Mixed polyanion glass cathodes: Glass-state conversion reactions

Kercher, Andrew K.; Kolopus, James A.; Carroll, Kyler; Unocic, Raymond R.; Kirklin, S.; Wolverton, C.; Stooksbury, Shelby L.; Boatner, Lynn A.; Dudney, Nancy J.

doi:10.1149/2.0381602jes

Title: Mixed polyanion glass cathodes: Glass-state conversion reactions

Journal Article · Tue Nov 10 00:00:00 EST 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0381602jes· OSTI ID:1234999

Kercher, Andrew K. ^[1]; Kolopus, James A. ^[1]; Carroll, Kyler ^[2]; Unocic, Raymond R. ^[1]; Kirklin, S. ^[3]; Wolverton, C. ^[4];

^[1]; Boatner, Lynn A. ^[1]; Dudney, Nancy J. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Wildcat Discovery Technologies, San Diego, CA (United States)
Northwestern Univ., Evanston, IL (United States)
Northwestern University, Evanston

Mixed polyanion (MP) glasses can undergo glass-state conversion (GSC) reactions to provide an alternate class of high-capacity cathode materials. GSC reactions have been demonstrated in phosphate/vanadate glasses with Ag, Co, Cu, Fe, and Ni cations. These MP glasses provided high capacity and good high power performance, but suffer from moderate voltages, large voltage hysteresis, and significant capacity fade with cycling. Details of the GSC reaction have been revealed by x-ray absorption spectroscopy, electron microscopy, and energy dispersive x-ray spectroscopy of ex situ cathodes at key states of charge. Using the Open Quantum Materials Database (OQMD), a computational thermodynamic model has been developed to predict the near-equilibrium voltages of glass-state conversion reactions in MP glasses.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1234999

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 2; ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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