Structure and superconductivity in (Bi{sub 0.35}Cu{sub 0.65})Sr{sub 2}YCu{sub 2}O{sub 7} and related materials
- Univ. of Birmingham (United Kingdom)
The recently reported (Bi/Cu)Sr{sub 2}YCu{sub 2}O{sub 7} phase has been studied by time of flight powder neutron diffraction. The proposed 1212 structure has been confirmed and refinements have shown the oxygen in the (Bi/Cu)O layer is displaced by 0.78{angstrom} from the ideal (1/2,1/2,0) site (P4/mmm space group) along (100). Bond Valence Sum calculations have suggested oxidation states of Bi{sup 5+} and Cu{sup 2+} for the cations in the (Bi/Cu)O layers. The material is non-superconducting and all attempts to induce superconductivity have been unsuccessful. Work on the related material (Ce/Cu)Sr{sub 2}YCu{sub 2}O{sub y} has shown the ideal Ce content to be 0.5 Ce per formula unit. The introduction of Ba (10%) onto the Sr site dramatically increases phase stability and also induces superconductivity (62K).
- Research Organization:
- National Aeronautics and Space Administration (NASA), Washington, DC (United States); National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center
- OSTI ID:
- 121644
- Report Number(s):
- CONF-940627-Vol.2; ON: TI95017155; TRN: 99:003583
- Resource Relation:
- Conference: 4. international conference and exhibition of the World Congress on Superconductivity, Orlando, FL (United States), 27 Jun - 1 Jul 1994; Other Information: PBD: 1994; Related Information: Is Part Of Proceedings of the fourth international conference and exhibition: World Congress on superconductivity. Volume 2; Krishen, K.; Burnham, C. [eds.] [National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center]; PB: 400 p.
- Country of Publication:
- United States
- Language:
- English
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