Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality

Yang, Sangmo; Strelcov, Evgheni; Paranthaman, Mariappan Parans; Tselev, Alexander; Noh, Tae Won; Kalinin, Sergei V.

doi:10.1021/nl5040286

Title: Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality

Journal Article · Wed Jan 07 00:00:00 EST 2015 · Nano Letters

DOI:https://doi.org/10.1021/nl5040286· OSTI ID:1185744

Yang, Sangmo ^[1]; Strelcov, Evgheni ^[1]; Paranthaman, Mariappan Parans ^[1]; Tselev, Alexander ^[1]; Noh, Tae Won ^[2]; Kalinin, Sergei V. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Seoul National Univ. (Korea, Republic of)

Scanning probe microscopy (SPM) is a powerful tool to investigate electrochemistry in nanoscale volumes. While most SPM-based studies have focused on reactions at the tip-surface junction, charge and mass conservation requires coupled and intrinsically non-local cathodic and anodic processes that can be significantly affected by ambient humidity. Here, we explore the role of water in both cathodic and anodic processes, associated charge transport, and topographic volume changes depending on the polarity of tip bias. The first-order reversal curve current-voltage technique combined with simultaneous detection of the sample topography, referred to as FORC-IVz, was applied to a silver solid ion conductor. We found that the protons generated from water affect silver ionic conduction, silver particle formation and dissolution, and mechanical integrity of the material. This work highlights the dual nature (simultaneously local and non-local) of electrochemical SPM studies, which should be considered for comprehensive understanding of nanoscale electrochemistry.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185744

Journal Information:: Nano Letters, Vol. 15, Issue 2; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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References (42)

Nanoscale Electrochemistry Oja, Stephen M.; Wood, Marissa; Zhang, Bo Analytical Chemistry, Vol. 85, Issue 2 https://doi.org/10.1021/ac3031702	journal	November 2012
Electrochemistry in nanoscopic volumes Li, Tao; Hu, Wenping Nanoscale, Vol. 3, Issue 1 https://doi.org/10.1039/C0NR00325E	journal	January 2011
The missing memristor found Strukov, Dmitri B.; Snider, Gregory S.; Stewart, Duncan R. Nature, Vol. 453, Issue 7191 https://doi.org/10.1038/nature06932	journal	May 2008
Nanobatteries in redox-based resistive switches require extension of memristor theory Valov, I.; Linn, E.; Tappertzhofen, S. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2784	journal	April 2013
Advanced scanning probe lithography Garcia, Ricardo; Knoll, Armin W.; Riedo, Elisa Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.157	journal	August 2014
Quantized conductance atomic switch Terabe, K.; Hasegawa, T.; Nakayama, T. Nature, Vol. 433, Issue 7021 https://doi.org/10.1038/nature03190	journal	January 2005
Short-term plasticity and long-term potentiation mimicked in single inorganic synapses Ohno, Takeo; Hasegawa, Tsuyoshi; Tsuruoka, Tohru Nature Materials, Vol. 10, Issue 8 https://doi.org/10.1038/nmat3054	journal	June 2011
Electrochemistry at the Nanoscale: The Force Dimension Black, J.; Strelcov, E.; Balke, N. Interface magazine, Vol. 23, Issue 2 https://doi.org/10.1149/2.F06142if	journal	January 2014
Probing Local Ionic Dynamics in Functional Oxides at the Nanoscale Strelcov, Evgheni; Kim, Yunseok; Jesse, Stephen Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl400780d	journal	July 2013
Electrical Modulation of the Local Conduction at Oxide Tubular Interfaces Hsieh, Ying-Hui; Strelcov, Evgheni; Liou, Jia-Ming ACS Nano, Vol. 7, Issue 10 https://doi.org/10.1021/nn402763w	journal	September 2013
Decoupling Electrochemical Reaction and Diffusion Processes in Ionically-Conductive Solids on the Nanometer Scale Balke, Nina; Jesse, Stephen; Kim, Yoongu ACS Nano, Vol. 4, Issue 12 https://doi.org/10.1021/nn101502x	journal	November 2010
Real Space Mapping of Li-Ion Transport in Amorphous Si Anodes with Nanometer Resolution Balke, Nina; Jesse, Stephen; Kim, Yoongu Nano Letters, Vol. 10, Issue 9 https://doi.org/10.1021/nl101439x	journal	September 2010
Nanoscale mapping of ion diffusion in a lithium-ion battery cathode Balke, N.; Jesse, S.; Morozovska, A. N. Nature Nanotechnology, Vol. 5, Issue 10 https://doi.org/10.1038/nnano.2010.174	journal	August 2010
Measuring oxygen reduction/evolution reactions on the nanoscale Kumar, Amit; Ciucci, Francesco; Morozovska, Anna N. Nature Chemistry, Vol. 3, Issue 9 https://doi.org/10.1038/nchem.1112	journal	August 2011
Quantitative nanoscopic impedance measurements on silver-ion conducting glasses using atomic force microscopy combined with impedance spectroscopy Kruempelmann, J.; Balabajew, M.; Gellert, M. Solid State Ionics, Vol. 198, Issue 1 https://doi.org/10.1016/j.ssi.2011.07.008	journal	September 2011
Electrochemical nanopatterning of Ag on solid-state ionic conductor RbAg4I5 using atomic force microscopy Lee, Minhwan; O’Hayre, Ryan; Prinz, Fritz B. Applied Physics Letters, Vol. 85, Issue 16 https://doi.org/10.1063/1.1807964	journal	October 2004
Generic Relevance of Counter Charges for Cation-Based Nanoscale Resistive Switching Memories Tappertzhofen, Stefan; Valov, Ilia; Tsuruoka, Tohru ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4026614	journal	June 2013
Redox-Based Resistive Switching Memories (ReRAMs): Electrochemical Systems at the Atomic Scale Valov, Ilia ChemElectroChem, Vol. 1, Issue 1 https://doi.org/10.1002/celc.201300165	journal	December 2013
Impact of the Counter-Electrode Material on Redox Processes in Resistive Switching Memories Tappertzhofen, Stefan; Waser, Rainer; Valov, Ilia ChemElectroChem, Vol. 1, Issue 8 https://doi.org/10.1002/celc.201402106	journal	June 2014
Proton mobility in SiO ₂ thin films and impact of hydrogen and humidity on the resistive switching effect Tappertzhofen, Stefan; Hempel, Marek; Valov, Ilia MRS Proceedings, Vol. 1330 https://doi.org/10.1557/opl.2011.1198	journal	January 2011
Evidence of electrochemical resistive switching in the hydrated alumina layers of Cu/CuTCNQ/(native AlOx)/Al junctions Knorr, Nikolaus; Bamedi, Ameneh; Karipidou, Zoi Journal of Applied Physics, Vol. 114, Issue 12 https://doi.org/10.1063/1.4823851	journal	September 2013
Effects of Moisture on the Switching Characteristics of Oxide-Based, Gapless-Type Atomic Switches Tsuruoka, Tohru; Terabe, Kazuya; Hasegawa, Tsuyoshi Advanced Functional Materials, Vol. 22, Issue 1 https://doi.org/10.1002/adfm.201101846	journal	October 2011
Nanoionic transport and electrochemical reactions in resistively switching silicon dioxide Tappertzhofen, Stefan; Mündelein, Hans; Valov, Ilia Nanoscale, Vol. 4, Issue 10 https://doi.org/10.1039/c2nr30413a	journal	January 2012
Field-Absorbed Water Induced Electrochemical Processes in Organic Thin Film Junctions Knorr, Nikolaus; Wirtz, René; Rosselli, Silvia The Journal of Physical Chemistry C, Vol. 114, Issue 37 https://doi.org/10.1021/jp103625w	journal	August 2010
Second harmonic detection in the electrochemical strain microscopy of Ag-ion conducting glass Yang, Sang Mo; Baris Okatan, M.; Parans Paranthaman, M. Applied Physics Letters, Vol. 105, Issue 19 https://doi.org/10.1063/1.4901736	journal	November 2014
Fast ionic conduction via site percolation in AgI-AgP $O_{3}$ glasses Mangion, M.; Johari, G. P. Physical Review B, Vol. 36, Issue 16 https://doi.org/10.1103/PhysRevB.36.8845	journal	December 1987
Neutron scattering from the superionic glasses, (AgI)x(AgPO3)1−x, through the glass transition Kartini, E.; Collins, M. F.; Indayaningsih, N. Solid State Ionics, Vol. 138, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00781-5	journal	December 2000
Charge carrier mobility and concentration as a function of composition in AgPO ₃ –AgI glasses Rodrigues, Ana Candida Martins; Nascimento, Marcio Luis Ferreira; Bragatto, Caio Barca The Journal of Chemical Physics, Vol. 135, Issue 23 https://doi.org/10.1063/1.3666835	journal	December 2011
Conductivity and viscosity of liquid and gel electrolytes based on LiClO4, LiN(CF3SO2)2 and PMMA Deepa, M. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00307-7	journal	December 2002
The partially reversible formation of Li-metal particles on a solid Li electrolyte: applications toward nanobatteries Arruda, Thomas M.; Kumar, Amit; Kalinin, Sergei V. Nanotechnology, Vol. 23, Issue 32 https://doi.org/10.1088/0957-4484/23/32/325402	journal	July 2012
Mapping Irreversible Electrochemical Processes on the Nanoscale: Ionic Phenomena in Li Ion Conductive Glass Ceramics Arruda, Thomas M.; Kumar, Amit; Kalinin, Sergei V. Nano Letters, Vol. 11, Issue 10 https://doi.org/10.1021/nl202039v	journal	October 2011
Quantum conductance and switching kinetics of AgI-based microcrossbar cells Tappertzhofen, S.; Valov, I.; Waser, R. Nanotechnology, Vol. 23, Issue 14 https://doi.org/10.1088/0957-4484/23/14/145703	journal	March 2012
AFM tip-induced metal particle formation on laser-structured and on unstructured surfaces of solid-state ion conductors Kruempelmann, Julia; Reinhardt, Hendrik; Yada, Chihiro Solid State Ionics, Vol. 234 https://doi.org/10.1016/j.ssi.2013.01.003	journal	March 2013
Towards a quantitative description of solid electrolyte conductance switches Morales-Masis, Monica; Wiemhöfer, Hans-Dieter; van Ruitenbeek, Jan M. Nanoscale, Vol. 2, Issue 10 https://doi.org/10.1039/c0nr00298d	journal	January 2010
Formation and disappearance of a nanoscale silver cluster realized by solid electrochemical reaction Terabe, K.; Nakayama, T.; Hasegawa, T. Journal of Applied Physics, Vol. 91, Issue 12 https://doi.org/10.1063/1.1481775	journal	January 2002
Atomically controlled electrochemical nucleation at superionic solid electrolyte surfaces Valov, Ilia; Sapezanskaia, Ina; Nayak, Alpana Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3307	journal	April 2012
Bulk and surface nucleation processes in Ag $_{2}$ S conductance switches Morales-Masis, M.; van der Molen, S. J.; Hasegawa, T. Physical Review B, Vol. 84, Issue 11 https://doi.org/10.1103/PhysRevB.84.115310	journal	September 2011
Rate-Limiting Processes Determining the Switching Time in a Ag ₂ S Atomic Switch Nayak, Alpana; Tamura, Takuro; Tsuruoka, Tohru The Journal of Physical Chemistry Letters, Vol. 1, Issue 3 https://doi.org/10.1021/jz900375a	journal	January 2010
WSXM : A software for scanning probe microscopy and a tool for nanotechnology Horcas, I.; Fernández, R.; Gómez-Rodríguez, J. M. Review of Scientific Instruments, Vol. 78, Issue 1 https://doi.org/10.1063/1.2432410	journal	January 2007
Nanoscale electrochemical measurements on a lithium-ion conducting glass ceramic: In-situ monitoring of the lithium particle growth Kruempelmann, Julia; Dietzel, Dirk; Schirmeisen, Andre Electrochemistry Communications, Vol. 18 https://doi.org/10.1016/j.elecom.2012.02.019	journal	January 2012
Free volume and dissociation effects in fast ion conducting glasses Swenson, J.; Matic, A.; Karlsson, C. Journal of Non-Crystalline Solids, Vol. 263-264 https://doi.org/10.1016/S0022-3093(99)00670-5	journal	March 2000
Direct observation of ground-state lactam–lactim tautomerization using temperature-jump transient 2D IR spectroscopy Peng, Chunte Sam; Baiz, Carlos R.; Tokmakoff, Andrei Proceedings of the National Academy of Sciences, Vol. 110, Issue 23 https://doi.org/10.1073/pnas.1303235110	journal	May 2013

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Facilitate Measurement of Electrochemical Reactions in Redox-Based Memristors by Simply Thickening the Electrolyte Layer Jamilpanah, Loghman; Mohseni, Seyed Majid physica status solidi (RRL) - Rapid Research Letters, Vol. 12, Issue 5 https://doi.org/10.1002/pssr.201800046	journal	March 2018
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38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
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Title: Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality

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