Long-term oxidation of candidate cast iron and stainless steel exhaust system alloys from 650 to 800 °C in air with water vapor

Journal Article · Fri Aug 29 00:00:00 EDT 2014 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-014-9496-1· OSTI ID:1185421

Brady, Michael P. ^[1]; Muralidharan, Govindarajan ^[1]; Leonard, Donovan . ^[1]; Haynes, James A. ^[1]; Weldon, R. G. ^[2]; England, R. D. ^[2]

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1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
2. Cummins Inc., Columbus, IN (United States)

Here, the oxidation behavior of SiMo cast iron, Ni-resist D₅S cast iron, cast chromia-forming austenitic stainless steels of varying Cr/Ni content based on CF8C plus, HK, and HP, and a developmental cast alumina-forming austenitic (AFA) stainless steel of interest for diesel exhaust system components were studied for up to 5000 h at 650-800 °C in air with 10% H₂O. At 650 °C, the Ni-resist D5S exhibited moderately better oxidation resistance than did the SiMo cast iron. However, the D5S suffered from oxide scale spallation issues at 700 °C and higher, whereas the oxide scales formed on SiMo cast iron remained adherent from 700-800 °C despite oxide scales hundreds of microns thick. The oxidation of the SiMo cast iron exhibited unusual temperature dependence, with periods of slower oxidation kinetics at 750-800 °C compared to 650-700 °C due to continuous silica-rich scale formation at the higher temperatures. The oxidation of the cast chromia-forming austenitics trended with the level of Cr and Ni additions, with small mass losses consistent with Cr oxy-hydroxide volatilization processes for the higher 25Cr/25-35Ni HK and HP type alloys, and transition to rapid Fe-base oxide formation and scale spallation in the lower 19Cr/12Ni CF8C plus type alloy. In contrast, small positive mass changes consistent with protective alumina scale formation were observed for the cast AFA alloy under all conditions studied. Implications of these findings for diesel exhaust system components are discussed.

• Research Organization: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Temperature Materials Lab. (HTML)
• Sponsoring Organization: USDOE Office of Energy Efficiency and Renewable Energy (EERE)
• Grant/Contract Number: AC05-00OR22725
• OSTI ID: 1185421
• Journal Information: Oxidation of Metals, Vol. 82, Issue 5-6; ISSN 0030-770X
• Publisher: Springer
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
water vapor
exhaust
cast iron
austenitic
oxidation