Constructing hierarchical interfaces: TiO2-supported PtFe-FeOx nanowires for room temperature CO oxidation

Zhu, Huiyuan; Wu, Zili; Dong, Su; Veith, Gabriel M.; Lu, Hanfeng; Zhang, Pengfei; Chai, Song -Hai; Dai, Sheng

doi:10.1021/jacs.5b07011

Title: Constructing hierarchical interfaces: TiO₂-supported PtFe-FeO_x nanowires for room temperature CO oxidation

Journal Article · Wed Aug 05 00:00:00 EDT 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b07011· OSTI ID:1214513

Zhu, Huiyuan ^[1]; Wu, Zili ^[1]; Dong, Su ^[2]; Veith, Gabriel M. ^[1]; Lu, Hanfeng ^[3]; Zhang, Pengfei ^[1]; Chai, Song -Hai ^[4]; Dai, Sheng ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Zhejiang Univ. of Technology, Zhejiang (China)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

In this study, we report a facile approach to constructing catalytic active hierarchical interfaces in one-dimensional (1D) nanostructure, exemplified by the synthesis of TiO₂-supported PtFe–FeO_x nanowires (NWs). The hierarchical interface, constituting atomic level interactions between PtFe and FeO_x within each NW and the interactions between NWs and support (TiO₂), enables CO oxidation with 100% conversion at room temperature. We identify the role of the two interfaces by probing the CO oxidation reaction with isotopic labeling experiments. Both the oxygen atoms (Os) in FeO_x and TiO₂ participate in the initial CO oxidation, facilitating the reaction through a redox pathway. Moreover, the intact 1D structure leads to the high stability of the catalyst. After 30 h in the reaction stream, the PtFe–FeO_x/TiO₂ catalyst exhibits no activity decay. Our results provide a general approach and new insights into the construction of hierarchical interfaces for advanced catalysis.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC00112704

OSTI ID:: 1214513

Alternate ID(s):: OSTI ID: 1226071

Report Number(s):: BNL-108553-2015-JA

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 32; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 80 works

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