Direct Observation of Photoinduced Charge Separation in Ruthenium Complex/Ni(OH)2 Nanoparticle Hybrid

Tang, Yu; Pattengale, Brian A.; Ludwig, John M.; Atifi, Abderrahman; Zinovev, Alexander V.; Dong, Bin; Kong, Qingyu; Zuo, Xiaobing; Zhang, Xiaoyi; Huang, Jier

doi:10.1038/srep18505

Title: Direct Observation of Photoinduced Charge Separation in Ruthenium Complex/Ni(OH)₂ Nanoparticle Hybrid

Journal Article · Thu Dec 17 00:00:00 EST 2015 · Scientific Reports

DOI:https://doi.org/10.1038/srep18505· OSTI ID:1236501

Tang, Yu ^[1]; Pattengale, Brian A. ^[1]; Ludwig, John M. ^[1]; Atifi, Abderrahman ^[1]; Zinovev, Alexander V. ^[2]; Dong, Bin ^[1]; Kong, Qingyu ^[3]; Zuo, Xiaobing ^[3]; Zhang, Xiaoyi ^[3]; Huang, Jier ^[1]

Marquette Univ., Milwaukee, WI (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division

We report that Ni(OH)₂ have emerged as important functional materials for solar fuel conversion because of their potential as cost-effective bifunctional catalysts for both hydrogen and oxygen evolution reactions. However, their roles as photocatalysts in the photoinduced charge separation (CS) reactions remain unexplored. In this paper, we investigate the CS dynamics of a newly designed hybrid catalyst by integrating a Ru complex with Ni(OH)₂ nanoparticles (NPs). Using time resolved X-ray absorption spectroscopy (XTA), we directly observed the formation of the reduced Ni metal site (~60 ps), unambiguously demonstrating CS process in the hybrid through ultrafast electron transfer from Ru complex to Ni(OH)₂ NPs. Compared to the ultrafast CS process, the charge recombination in the hybrid is ultraslow (>>50 ns). These results not only suggest the possibility of developing Ni(OH)₂ as solar fuel catalysts, but also represent the first time direct observation of efficient CS in a hybrid catalyst using XTA.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1236501

Journal Information:: Scientific Reports, Vol. 5; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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References (30)

Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces Subbaraman, R.; Tripkovic, D.; Strmcnik, D. Science, Vol. 334, Issue 6060 https://doi.org/10.1126/science.1211934	journal	December 2011
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Excited-State Metal-to-Ligand Charge Transfer Dynamics of a Ruthenium(II) Dye in Solution and Adsorbed on TiO 2 Nanoparticles from Resonance Raman Spectroscopy Shoute, Lian C. T.; Loppnow, Glen R. Journal of the American Chemical Society, Vol. 125, Issue 50 https://doi.org/10.1021/ja035231v	journal	December 2003
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO ₄ Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja207348x	journal	November 2011
Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts Reece, S. Y.; Hamel, J. A.; Sung, K. Science, Vol. 334, Issue 6056 https://doi.org/10.1126/science.1209816	journal	September 2011
The Role of Hole Localization in Sacrificial Hydrogen Production by Semiconductor–Metal Heterostructured Nanocrystals Acharya, Krishna P.; Khnayzer, Rony S.; O’Connor, Timothy Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1021/nl201388c	journal	July 2011
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) ₂ /Metal Catalysts Danilovic, N.; Subbaraman, Ram; Strmcnik, D. Angewandte Chemie International Edition, Vol. 51, Issue 50 https://doi.org/10.1002/anie.201204842	journal	November 2012
Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution Trotochaud, Lena; Ranney, James K.; Williams, Kerisha N. Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja307507a	journal	October 2012
Photoelectrochemical cells Grätzel, Michael Nature, Vol. 414, Issue 6861 https://doi.org/10.1038/35104607	journal	November 2001
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors Youngblood, W. Justin; Lee, Seung-Hyun Anna; Maeda, Kazuhiko Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9002398	journal	December 2009
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Colloidal CdS nanorods decorated with subnanometer sized Pt clusters for photocatalytic hydrogen generation Berr, Maximilian; Vaneski, Aleksandar; Susha, Andrei S. Applied Physics Letters, Vol. 97, Issue 9 https://doi.org/10.1063/1.3480613	journal	August 2010
Structural and Electronic Study of an Amorphous MoS3 Hydrogen-Generation Catalyst on a Quantum-Controlled Photosensitizer Tang, Ming L.; Grauer, David C.; Lassalle-Kaiser, Benedikt Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201104412	journal	September 2011
Photocatalytic H₂ Evolution on MoS₂/CdS Catalysts under Visible Light Irradiation Zong, Xu; Wu, Guopeng; Yan, Hongjian The Journal of Physical Chemistry C, Vol. 114, Issue 4 https://doi.org/10.1021/jp904350e	journal	January 2010
Evaluation of Pt, Ni, and Ni–Mo electrocatalysts for hydrogen evolution on crystalline Si electrodes McKone, James R.; Warren, Emily L.; Bierman, Matthew J. Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01488a	journal	January 2011
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
Nanostructured Cobalt Oxide Clusters in Mesoporous Silica as Efficient Oxygen-Evolving Catalysts Jiao, Feng; Frei, Heinz Angewandte Chemie International Edition, Vol. 48, Issue 10 https://doi.org/10.1002/anie.200805534	journal	February 2009
Adaptive semiconductor/electrocatalyst junctions in water-splitting photoanodes Lin, Fuding; Boettcher, Shannon W. Nature Materials, Vol. 13, Issue 1 https://doi.org/10.1038/nmat3811	journal	December 2013
Efficient Water Oxidation Using Nanostructured α-Nickel-Hydroxide as an Electrocatalyst Gao, Minrui; Sheng, Wenchao; Zhuang, Zhongbin Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja502128j	journal	May 2014
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts Subbaraman, Ram; Tripkovic, Dusan; Chang, Kee-Chul Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3313	journal	May 2012
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts Luo, J.; Im, J. -H.; Mayer, M. T. Science, Vol. 345, Issue 6204 https://doi.org/10.1126/science.1258307	journal	September 2014
Ni(OH)2 modified CdS nanorods for highly efficient visible-light-driven photocatalytic H2 generation Ran, Jingrun; Yu, Jiaguo; Jaroniec, Mietek Green Chemistry, Vol. 13, Issue 10 https://doi.org/10.1039/c1gc15465f	journal	January 2011
Subpicosecond Interfacial Charge Separation in Dye-Sensitized Nanocrystalline Titanium Dioxide Films Tachibana, Yasuhiro; Moser, Jacques E.; Grätzel, Michael The Journal of Physical Chemistry, Vol. 100, Issue 51 https://doi.org/10.1021/jp962227f	journal	January 1996
Spectroelectrochemistry of Nanostructured NiO Boschloo, Gerrit; Hagfeldt, Anders The Journal of Physical Chemistry B, Vol. 105, Issue 15, p. 3039-3044 https://doi.org/10.1021/jp003499s	journal	April 2001
Paraotwayite-type α-Ni(OH) ₂ Nanowires: Structural, Optical, and Electrochemical Properties Gao, Tao; Jelle, Bjørn Petter The Journal of Physical Chemistry C, Vol. 117, Issue 33 https://doi.org/10.1021/jp405149d	journal	August 2013
Ultrafast Dynamics in the Metal-to-Ligand Charge Transfer Excited-State Evolution of [Ru(4,4‘-diphenyl-2,2‘-bipyridine) ₃ ] ²⁺ Damrauer, Niels H.; McCusker, James K. The Journal of Physical Chemistry A, Vol. 103, Issue 42 https://doi.org/10.1021/jp9927754	journal	October 1999
Structural Characterization of Surfactant-Coated Bimetallic Cobalt/Nickel Nanoclusters by XPS, EXAFS, WAXS, and SAXS Sciortino, Luisa; Giannici, Francesco; Martorana, Antonino The Journal of Physical Chemistry C, Vol. 115, Issue 14 https://doi.org/10.1021/jp200288y	journal	March 2011
Some Structural Approaches to Cinema: A Survey of Models Cook, David A. Cinema Journal, Vol. 14, Issue 3 https://doi.org/10.2307/1225133	journal	January 1975

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