A novel high capacity positive electrode material with tunnel-type structure for aqueous sodium-ion batteries

Wang, Yuesheng; Mu, Linqin; Liu, Jue; Yang, Zhenzhong; Yu, Xiqian; Gu, Lin; Hu, Yong -Sheng; Li, Hong; Yang, Xiao -Qing; Chen, Liquan; Huang, Xuejie

doi:10.1002/aenm.201501005

Title: A novel high capacity positive electrode material with tunnel-type structure for aqueous sodium-ion batteries

Journal Article · Thu Aug 06 00:00:00 EDT 2015 · Advanced Energy Materials (Online)

DOI:https://doi.org/10.1002/aenm.201501005· OSTI ID:1214527

Wang, Yuesheng ^[1]; Mu, Linqin ^[1]; Liu, Jue ^[2]; Yang, Zhenzhong ^[1]; Yu, Xiqian ^[2]; Gu, Lin ^[3]; Hu, Yong -Sheng ^[1]; Li, Hong ^[1]; Yang, Xiao -Qing ^[2]; Chen, Liquan ^[1]; Huang, Xuejie ^[1]

Chinese Academy of Sciences (CAS), Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Collaborative Innovation Center of Quantum Matter, Beijing (China); Chinese Academy of Sciences (CAS), Beijing (China)

In this study, aqueous sodium-ion batteries have shown desired properties of high safety characteristics and low-cost for large-scale energy storage applications such as smart grid, because of the abundant sodium resources as well as the inherently safer aqueous electrolytes. Among various Na insertion electrode materials, tunnel-type Na_0.44MnO₂ has been widely investigated as a positive electrode for aqueous sodium-ion batteries. However, the low achievable capacity hinders its practical applications. Here we report a novel sodium rich tunnel-type positive material with a nominal composition of Na_0.66[Mn_0.66Ti_0.34]O₂. The tunnel-type structure of Na_0.44MnO₂ obtained for this compound was confirmed by XRD and atomic-scale STEM/EELS. When cycled as positive electrode in full cells using NaTi₂(PO₄)₃/C as negative electrode in 1M Na₂SO₄ aqueous electrolyte, this material shows the highest capacity of 76 mAh g^-1 among the Na insertion oxides with an average operating voltage of 1.2 V at a current rate of 2C. These results demonstrate that Na_0.66[Mn_0.66Ti_0.34]O₂ is a promising positive electrode material for rechargeable aqueous sodium-ion batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC00112704

OSTI ID:: 1214527

Report Number(s):: BNL-108337-2015-JA; VT1201000

Journal Information:: Advanced Energy Materials (Online), Journal Name: Advanced Energy Materials (Online); ISSN 1614-6840

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 141 works

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
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Title: A novel high capacity positive electrode material with tunnel-type structure for aqueous sodium-ion batteries

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