Do TFSA anions slither? Pressure exposes the role of TFSA conformational exchange in self-diffusion

Suarez, Sophia N.; Wishart, James F.; Rua, Armando; Cuffari, David; Pilar, Kartik; Hatcher, Jasmine L.; Ramati, Sharon

doi:10.1021/acs.jpcb.5b08658

Title: Do TFSA anions slither? Pressure exposes the role of TFSA conformational exchange in self-diffusion

Journal Article · Wed Oct 28 00:00:00 EDT 2015 · Journal of Physical Chemistry. B

DOI:https://doi.org/10.1021/acs.jpcb.5b08658· OSTI ID:1222605

Suarez, Sophia N. ^[1]; Wishart, James F. ^[2]; Rua, Armando ^[3]; Cuffari, David ^[1]; Pilar, Kartik ^[3]; Hatcher, Jasmine L. ^[4]; Ramati, Sharon ^[2]

Brooklyn College, Brooklyn, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Hunter College, New York, NY (United States)
City Univ. Graduate School (CUNY), NY, New York (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Multinuclear (¹H, ²H, and ¹⁹F) magnetic resonance spectroscopy techniques as functions of temperature and pressure were applied to the study of selectively deuterated 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (EMIM TFSA) ionic liquid isotopologues and related ionic liquids. For EMIM TFSA, temperature-dependent ²H T₁ data indicate stronger electric field gradients in the alkyl chain region compared to the imidazolium ring. Most significantly, the pressure dependences of the EMIM and TFSA self-diffusion coefficients revealed that the displacements of the cations and anions are independent, with diffusion of the TFSA anions being slowed much more by increasing pressure than for the EMIM cations, as shown by their respective activation volumes (28.8 ± 2.5 cm³/mol for TFSA vs 14.6 ± 1.3 cm³/mol for EMIM). Increasing pressure may lower the mobility of the TFSA anion by hindering its interconversion between trans and cis conformers, a process that is coupled to diffusion according to published molecular dynamics simulations. Measured activation volumes (ΔV‡) for ion self-diffusion in EMIM bis(fluoromethylsulfonyl)amide and EMIM tetrafluoroborate support this hypothesis. In addition, ²H T₁ data suggest increased ordering with increasing pressure, with two T₁ regimes observed for the MD₃ and D₂ isotopologues between 0.1–100 and 100–250 MPa, respectively. As a result, the activation volumes for T₁ were 21 and 25 cm³/mol (0–100 MPa) and 11 and 12 cm³/mol (100–250 MPa) for the MD₃ and D₂ isotopologues, respectively.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1222605

Alternate ID(s):: OSTI ID: 1226072

Report Number(s):: BNL-108392-2015-JA; BNL-108556-2015-JA; R&D Project: CO-031; KC0301010

Journal Information:: Journal of Physical Chemistry. B, Journal Name: Journal of Physical Chemistry. B; ISSN 1520-6106

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 31 works

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References (58)

Pressure effect on vibrational frequency and dephasing of 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids Pison, L.; Costa Gomes, M. F.; Pádua, A. A. H. The Journal of Chemical Physics, Vol. 139, Issue 5 https://doi.org/10.1063/1.4817403	journal	August 2013
High Pressure Chemistry: Synthetic, Mechanistic, and Supercritical Applications van Eldik, Rudi; Klärner, Frank‐Gerrit WILEY‐VCH Verlag GmbH https://doi.org/10.1002/9783527612628	book	May 2002
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Hydrogen Bond Stabilization in 1,3-Dimethylimidazolium Methyl Sulfate and 1-Butyl-3-Methylimidazolium Hexafluorophosphate Probed by High Pressure: The Role of Charge-Enhanced C−H···O Interactions in the Room-Temperature Ionic Liquid Chang, Hai-Chou; Jiang, Jyh-Chiang; Tsai, Wei-Cheng The Journal of Physical Chemistry B, Vol. 110, Issue 7 https://doi.org/10.1021/jp0560009	journal	February 2006
Temperature and Pressure Dependence of the Viscosity of the Ionic Liquids 1-Hexyl-3-methylimidazolium Hexafluorophosphate and 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Harris, Kenneth R.; Kanakubo, Mitsuhiro; Woolf, Lawrence A. Journal of Chemical & Engineering Data, Vol. 52, Issue 3 https://doi.org/10.1021/je700032n	journal	May 2007
In Situ Observation of Multiple Phase Transitions in Low-Melting Ionic Liquid [BMIM][BF ₄ ] under High Pressure up to 30 GPa Su, Lei; Zhu, Xiang; Wang, Zheng The Journal of Physical Chemistry B, Vol. 116, Issue 7 https://doi.org/10.1021/jp2108939	journal	February 2012
Effect of Pressure on the Transport Properties of Ionic Liquids: 1-Alkyl-3-methylimidazolium Salts Harris, Kenneth R.; Kanakubo, Mitsuhiro; Tsuchihashi, Noriaki The Journal of Physical Chemistry B, Vol. 112, Issue 32 https://doi.org/10.1021/jp8021375	journal	August 2008
Ion Transport Effects in a Solid Polymer Electrolyte Due to Salt Substitution and Addition Using an Ionic Liquid Kösters, Johannes; Schönhoff, Monika; Stolwijk, Nicolaas A. The Journal of Physical Chemistry B, Vol. 117, Issue 8 https://doi.org/10.1021/jp311563h	journal	February 2013
A Tale of Two Ions: The Conformational Landscapes of Bis(trifluoromethanesulfonyl)amide and N , N -Dialkylpyrrolidinium Canongia Lopes, José N.; Shimizu, Karina; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 112, Issue 5 https://doi.org/10.1021/jp076997a	journal	February 2008
Understanding chemical reaction mechanisms in ionic liquids: successes and challenges Hubbard, Colin D.; Illner, Peter; van Eldik, Rudi Chem. Soc. Rev., Vol. 40, Issue 1 https://doi.org/10.1039/C0CS00043D	journal	January 2011
Temperature-dependent structure of methyltributylammonium bis(trifluoromethylsulfonyl)amide: X ray scattering and simulations Santos, Cherry S.; Annapureddy, Harsha V. R.; Murthy, N. Sanjeeva The Journal of Chemical Physics, Vol. 134, Issue 6 https://doi.org/10.1063/1.3526958	journal	February 2011
Pulsed-Gradient Spin−Echo ¹ H and ¹⁹ F NMR Ionic Diffusion Coefficient, Viscosity, and Ionic Conductivity of Non-Chloroaluminate Room-Temperature Ionic Liquids Noda, Akihiro; Hayamizu, Kikuko; Watanabe, Masayoshi The Journal of Physical Chemistry B, Vol. 105, Issue 20 https://doi.org/10.1021/jp004132q	journal	May 2001
Design of Polymer Electrolytes Based on a Lithium Salt of a Weakly Coordinating Anion to Realize High Ionic Conductivity with Fast Charge-Transfer Reaction Tokuda, Hiroyuki; Tabata, Sei-ichiro; Susan, Md. Abu Bin Hasan The Journal of Physical Chemistry B, Vol. 108, Issue 32 https://doi.org/10.1021/jp048646r	journal	August 2004
Highly reversible lithium metal secondary battery using a room temperature ionic liquid/lithium salt mixture and a surface-coated cathode active material Seki, Shiro; Kobayashi, Yo; Miyashiro, Hajime Chem. Commun., Issue 5 https://doi.org/10.1039/B514681J	journal	January 2006
Temperature and Pressure Dependence of the Viscosity of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate: Viscosity and Density Relationships in Ionic Liquids Harris, Kenneth R.; Kanakubo, Mitsuhiro; Woolf, Lawrence A. Journal of Chemical & Engineering Data, Vol. 52, Issue 6 https://doi.org/10.1021/je700370z	journal	November 2007
Capacitance Measurements in a Series of Room-Temperature Ionic Liquids at Glassy Carbon and Gold Electrode Interfaces Alam, Muhammad Tanzirul; Islam, Md. Mominul; Okajima, Takeyoshi The Journal of Physical Chemistry C, Vol. 112, Issue 42 https://doi.org/10.1021/jp804620m	journal	September 2008
Nanostructural Organization in Ionic Liquids Canongia Lopes, José N. A.; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 110, Issue 7 https://doi.org/10.1021/jp056006y	journal	February 2006
Nuclear magnetic resonance studies on the rotational and translational motions of ionic liquids composed of 1-ethyl-3-methylimidazolium cation and bis(trifluoromethanesulfonyl)amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts Hayamizu, Kikuko; Tsuzuki, Seiji; Seki, Shiro The Journal of Chemical Physics, Vol. 135, Issue 8 https://doi.org/10.1063/1.3625923	journal	August 2011
Solvation dynamics of room-temperature ionic liquids: evidence for collective solvent motion on sub-picosecond timescales Kobrak, Mark N.; Znamenskiy, Vasiliy Chemical Physics Letters, Vol. 395, Issue 1-3 https://doi.org/10.1016/j.cplett.2004.07.049	journal	September 2004
Ionic Conduction and Ion Diffusion in Binary Room-Temperature Ionic Liquids Composed of [emim][BF ₄ ] and LiBF ₄ Hayamizu, Kikuko; Aihara, Yuichi; Nakagawa, Hiroe The Journal of Physical Chemistry B, Vol. 108, Issue 50 https://doi.org/10.1021/jp0476601	journal	December 2004
Evidence of Rotational Isomerism in 1-Butyl-3-methylimidazolium Halides: A Combined High-Pressure Infrared and Raman Spectroscopic Study ^† Chang, Hai-Chou; Jiang, Jyh-Chiang; Su, Jong-Chang The Journal of Physical Chemistry A, Vol. 111, Issue 38 https://doi.org/10.1021/jp071055r	journal	September 2007
Experimental methodology for precise determination of density of RTILs as a function of temperature and pressure using vibrating tube densimeters Sanmamed, Y. A.; González-Salgado, D.; Troncoso, J. The Journal of Chemical Thermodynamics, Vol. 42, Issue 4 https://doi.org/10.1016/j.jct.2009.11.014	journal	April 2010
NMR Studies of Translational Motion Price, William S. https://doi.org/10.1017/CBO9780511770487		January 2009
In Situ Crystallization of Low-Melting Ionic Liquid [BMIM][PF ₆ ] under High Pressure up to 2 GPa Su, Lei; Li, Min; Zhu, Xiang The Journal of Physical Chemistry B, Vol. 114, Issue 15 https://doi.org/10.1021/jp912191z	journal	April 2010
Why Does a Reduction in Hydrogen Bonding Lead to an Increase in Viscosity for the 1-Butyl-2,3-dimethyl-imidazolium-Based Ionic Liquids? ^† Hunt, Patricia A. The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067182p	journal	May 2007
Viscosity of Imidazolium-Based Ionic Liquids at Elevated Pressures: Cation and Anion Effects Ahosseini, Azita; Scurto, Aaron M. International Journal of Thermophysics, Vol. 29, Issue 4 https://doi.org/10.1007/s10765-008-0497-7	journal	August 2008
Potential Energy Landscape of Bis(fluorosulfonyl)amide Canongia Lopes, José N.; Shimizu, Karina; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 112, Issue 31 https://doi.org/10.1021/jp803309c	journal	August 2008
Transport Properties of N -Butyl- N -methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide Harris, Kenneth R.; Woolf, Lawrence A.; Kanakubo, Mitsuhiro Journal of Chemical & Engineering Data, Vol. 56, Issue 12 https://doi.org/10.1021/je2006049	journal	December 2011
Conformational Equilibrium of Bis(trifluoromethanesulfonyl) Imide Anion of a Room-Temperature Ionic Liquid: Raman Spectroscopic Study and DFT Calculations Fujii, Kenta; Fujimori, Takao; Takamuku, Toshiyuki The Journal of Physical Chemistry B, Vol. 110, Issue 16 https://doi.org/10.1021/jp0612477	journal	April 2006
Pressure-Induced Spectral Changes of Room-Temperature Ionic Liquid, N , N -Diethyl- N -methyl- N -(2-methoxyethyl)ammonium Bis(trifluoromethylsulfonyl)imide, [DEME][TFSI] Yoshimura, Yukihiro; Takekiyo, Takahiro; Imai, Yusuke The Journal of Physical Chemistry C, Vol. 116, Issue 3 https://doi.org/10.1021/jp205314f	journal	September 2011
Supercapacitance of Solid Carbon Nanofibers Made from Ethanol Flames Bao, Qiaoliang; Bao, Shujuan; Li, Chang Ming The Journal of Physical Chemistry C, Vol. 112, Issue 10 https://doi.org/10.1021/jp710420k	journal	March 2008
Solute Diffusion in Ionic Liquids, NMR Measurements and Comparisons to Conventional Solvents Kaintz, Anne; Baker, Gary; Benesi, Alan The Journal of Physical Chemistry B, Vol. 117, Issue 39 https://doi.org/10.1021/jp405393d	journal	September 2013
Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes Shin, J. Electrochemistry Communications, Vol. 5, Issue 12 https://doi.org/10.1016/j.elecom.2003.09.017	journal	December 2003
Cation Trapping in Highly Porous Carbon Electrodes for EDLC Cells Aurbach, D.; Levi, M. D.; Salitra, G. Journal of The Electrochemical Society, Vol. 155, Issue 10 https://doi.org/10.1149/1.2957911	journal	January 2008
Nuclear Magnetic Resonance Study of the Dynamics of Imidazolium Ionic Liquids with −CH ₂ Si(CH ₃ ) ₃ vs −CH ₂ C(CH ₃ ) ₃ Substituents ^† Chung, Song H.; Lopato, Richard; Greenbaum, Steven G. The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp071755w	journal	May 2007
Pressure and temperature effects on intermolecular vibrational dynamics of ionic liquids Penna, Tatiana C.; Faria, Luiz F. O.; Matos, Jivaldo R. The Journal of Chemical Physics, Vol. 138, Issue 10 https://doi.org/10.1063/1.4793760	journal	March 2013
Thermodynamics and Micro Heterogeneity of Ionic Liquids Gomes, Margarida F. Costa; Lopes, J. N. Canongia; Padua, A. A. H. Topics in Current Chemistry https://doi.org/10.1007/128_2009_2	book	January 2009
Effects of conformational flexibility of alkyl chains of cations on diffusion of ions in ionic liquids Tsuzuki, Seiji; Matsumoto, Hajime; Shinoda, Wataru Physical Chemistry Chemical Physics, Vol. 13, Issue 13 https://doi.org/10.1039/c0cp02087g	journal	January 2011
Ionic Liquid Near a Charged Wall: Structure and Capacitance of Electrical Double Layer Fedorov, Maxim V.; Kornyshev, Alexei A. The Journal of Physical Chemistry B, Vol. 112, Issue 38 https://doi.org/10.1021/jp803440q	journal	September 2008
Effect of Pressure on Transport Properties of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate Kanakubo, Mitsuhiro; Harris, Kenneth R.; Tsuchihashi, Noriaki The Journal of Physical Chemistry B, Vol. 111, Issue 8 https://doi.org/10.1021/jp067328k	journal	March 2007
Conformational preferences of two imidazolium-based ionic liquids at high pressures Takekiyo, Takahiro; Imai, Yusuke; Hatano, Naohiro Chemical Physics Letters, Vol. 511, Issue 4-6 https://doi.org/10.1016/j.cplett.2011.06.022	journal	August 2011
Molecular Dynamics Simulation and Pulsed-Field Gradient NMR Studies of Bis(fluorosulfonyl)imide (FSI) and Bis[(trifluoromethyl)sulfonyl]imide (TFSI)-Based Ionic Liquids Borodin, Oleg; Gorecki, W.; Smith, Grant D. The Journal of Physical Chemistry B, Vol. 114, Issue 20 https://doi.org/10.1021/jp911950q	journal	May 2010
Structural Organization in Aqueous Solutions of 1-Butyl-3-methylimidazolium Halides: A High-Pressure Infrared Spectroscopic Study on Ionic Liquids Chang, Hai-Chou; Jiang, Jyh-Chiang; Chang, Chao-Yen The Journal of Physical Chemistry B, Vol. 112, Issue 14 https://doi.org/10.1021/jp0773482	journal	April 2008
Computational study of imidazolium-based ionic solvents with alkyl substituents of different lengths Margulis *, C. J. Molecular Physics, Vol. 102, Issue 9-10 https://doi.org/10.1080/00268970410001683843	journal	May 2004
Polarizable Force Field Development and Molecular Dynamics Simulations of Ionic Liquids Borodin, Oleg The Journal of Physical Chemistry B, Vol. 113, Issue 33 https://doi.org/10.1021/jp905220k	journal	August 2009
Ionic liquids as electrolytes Galiński, Maciej; Lewandowski, Andrzej; Stępniak, Izabela Electrochimica Acta, Vol. 51, Issue 26 https://doi.org/10.1016/j.electacta.2006.03.016	journal	August 2006
Structure, Conformations, Vibrations, and Ideal-Gas Properties of 1-Alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide Ionic Pairs and Constituent Ions Paulechka, Yauheni U.; Kabo, Gennady J.; Emel’yanenko, Vladimir N. The Journal of Physical Chemistry B, Vol. 112, Issue 49 https://doi.org/10.1021/jp804607n	journal	November 2008
Radiation Induced Redox Reactions and Fragmentation of Constituent Ions in Ionic Liquids. 2. Imidazolium Cations Shkrob, Ilya A.; Marin, Timothy W.; Chemerisov, Sergey D. The Journal of Physical Chemistry B, Vol. 115, Issue 14 https://doi.org/10.1021/jp200305b	journal	April 2011
Structure and thermal properties of crystals, VI. The role of hydrogen bonds in Rochelle salt Ubbelohde, Alfred Rene Jean Paul; Woodward, Ida Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 185, Issue 1003, p. 448-465 https://doi.org/10.1098/rspa.1946.0030	journal	April 1946
Temperature and Pressure Dependence of the Viscosity of the Ionic Liquids 1-Methyl-3-octylimidazolium Hexafluorophosphate and 1-Methyl-3-octylimidazolium Tetrafluoroborate Harris, Kenneth R.; Kanakubo, Mitsuhiro; Woolf, Lawrence A. Journal of Chemical & Engineering Data, Vol. 51, Issue 3 https://doi.org/10.1021/je060082s	journal	May 2006
Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 2. Variation of Alkyl Chain Length in Imidazolium Cation Tokuda, Hiroyuki; Hayamizu, Kikuko; Ishii, Kunikazu The Journal of Physical Chemistry B, Vol. 109, Issue 13 https://doi.org/10.1021/jp044626d	journal	April 2005
Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid Sangoro, J.; Iacob, C.; Serghei, A. The Journal of Chemical Physics, Vol. 128, Issue 21 https://doi.org/10.1063/1.2921796	journal	June 2008
Room temperature molten salts as lithium battery electrolyte Garcia, Béatrice; Lavallée, Serge; Perron, Gérald Electrochimica Acta, Vol. 49, Issue 26 https://doi.org/10.1016/j.electacta.2004.04.041	journal	October 2004
Effect of Anions on Static Orientational Correlations, Hydrogen Bonds, and Dynamics in Ionic Liquids: A Simulational Study Qiao, Baofu; Krekeler, Christian; Berger, Robert The Journal of Physical Chemistry B, Vol. 112, Issue 6 https://doi.org/10.1021/jp0759067	journal	February 2008
Nuclear magnetic resonance study on rotational dynamics of water and benzene in a series of ionic liquids: Anion and cation effects Kimura, Hiroshi; Yasaka, Yoshiro; Nakahara, Masaru The Journal of Chemical Physics, Vol. 137, Issue 19 https://doi.org/10.1063/1.4766258	journal	November 2012
Hydrogen bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO ₃ and KDCO ₃ at 298, 219 and 95 K Thomas, J. O.; Tellgren, R.; Olovsson, I. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 5 https://doi.org/10.1107/S0567740874004481	journal	May 1974
NMR evidence of hydrogen bonding in 1-ethyl-3-methylimidazolium-tetrafluoroborate room temperature ionic liquid Huang, Jing-Fang; Chen, Po-Yu; Sun, I-Wen Inorganica Chimica Acta, Vol. 320, Issue 1-2 https://doi.org/10.1016/S0020-1693(01)00477-7	journal	August 2001
Molecular Force Field for Ionic Liquids Composed of Triflate or Bistriflylimide Anions Canongia Lopes, José N.; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 108, Issue 43 https://doi.org/10.1021/jp0476545	journal	October 2004

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Title: Do TFSA anions slither? Pressure exposes the role of TFSA conformational exchange in self-diffusion

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