 6 https://doi.org/10.1016/j.ceramint.2013.02.026	journal	August 2013
Luminescence, absorption, and Stern–Volmer studies of cerium chloride and nitrate compounds in acidic and neutral aqueous, and non-aqueous solutions Forcha, Derick; Brown, Kwame J.; Assefa, Zerihun Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 103 https://doi.org/10.1016/j.saa.2012.11.015	journal	February 2013
Energy transfer and photoextinction from Ln3+ to Tb3+ and Eu3+ in aqueous chloride solutions Wang, Jiwei; Tanner, Peter A. Journal of Luminescence, Vol. 128, Issue 11 https://doi.org/10.1016/j.jlumin.2008.05.012	journal	November 2008
Molecular Dynamics Studies of Concentrated Binary Aqueous Solutions of Lanthanide Salts: Structures and Exchange Dynamics Duvail, Magali; Ruas, Alexandre; Venault, Laurent Inorganic Chemistry, Vol. 49, Issue 2 https://doi.org/10.1021/ic9017085	journal	January 2010
A new simple criterion for distinguishing the types of structures in eight-coordinate complexes: The pattern of bond angles Haigh, C. W. Polyhedron, Vol. 14, Issue 20-21 https://doi.org/10.1016/0277-5387(95)00213-C	journal	September 1995
Bis({tris[2-(3,5-di- tert -butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate Dröse, Peter; Hrib, Cristian G.; Edelmann, Frank T. Acta Crystallographica Section E Structure Reports Online, Vol. 66, Issue 11 https://doi.org/10.1107/S1600536810039565	journal	October 2010
Solvent Exchange and Electron-Spin Relaxation on Homoleptic Acetonitrile Complexes of Trivalent Lanthanides Bodizs, Gabriella; Helm, Lothar Inorganic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/ic5028493	journal	January 2015
Luminescence study on preferential solvation of Europium(III) in water/non-aqueous solvent mixtures Kimura, Takaumi; Nagaishi, Ryuji; Kato, Yoshiharu Journal of Alloys and Compounds, Vol. 323-324 https://doi.org/10.1016/S0925-8388(01)01121-5	journal	July 2001
Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides Bradley, Donald C.; Ghotra, Joginder S.; Hart, F. Alan Journal of the Chemical Society, Dalton Transactions, Issue 10 https://doi.org/10.1039/dt9730001021	journal	January 1973
Amine Elimination Reactions between Homoleptic Silylamide Lanthanide Complexes and an Isopropylidene-Bridged Cyclopentadiene−Fluorene System Dash, Aswini K.; Razavi, Abbas; Mortreux, André Organometallics, Vol. 21, Issue 15 https://doi.org/10.1021/om0200398	journal	June 2002
Synthesis and Characterization of Volatile, Fluorine-Free β-Ketoiminate Lanthanide MOCVD Precursors and Their Implementation in Low-Temperature Growth of Epitaxial CeO ₂ Buffer Layers for Superconducting Electronics Edleman, Nikki L.; Wang, Anchuan; Belot, John A. Inorganic Chemistry, Vol. 41, Issue 20 https://doi.org/10.1021/ic020299h	journal	October 2002
Cerium( iii ) dialkyl dithiocarbamates from [Ce{N(SiMe ₃ ) ₂ } ₃ ] and tetraalkylthiuram disulfides, and [Ce(κ ² -S ₂ CNEt ₂ ) ₄ ] from the Ce ^III precursor; Tb ^III and Nd ^III analogues Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F. Dalton Trans., Issue 1 https://doi.org/10.1039/B311397C	journal	January 2004
Single-crystal structure validation with the program PLATON Spek, A. L. Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13 https://doi.org/10.1107/S0021889802022112	journal	January 2003

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